Citation: Lei Xu, Wenya Ding, Anyun Zhang, Ziyang Liu. Effect of ligand initial conformation and counteranion on complexation behaviors of R-BTBP toward Pd(Ⅱ) contained in highly active liquid waste[J]. Chinese Chemical Letters, ;2022, 33(7): 3565-3569. doi: 10.1016/j.cclet.2022.02.074 shu

Effect of ligand initial conformation and counteranion on complexation behaviors of R-BTBP toward Pd(Ⅱ) contained in highly active liquid waste

Lei Xu ^{a, b} ,
Wenya Ding ^a ,
Anyun Zhang ^{b, *,} ,
Ziyang Liu ^c

a.
Key Laboratory of Nuclear Agricultural Sciences of Ministry of Agriculture and Zhejiang Province, Institute of Nuclear Agricultural Sciences, Zhejiang University, Hangzhou 310058, China
b.
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
c.
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, China

zhangay@zju.edu.cn

Received Date: 23 December 2021
Revised Date: 26 February 2022
Accepted Date: 26 February 2022
Available Online: 3 March 2022

Figures(6)

Soft N-donor bis-triazin bipyridines derives (R-BTBP) are a type of very promising extratant for extraction and complexation with long-lived trivalent minor actinides over lanthanides from highly active liquid waste (HLW). In addition to minor actinides, R-BTBP also holds very strong complexation ability toward fission palladium. However, few studies have been focused on the separation and complexation with the fission product Pd(Ⅱ) by R-BTBP. Herein, the complexation behaviors of Pd(Ⅱ) with four typical R-BTBP ligands were systematically studied by single crystal X-ray diffraction, ¹H NMR titration and theoretical calculation. The effects of R-BTBP initial conformation and nitrate anions on the complexation behaviors of R-BTBP with Pd(Ⅱ) were thoughtfully analyzed. Both the 1:1 and 2:1 binuclear complexes could be formed between Pd(Ⅱ) and R-BTBP with initial Ⅱ conformation in the presence of nitrate anions, while only one 1:1 type Pd(Ⅱ) complex could be formed for those with initial OO conformation. Without nitrate anion, only one 1:1 type complex was formed in solution. The structure of the 1:1 Pd(Ⅱ)/R-BTBP complex was firstly characterized by single crystal crystallography. DFT calculation results showed that a significant large rotational energy barrier (21.8~22.6 kcal/mol) must be overcome to form the Ⅱ type 2:1 Pd(Ⅱ) complex for those OO type R-BTBP ligands, however which would not prevent them from forming the 1:1 type complex.
- R-BTBP,
- Fission product palladium,
- Minor actinides,
- Complexation,
- Highly active liquid waste
1. [1]
  D.D. Sood, S.K. Patil, J. Radioanal. Nucl. Chem.203 (1996) 547–573. doi: 10.1007/BF02041529
2. [2]
  R.M. Sawant, R.K. Rastogi, N.K. Chaudhuri, J. Radioanal. Nucl. Chem. 229 (1998) 203–206. doi: 10.1007/BF02389477
