Citation: Mulati Mansuer, Ling Miao, Yang Qin, Ziyang Song, Dazhang Zhu, Hui Duan, Yaokang Lv, Liangchun Li, Mingxian Liu, Lihua Gan. Trapping precursor-level functionalities in hierarchically porous carbons prepared by a pre-stabilization route for superior supercapacitors[J]. Chinese Chemical Letters, ;2023, 34(3): 107304. doi: 10.1016/j.cclet.2022.03.027 shu

Trapping precursor-level functionalities in hierarchically porous carbons prepared by a pre-stabilization route for superior supercapacitors

Mulati Mansuer ^{a, 1} ,
Ling Miao ^{a, 1} ,
Yang Qin ^a ,
Ziyang Song ^a ,
Dazhang Zhu ^a ,
Hui Duan ^a ,
Yaokang Lv ^c ,
Liangchun Li ^a ,
Mingxian Liu ^{a, b, *,} ,
Lihua Gan ^{a, *,}

a.
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
c.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

liumx@tongji.edu.cn

ganlh@tongji.edu.cn

Received Date: 2 January 2022
Revised Date: 26 February 2022
Accepted Date: 7 March 2022
Available Online: 9 March 2022

Figures(6)

Versatile module design of precursor networks enables flexible functionalization of nano-carbon electrode materials to meet the adaptable energy-storage demand. Functionalized heterogeneous networks are more likely to decompose by swift temperature programming together with predesign module removal, so high functionality/network transfer from precursor to carbon is still a work in progress. A pre-stabilization route is proposed here to enhance the network strength at early pyrolysis and pin up precursor-level functionalities on the final carbon. Such strategy successfully fixes more electroactive N (4.28−8.86 wt%) into the resultant carbon microspheres compared with non-pretreated carbon (2.89 wt%), as well as achieves broad ion-accessible platforms of 1575–2269 m²/g with preset structural superiorities. As a result, a typical acidic device reveals an outstanding specific capacitance of 383 F/g at 10 mV/s. Taking advantage of a novel LiNO₃-PAM polymer electrolyte, the upgraded symmetric device displays the maximum specific capacitance of 229 F/g, along with a boosted energy density of 41.1 Wh/kg at 643.4 W/kg. This work opens up a feasible insight into realizing highly efficient precursor/electrode design toward superior system with outstanding energy/power feature and temperature applicability.
- Carbon-based supercapacitors,
- Quinone-amine network,
- Pre-stabilization process,
- Symmetric device,
- Polymer electrolyte
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