Citation: Chengyu Zheng, Songyuan Tao, Yang Liu, Chunyuan Kang, Bai Yang. Achieving blue water-dispersed room-temperature phosphorescence of carbonized polymer dots through nano-compositing with mesoporous silica[J]. Chinese Chemical Letters, ;2022, 33(9): 4213-4218. doi: 10.1016/j.cclet.2022.03.041 shu

Achieving blue water-dispersed room-temperature phosphorescence of carbonized polymer dots through nano-compositing with mesoporous silica

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

byangchem@jlu.edu.cn

Received Date: 28 November 2021
Revised Date: 6 March 2022
Accepted Date: 9 March 2022
Available Online: 13 March 2022

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Stabilizing triplet excited states is important for room temperature phosphorescence (RTP) materials to achieve multifunctional applications in humid environment. However, due to the lack of preparation strategies, the realization of RTP materials in water still faces challenges. Herein, a new design strategy was presented to achieve RTP in water by confining carbonized polymer dots (CPDs) in amino functional mesoporous silica (MSNs-NH₂). The as-prepared MSNs-CPDs aqueous dispersion exhibited blue afterglow, lasting more than 3 s to naked eyes. The triplet excited states were protected from non-radiative deactivation by the double-confinement effect including covalent bonding fixation and mesoporous structure confinement. The MSNs-CPDs inherited the structure of MSNs-NH₂, so the stability of morphology and properties were superior to CPDs and even most of silica-based CPDs RTP materials. A water-related encryption technique demonstrated the promising application of MSNs-CPDs as smart materials in the field of information security. Besides, the possibility of potential application in ion detection was also explored.
- Carbonized polymer dots,
- Mesoporous silica,
- Nano-composite,
- Blue room-temperature phosphorescence,
- Water dispersion
1. [1]
  Y. Lei, W. Dai, J. Guan, Angew. Chem. Int. Ed. 59 (2020) 16054–16060. doi: 10.1002/anie.202003585
2. [2]
  Q. Xiong, C. Xu, N. Jiao, Chin. Chem. Lett. 30 (2019) 1387–1389. doi: 10.1016/j.cclet.2019.04.010
3. [3]
  Z. Yang, Z. Mao, X. Zhang, Angew. Chem. Int. Ed. 55 (2016) 2181–2185. doi: 10.1002/anie.201509224
4. [4]
  H. Sun, S. Liu, W. Lin, Nat. Commun. 5 (2014) 3601. doi: 10.1038/ncomms4601
5. [5]
  S.M. Borisov, R. Pommer, J. Svec, J. Mater. Chem. C 6 (2018) 8999–9009. doi: 10.1039/c8tc02726a
6. [6]
  W. Li, Y. Liu, B. Wang, Chin. Chem. Lett. 30 (2019) 2323–2327. doi: 10.1016/j.cclet.2019.06.040
7. [7]
  H. Zhang, J. Jiang, P. Gao, ACS Appl. Mater. Interfaces 10 (2018) 17542–17550. doi: 10.1021/acsami.8b01565
8. [8]
  P.K. Chow, G. Cheng, G.S.M. Tong, Chem. Sci. 7 (2016) 6083–6098. doi: 10.1039/C6SC00462H
9. [9]
  L. Xiao, Z. Chen, B. Qu, Adv. Mater. 23 (2011) 926–952. doi: 10.1002/adma.201003128
10. [10]
  B. Wang, J. Li, Z. Tang, Sci. Bull. 64 (2019) 1285–1292. doi: 10.1016/j.scib.2019.07.021
11. [11]
  X. Yang, L. Sui, B. Wang, Sci China Chem 64 (2021) 1547–1553. doi: 10.1007/s11426-021-1033-6
12. [12]
  V. Caratto, F. Locardi, G.A. Costa, ACS Appl Mater. Interfaces 6 (2014) 17346–17351. doi: 10.1021/am504523s
13. [13]
  T. Aitasalo, P. Dereń, J. Hölsä, J. Solid State Chem. 171 (2003) 114–122. doi: 10.1016/S0022-4596(02)00194-9
14. [14]
  Q. Zhao, F. Li, C. Huang, Chem. Soc. Rev. 39 (2010) 3007–3030. doi: 10.1039/b915340c
15. [15]
  X. Yang, D. Yan, Adv. Opt. Mater. 4 (2016) 897–905. doi: 10.1002/adom.201500666
16. [16]
  Z. An, C. Zheng, Y. Tao, Nat. Mater. 14 (2015) 685–690. doi: 10.1038/nmat4259
17. [17]
  W. Jia, Q. Wang, H. Shi, Chem. Eur. J. 26 (2020) 4437–4448. doi: 10.1002/chem.201904500
18. [18]
  X. Xu, R. Ray, Y. Gu, J. Am. Chem. Soc. 126 (2004) 12736–12737. doi: 10.1021/ja040082h
19. [19]