3. [3]
  A. Wilden, C. Schreinemachers, M. Sypula, G. Modolo, Solvent Extr. Ion Exch. 31 (2013) 519–537. doi: 10.1080/07366299.2013.775890
4. [4]
  S. Taczanowski, Int. J. Energy Res. 24 (2000) 935–951. doi: 10.1002/1099-114X(200009)24:11<935::AID-ER633>3.0.CO;2-A
5. [5]
  P.J. Panak, A. Geist, Chem. Rev. 113 (2013) 1199–1236. doi: 10.1021/cr3003399
6. [6]
  Z. Kolarik, Chem. Rev. 108 (2008) 4208–4252. doi: 10.1021/cr078003i
7. [7]
  A. Zhang, G. Wanyan, M. Kumagai, Transit. Met. Chem. 29 (2004) 571–576. doi: 10.1023/B:TMCH.0000037532.41519.61
8. [8]
  L. Berthon, J. Morel, N. Zorz, et al., Sep. Sci. Technol. 36 (2001) 709–728. doi: 10.1081/SS-100103616
9. [9]
  S. Tachimori, Solvent Extr. Ion Exch. 20 (2002) 21–34. doi: 10.1081/SEI-100108822
10. [10]
  M. Wei, X. Liu, J. Chen, J. Radioanal. Nucl. Chem. 291 (2012) 717–723. doi: 10.1007/s10967-012-1623-3
11. [11]
  J.N. Mathur, M.S. Murali, P.R. Natarajan, et al., Waste Manag. (Oxford)13 (1993) 317–325. doi: 10.1016/0956-053X(93)90060-A
12. [12]
  D. Magnusson, B. Christiansen, M. Foreman, et al., J. Radioanal. Nucl. Chem. 27 (2009) 97–106. doi: 10.1080/07366290802672204
13. [13]
  Y. Zhu, J. Chen, R. Jiao, Solvent Extr. Ion Exch. 14 (1996) 61–68. doi: 10.1080/07366299608918326
14. [14]
  A. Zhang, C. Xiao, E. Kuraoka, M. Kumagai, J. Hazard. Mater. 147 (2007) 601–609. doi: 10.1016/j.jhazmat.2007.01.056
15. [15]
  A. Zhang, E. Kuraoka, H. Hoshi, M. Kumagai, J. Chromatogr. A1061 (2004) 175–182. doi: 10.1016/j.chroma.2004.11.023
16. [16]
  A. Afsar, L.M. Harwood, M.J. Hudson, P. Distler, J. John, Chem. Commun. 50 (2014) 15082–15085. doi: 10.1039/C4CC07478E
17. [17]
  M.J. Hudson, Czech. J. Phys. 53 (2003) A305–A311. doi: 10.1007/s10582-003-0039-2
18. [18]
  H.H. Dam, D.N. Reinhoudt, W. Verboom, Chem. Soc. Rev. 36 (2007) 367–377. doi: 10.1039/B603847F
19. [19]
  Z. Kolarik, U. Muellich, F. Gassner, Solvent Extr. Ion Exch. 17 (1999) 1155–1170. doi: 10.1080/07366299908934641
20. [20]
  S. Trumm, A. Geist, P.J. Panak, T. Fanghänel, Solvent Extr. Ion Exch. 29 (2011) 213–229. doi: 10.1080/07366299.2011.539129
21. [21]
  D.M. Whittaker, T.L. Griffiths, M. Helliwell, et al., Inorg. Chem. 52 (2013) 3429–3444. doi: 10.1021/ic301599y
22. [22]
  M.G. Drew, M.R. Foreman, C. Hill, M.J. Hudson, C. Madic, Inorg. Chem. Commun. 8 (2005) 239–241. doi: 10.1016/j.inoche.2004.12.017
23. [23]
  M. Nilsson, S. Andersson, F. Drouet, et al., Solvent Extr. Ion Exch. 24 (2006) 299–318. doi: 10.1080/07366290600646947
24. [24]
  M.J. Hudson, L.M. Harwood, D.M. Laventine, F.W. Lewis., Inorg. Chem. 52 (2012) 3414–3428.
25. [25]
  A. Wilden, G. Modolo, C. Schreinemachers, et al., Solvent Extr. Ion Exch. 31 (2013) 519–537. doi: 10.1080/07366299.2013.775890
