Citation: Xu Zhang, Lei Zhang, Tao Bo, Shanen Huang, Zhiwei Huang, Weiqun Shi. Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K₂USi₃O₉ and Cs₂UGe₃O₉[J]. Chinese Chemical Letters, ;2022, 33(7): 3527-3530. doi: 10.1016/j.cclet.2022.03.026 shu

Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K₂USi₃O₉ and Cs₂UGe₃O₉

Xu Zhang ^{a, b, 1} ,
Lei Zhang ^{a, 1} ,
Tao Bo ^a ,
Shanen Huang ^{a, c} ,
Zhiwei Huang ^a ,
Weiqun Shi ^{d, *,}

a.
Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
b.
College of Nuclear Science and Technology, Harbin Engineering University, Harbin 150001, China
c.
School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China
d.
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

shiwq@ihep.ac.cn

Received Date: 28 January 2022
Revised Date: 5 March 2022
Accepted Date: 6 March 2022
Available Online: 9 March 2022

Figures(3)

Two tetravalent uranium silicate and germanate M₂U^IVT₃O₉ (M = K, Cs; T = Si, Ge) crystals were crystalized under inert gas by molten salt flux growth method. K₂USi₃O₉ (1) crystallizes in the monoclinic space group P1₂₁/n1 with lattice parameters a = 7.1076 Å, b = 10.4776 Å, c = 12.2957 Å, γ = 120° and V = 915.67 Å³. Cs₂UGe₃O₉ (2) crystallizes in a hexagonal space group P-6 with lattice constants of a = 7.5138 Å, b = 7.5138 Å, c = 11.0114 Å, γ = 120° and V = 538.38 Å³. Bond valence calculations indicate tetravalent uranium in both structures, which contain three-membered single-ring T₃O₉⁶⁻ trimers. K₂USi₃O₉ is the first uranium silicate that contains the Si₃O₉⁶⁻ trimers.
- Uranium silicate,
- Uranium germanate,
- Framework,
- Single crystal,
- Molten salt method
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沈阳化工大学材料科学与工程学院沈阳 110142

Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K2USi3O9 and Cs2UGe3O9

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通讯作者: 陈斌, bchen63@163.com

Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K₂USi₃O₉ and Cs₂UGe₃O₉