Citation: Heshan Zheng, Yunying Hou, Shuo Li, Jun Ma, Jun Nan, Nannan Wang. Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation[J]. Chinese Chemical Letters, ;2023, 34(1): 107253. doi: 10.1016/j.cclet.2022.02.058 shu

Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation

Heshan Zheng ^a ,
Yunying Hou ^a ,
Shuo Li ^{a, b, c, **,} ,
Jun Ma ^{a, b} ,
Jun Nan ^{b, c} ,
Nannan Wang ^{d, *,}

a.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
b.
Urban Water Resources Development and Northern National Engineering Research Center, Harbin 150090, China
c.
School of Environment, Harbin Institute of Technology, Harbin 150090, China
d.
Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China

^**

shuo_105@163.com

wnn_flying@163.com

Received Date: 2 December 2021
Revised Date: 19 January 2022
Accepted Date: 20 February 2022
Available Online: 23 February 2022

Figures(4)

This study explored the catalytic mechanism and performance impacted by the materials ratio of Fe₃O₄-GO_x composites in three typical advanced oxidation processes (AOPs) of O₃, peroxodisulfate (PDS) and photo-Fenton processes for tetracycline hydrochloride (TCH) degradation. The ratio of GO in the Fe₃O₄-GO_x composites exhibited different trends of degradation capacity in each AOPs based on different mechanisms. Fe₃O₄-rGO_20wt% exhibited the optimum catalytic performance which enhanced the ozone decomposition efficiency from 33.48% (ozone alone) to 51.83% with the major reactive oxygen species (ROS) of O₂^•−. In PDS and photo-Fenton processes, Fe₃O₄-rGO_5wt% had the highest catalytic performance in PDS and H₂O₂ decomposition for SO₄^•‒, and ^•OH generation, respectively. Compared with using PDS alone, PDS decomposition rate and TCH degradation rate could be increased by 5.97 and 1.73 times under Fe₃O₄-rGO_5wt% catalysis. In the photo-Fenton system, Fe₃O₄-rGO_5wt% with the best catalyst performance in H₂O₂ decomposition, and TCH degradation rate increased by 2.02 times compared with blank group. Meantime, the catalytic mechanisms in those systems of that the ROS produced by conversion between Fe²⁺/Fe³⁺ were also analyzed.
- Advanced oxidation progresses,
- Fe₃O₄,
- Graphene oxide,
- Mechanism,
- Reactive oxygen species
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沈阳化工大学材料科学与工程学院沈阳 110142

Study on catalytic mechanisms of Fe3O4-rGOx in three typical advanced oxidation processes for tetracycline hydrochloride degradation

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通讯作者: 陈斌, bchen63@163.com

Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation