Citation: Jiayuan Zhang, Xinyu Wang, Gui Wang, Yi Feng, Chunhui Zhang, Tao Pang, Guanggang Gao, Linlin Fan, Hong Liu. Ultrasensitive photochromism and impedance dual response to weak visible light by solvated Pb(II) modified polyoxomolybdate[J]. Chinese Chemical Letters, ;2023, 34(2): 107231. doi: 10.1016/j.cclet.2022.02.036 shu

Ultrasensitive photochromism and impedance dual response to weak visible light by solvated Pb(II) modified polyoxomolybdate

Jiayuan Zhang ^{a, b} ,
Xinyu Wang ^{a, b} ,
Gui Wang ^a ,
Yi Feng ^a ,
Chunhui Zhang ^a ,
Tao Pang ^b ,
Guanggang Gao ^{a, *,} ,
Linlin Fan ^a ,
Hong Liu ^{a, *,}

a.
School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
b.
College of Pharmacy, Jiamusi University, Jiamusi 154007, China

mse_gaogg@ujn.edu.cn

mse_liuh@ujn.edu.cn

Received Date: 9 December 2021
Revised Date: 31 December 2021
Accepted Date: 15 February 2022
Available Online: 18 February 2022

Figures(4)

Polyoxometalates (POMs) are important inorganic photochromic materials to be potentially applied in photo-induced switch, energy storage, and even the detection of light. However, due to the limited sensitivity of POMs, it is difficult to realize the photochromic response to weak visible light. In this paper, by the coordination of solvated Pb(II), a new structure-defined chain-like polyoxomolybdate complex of [(Pb(DMF)₄)₃(P₂Mo₁₈O₆₂)₂]_n (Pb₃Mo₁₈, DMF = dimethylformamide) has been demonstrated by a facile solvent-diffusion approach. By virtue of interactions between Pb(DMF)₄ and polyoxoanions, Pb₃Mo₁₈ shows an ultrasensitive photochromic response to weak visible lights and forms the reduced 'heteropoly blue' species through ligand-to-metal charge transfer (LMCT) process. A new mechanism is firstly proposed here that the 6s orbital lone electron pair on Pb(II) can effectively stabilize the generated hole of oxygen atoms as a result of O→Mo charge transfer. Through the proposed mechanism, the LMCT barrier is drastically lowered and allows the coloration to be occurred even upon weak visible light. Also, because the conductivity of Pb₃Mo₁₈ enhances with the increase of reduction extent, its electrochemical impedance signals are proportionally response to irradiation intensity. Especially, for the first time, the polyoxomolybdate composite can be used to detect weak visible light, in which the optical signal can be converted into electrical signal output. Moreover, Pb₃Mo₁₈ can be drip-coated on the surface of the screen printed chip electrode, which is facile to the detection of light by portable devices compatible with computers, mobile phones and other electronic equipment. This work not only highlights a new approach to the molecular design of photochromic POMs by the coordination of metal ions with the effect of inert electron pair, but also lays a foundation to extend the application of POMs as light signal sensors.
- Photochromism,
- Polyoxometalate,
- Impedance,
- Visible light,
- Screen printed chip
1. [1]
  C.B. Fan, L. Le Gong, L. Huang, et al., Angew. Chem. Int. Ed. 56 (2017) 7900–7906. doi: 10.1002/anie.201702484
2. [2]
  R. Pardo, M. Zayat, D. Levy, Chem. Soc. Rev. 40 (2011) 672–687. doi: 10.1039/c0cs00065e
3. [3]
  Y. Qi, W. Niu, S. Zhang, et al., ACS Appl. Mater. Interfaces 12 (2020) 9664–9672. doi: 10.1021/acsami.9b21947
4. [4]
  L. Li, J.R. Wang, Y. Hua, et al., J. Mater. Chem. C 7 (2019) 38–42. doi: 10.1039/c8tc03172j
5. [5]
  Q. Li, W.J. Wei, Z.Z. Xue, et al., Chin. Chem. Lett. 33 (2022) 3203–3206. doi: 10.1016/j.cclet.2021.10.015
6. [6]
  Y. Yang, J. Xu, Y. Li, G. Gao, J. Mater. Chem. C 7 (2019) 12518–12522. doi: 10.1039/c9tc04505h
7. [7]
  G. Ligorio, G.F. Cotella, A. Bonasera, et al., Nanoscale 12 (2020) 5444–5451. doi: 10.1039/d0nr00724b