  S. Tao, T. Feng, C. Zheng, J. Phys. Chem. Lett. 10 (2019) 5182–5188. doi: 10.1021/acs.jpclett.9b01384
20. [20]
  C. Xia, S. Zhu, T. Feng, Adv. Sci 6 (2019) 1901316. doi: 10.1002/advs.201901316
21. [21]
  S. Li, L. Li, H. Tu, Mater. Today 51 (2021) 188–207. doi: 10.1016/j.mattod.2021.07.028
22. [22]
  B. Wang, J. Yu, L. Sui, Adv. Sci. 8 (2020) 2001453.
23. [23]
  P. Long, Y. Feng, C. Cao, Adv. Funct. Mater. 28 (2018) 1800791. doi: 10.1002/adfm.201800791
24. [24]
  K. Jiang, Y. Wang, X. Gao, Angew. Chem. Int. Ed. 57 (2018) 6216–6220. doi: 10.1002/anie.201802441
25. [25]
  K. Jiang, Y. Wang, C. Cai, Adv. Mater. 30 (2018) e1800783. doi: 10.1002/adma.201800783
26. [26]
  S. Zhu, Y. Song, J. Shao, Angew. Chem. Int. Ed. 54 (2015) 14626–14637. doi: 10.1002/anie.201504951
27. [27]
  S. Tao, S. Zhu, T. Feng, Angew. Chem. Int. Ed. 59 (2020) 9826–9840. doi: 10.1002/anie.201916591
28. [28]
  Y. Deng, D. Zhao, X. Chen, Chem. Commun. 49 (2013) 5751–5753. doi: 10.1039/c3cc42600a
29. [29]
  J. Tan, J. Zhang, W. Li, J. Mater. Chem. C 4 (2016) 10146–10153. doi: 10.1039/C6TC03027K
30. [30]
  W. Li, W. Zhou, Z. Zhou, Angew. Chem. Int. Ed. 58 (2019) 7278–7283. doi: 10.1002/anie.201814629
31. [31]
  Q. Li, M. Zhou, M. Yang, Nat. Commun. 9 (2018) 734. doi: 10.1038/s41467-018-03144-9
32. [32]
  C. Wang, Y. Chen, T. Hu, Nanoscale 11 (2019) 11967–11974. doi: 10.1039/c9nr03038g
33. [33]
  W. Li, S. Wu, X. Xu, Chem. Mater. 31 (2019) 9887–9894. doi: 10.1021/acs.chemmater.9b04120
34. [34]
  J. He, Y. Chen, Y. He, Small 16 (2020) e2005228. doi: 10.1002/smll.202005228
35. [35]
  Y. Liang, S. Gou, K. Liu, Nano Today 34 (2020) 100900. doi: 10.1016/j.nantod.2020.100900
36. [36]
  S. Tao, S. Lu, Y. Geng, Angew. Chem. Int. Ed. 57 (2018) 2393–2398. doi: 10.1002/anie.201712662
37. [37]
  K. Jiang, Y. Wang, C. Cai, Chem. Mater. 29 (2017) 4866–4873. doi: 10.1021/acs.chemmater.7b00831
38. [38]
  H. Zhang, B. Wang, X. Yu, Angew. Chem. Int. Ed. 59 (2020) 19390–19402. doi: 10.1002/anie.202006545
39. [39]
  S. Zhu, Q. Meng, L. Wang, Angew. Chem. Int. Ed. 52 (2013) 3953–3957. doi: 10.1002/anie.201300519
40. [40]
  J. Tan, Y. Ye, X. Ren, J. Mater. Chem. C 6 (2018) 7890–7895. doi: 10.1039/C8TC02012D
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2. [2]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
3. [3]
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4. [4]
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5. [5]
  Jichun Li , Zhengren Wang , Yu Deng , Hongxiu Yu , Yonghui Deng , Xiaowei Cheng , Kaiping Yuan . Construction of mesoporous silica-implanted tungsten oxides for selective acetone gas sensing. Chinese Chemical Letters, 2024, 35(11): 110111-. doi: 10.1016/j.cclet.2024.110111
6. [6]
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7. [7]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
8. [8]
  Jianmei Guo , Yupeng Zhao , Lei Ma , Yongtao Wang . Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems. Chinese Journal of Structural Chemistry, 2024, 43(9): 100335-100335. doi: 10.1016/j.cjsc.2023.100335
9. [9]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
10. [10]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
11. [11]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
12. [12]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
13. [13]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
14. [14]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
15. [15]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
16. [16]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
17. [17]
  Chengcheng Xie , Chengyi Xiao , Hongshuo Niu , Guitao Feng , Weiwei Li . Mesoporous organic solar cells. Chinese Chemical Letters, 2024, 35(11): 109849-. doi: 10.1016/j.cclet.2024.109849
18. [18]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
19. [19]
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