Citation: Weifan Zhang, Lei Wang, Guochun Ding, Yuejia Yang, Guang Yang, Jing Xu, Ningning Xu, Lingling Xie, Qing Han, Limin Zhu, Xiaoyu Cao, Jianmin Ma. Bimetallic CoNiSe₂/C nanosphere anodes derived from Ni-Co-metal-organic framework precursor towards higher lithium storage capacity[J]. Chinese Chemical Letters, ;2023, 34(2): 107328. doi: 10.1016/j.cclet.2022.03.051 shu

Bimetallic CoNiSe₂/C nanosphere anodes derived from Ni-Co-metal-organic framework precursor towards higher lithium storage capacity

Weifan Zhang ^{a, c} ,
Lei Wang ^{a, c} ,
Guochun Ding ^{a, c} ,
Yuejia Yang ^{a, c} ,
Guang Yang ^{a, c} ,
Jing Xu ^{a, c} ,
Ningning Xu ^{a, c} ,
Lingling Xie ^{b, c} ,
Qing Han ^{a, c} ,
Limin Zhu ^{a, c, *,} ,
Xiaoyu Cao ^{a, c, *,} ,
Jianmin Ma ^{d, **,}

a.
School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China
b.
School of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, China
c.
Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City, Henan University of Technology, Zhengzhou 450001, China
d.
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China

^**

lmzhu@haut.edu.cn

caoxy@haut.edu.cn

nanoelechem@uestc.edu.cn

Received Date: 19 December 2021
Revised Date: 5 January 2022
Accepted Date: 10 March 2022
Available Online: 14 March 2022

Figures(7)

Through uncomplicated carbonation process, a carbon-embedded CoNiSe₂/C nanosphere was synthesized from Ni-Co-MOF (metal-organic framework) precursor whose controllable structure and synergistic effect of bimetallic Ni/Co brought CoNiSe₂/C anodes with high specific surface area (172.79 m²/g) and outstanding electrochemical performance. CoNiSe₂/C anodes obtained reversible discharge capacities of 850.9 mAh/g at 0.1 A/g after cycling for 100 cycles. In addition, CoNiSe₂/C exhibits excellent cycle stability and reversibility in the rate test at a current density of 0.1–2.0 A/g. When the current density returns to 0.5 A/g for 150 cycles, its discharge ratio the capacity is 330.8 mAh/g. Electrochemical impedance spectroscopy (EIS) tests suggested that CoNiSe₂/C anodes had a lower charge transfer impedance of 130.02 Ω after 30 cycles. In-situ X-ray diffraction (XRD) tests confirmed the alloying mechanism of CoNiSe₂/C which realized higher lithium storage capacity. This work affords substantial evidence for the extension of bimetallic selenides in secondary batteries, promoting the development of bimetallic selenides in anode materials for LIBs.
- MOFs,
- Bimetallic compound,
- CoNiSe₂/C anode nanosphere,
- Lithium-ion batteries,
- Lithium storage performance
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Bimetallic CoNiSe2/C nanosphere anodes derived from Ni-Co-metal-organic framework precursor towards higher lithium storage capacity

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Bimetallic CoNiSe₂/C nanosphere anodes derived from Ni-Co-metal-organic framework precursor towards higher lithium storage capacity