26. [26]
  J.H. Lan, W.Q. Shi, L.Y. Yuan, et al., Inorg. Chem. 50 (2011) 9230–9237. doi: 10.1021/ic200078j
27. [27]
  F.W. Lewis, L.M. Harwood, M.J. Hudson, et al., J. Am. Chem. Soc. 133 (2011) 13093–13102. doi: 10.1021/ja203378m
28. [28]
  A. Afsar, D.M. Laventine, L.M. Harwood, M.J. Hudson, A. Geist, Chem. Commun. 49 (2013) 8534–8536. doi: 10.1039/c3cc45126g
29. [29]
  H. Wu, Q. Wu, C. Wang, et al., Dalton Trans. 45 (2016) 8107–8117. doi: 10.1039/C6DT00296J
30. [30]
  A. Zhang, L. Xu, G. Lei, New J. Chem. 40 (2016) 6374–6383. doi: 10.1039/C5NJ03082J
31. [31]
  C. Ekberg, I. Dubois, A. Fermvik, et al., Solvent Extr. Ion Exch. 25 (2007) 603–617. doi: 10.1080/07366290701512634
32. [32]
  E. Aneheim, B. Grüner, C. Ekberg, et al., Polyhedron50 (2012) 154–163.
33. [33]
  F.W. Lewis, L.M. Harwood, M.J. Hudson, et al., Eur. J. Org. Chem. 2012 (2012) 1509–1519. doi: 10.1002/ejoc.201101576
34. [34]
  H.J. Ache, L.H. Baetsle, R.P. Bust, et al., IAEA, Technical Report Series, 308 (1989), IAEA, Vienna.
35. [35]
  G.A. Jensen, A.M. Platt, G.B. Mellinger, W.J. Bjorklund, Trans. Am. Nucl. Soc. 43 (1984) 90–91.
36. [36]
  F.W. Lewis, L.M. Harwood, M.J. Hudson, U. Müllich, A. Geist, Chem. Commun. 51 (2015) 9189–9192. doi: 10.1039/C5CC02336J
37. [37]
  D. Magnusson, A. Geist, A. Wilden, G. Modolo, Solvent Extr. Ion Exch. 31 (2013) 1–11. doi: 10.1080/07366299.2012.700596
38. [38]
  M. Sypula, A. Wilden, C. Schreinemachers, et al., Solvent Extr. Ion Exch. 30 (2012) 748–764. doi: 10.1080/07366299.2012.700591
39. [39]
  A. Zhang, W. Xue, AlChE J. 58 (2012) 3517–3525. doi: 10.1002/aic.13741
40. [40]
  A. Zhang, Y. Zhu, Y. Liu, Z. Chai, Ind. Eng. Chem. Res. 50 (2011) 6898–6905. doi: 10.1021/ie1021893
41. [41]
  L. Xu, A. Zhang, F. Zhang, J. Liu, J. Hazard. Mater. 337 (2017) 178–188. doi: 10.1016/j.jhazmat.2017.04.038
42. [42]
  A. Zhang, E. Kuraoka, M. Kumagai, J. Radioanal. Nucl. Chem. 274 (2007) 455–464. doi: 10.1007/s10967-006-6923-z
43. [43]
  Y. Lu, L. Xu, Y. Li, et al., Solvent Extr. Ion Exch. 36 (2017) 1–16.
44. [44]
  M.R.S. Foreman, M.J. Hudson, M.G.B. Drew, C. Hill, C. Madic, Dalton Trans. (2006) 1645–1653.
45. [45]
  Y. Fang, X. Yuan, L. Wu, et al., Chem. Commun. 20 (2015) 4263–4266. doi: 10.1039/C4CC09248A
46. [46]
  T.V. Laine, U. Piironen, K. Lappalainen, et al., J. Organomet. Chem. 606 (2000) 112–124.
47. [47]
  F.W. Lewis, L.M. Harwood, M.J. Hudson, et al., Plant Ecol. 80 (2009) 474–477.
48. [48]
  P. Castan, F. Dahan, S. Wimmer, F.L. Wimmer, J. Chem. Soc., Dalton Trans. 21 (1990) 2679–2683.
49. [49]
  L. Xu, A. Zhang, N. Pu, et al., New J. Chem. 43 (2019) 9052–9065. doi: 10.1039/c9nj00343f
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