8. [8]
  Y.Y. Liu, Q.C. Peng, Y.Y. Li, H.W. Hou, K. Li, Chin. Chem. Lett. 31 (2020) 3271–3275. doi: 10.1016/j.cclet.2020.05.007
9. [9]
  Z. Li, G. Wang, Y. Ye, et al., Angew. Chem. Int. Ed. 58 (2019) 18025–18031. doi: 10.1002/anie.201910467
10. [10]
  O. Sato, J. Tao, Y.Z. Zhang, Angew. Chem. Int. Ed. 46 (2007) 2152–2187. doi: 10.1002/anie.200602205
11. [11]
  H.L. Zhang, J.Z. Liao, W. Yang, X.Y. Wu, C.Z. Lu, Dalton Trans. 46 (2017) 4898–4901. doi: 10.1039/C7DT00631D
12. [12]
  K. Tandekar, S. Garai, S. Supriya, Chem. Eur. J. 24 (2018) 9747–9753. doi: 10.1002/chem.201801126
13. [13]
  K. Tandekar, N.K. Mishra, S. Supriya, Dalton Trans. 50 (2021) 6146–6151. doi: 10.1039/d1dt00628b
14. [14]
  L. Deng, X. Dong, Z.H. Zhou, Chem. Eur. J. 27 (2021) 9643–9653. doi: 10.1002/chem.202100745
15. [15]
  D. Gedamu, I. Paulowicz, S. Kaps, et al., Adv. Mater. 26 (2014) 1541–1550. doi: 10.1002/adma.201304363
16. [16]
  X. Fang, Y. Bando, M. Liao, et al., Adv. Mater. 21 (2009) 2034–2039. doi: 10.1002/adma.200802441
17. [17]
  J.D. Prades, R. Jimenez-Diaz, F. Hernandez-Ramirez, et al., Sens. Actuator. B: Chem. 140 (2009) 337–341. doi: 10.1016/j.snb.2009.04.070
18. [18]
  L. Li, Y.C. Zou, Y. Hua, et al., Dalton Trans. 49 (2020) 89–94. doi: 10.1039/c9dt04116h
19. [19]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
20. [20]
  M.L. Sun, Y.R. Wang, W.W. He, et al., Small 17 (2021) 2100762. doi: 10.1002/smll.202100762
21. [21]
  S.L. Xie, J. Liu, L.Z. Dong, et al., Chem. Sci. 10 (2019) 185–190. doi: 10.1039/c8sc03471k
22. [22]
  C.H. Shan, H. Zhang, W.L. Chen, Z.M. Su, E.B. Wang, J. Mater. Chem. A 4 (2016) 3297–3303. doi: 10.1039/C5TA10601J
23. [23]
  Z. Li, X.X. Li, T. Yang, Z.W. Cai, S.T. Zheng, Angew. Chem. Int. Ed. 56 (2017) 2664–2669. doi: 10.1002/anie.201612046
24. [24]
  L.Z. Qiao, M. Song, A.F. Geng, S. Yao, Chin. Chem. Lett. 30 (2019) 1273–1276. doi: 10.1016/j.cclet.2019.01.024
25. [25]
  D.F. Shen, S. Li, H. Liu, et al., J. Mater. Chem. C 3 (2015) 12090–12097. doi: 10.1039/C5TC03270A
26. [26]
  N. Zhang, L.Y. Hong, A.F. Geng, et al., Chin. Chem. Lett. 29 (2018) 1409–1412. doi: 10.1016/j.cclet.2017.12.003
27. [27]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
28. [28]
  L.L. Liu, J. Jiang, G.P. Liu, et al., ACS Appl. Mater. Interfaces 13 (2021) 35997–36010. doi: 10.1021/acsami.1c10012
29. [29]
  K. Yang, Y.X. Ying, L.L. Cui, et al., Energy Stor. Mater. 34 (2021) 203–210.
30. [30]
  K. Yang, Y.Y. Hu, L.Y. Li, et al., Nano Energy 74 (2020) 104851. doi: 10.1016/j.nanoen.2020.104851
31. [31]
  Y.R. Huang, X.L. Lin, B. Chen, et al., Angew. Chem. Int. Ed. 60 (2021) 16911–16916. doi: 10.1002/anie.202104333
32. [32]
  S. Zhang, X. Wang, H.X. Zhang, Z.H. Zhao, X.L. Wang, Chin. Chem. Lett. 29 (2018) 309–312. doi: 10.1016/j.cclet.2017.08.044
33. [33]
  X.X. Lu, Y.H. Luo, Y. Xu, H. Zhang, CrystEngComm 17 (2015) 1631–1636. doi: 10.1039/C4CE02211D
34. [34]
  G.P. Yang, Y.F. Liu, K. Li, et al., Chin. Chem. Lett. 31 (2020) 3233–3236. doi: 10.1016/j.cclet.2020.07.018
35. [35]
  T. He, J. Yao, J. Mater. Chem. 17 (2007) 4547–4557. doi: 10.1039/b709380b
36. [36]
  Y. Wei, B. Han, Z. Dong, W. Feng, J. Mater. Sci. Technol. 35 (2019) 1951–1958. doi: 10.1016/j.jmst.2019.05.014
37. [37]
  D.L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 36 (2007) 105–121. doi: 10.1039/B502666K
38. [38]
  H. Zhang, L.Y. Duan, Y. Lan, E.B. Wang, C.W. Hu, Inorg. Chem. 42 (2003) 8053–8058. doi: 10.1021/ic0343962
39. [39]
  L. Li, Y. Hua, Y. Guo, et al., Eur. J. Inorg. Chem. 2018 (2018) 3757–3760. doi: 10.1002/ejic.201800671
40. [40]
  X. Cao, Z. Chen, R. Lin, et al., Nat. Catal. 1 (2018) 704–710. doi: 10.1038/s41929-018-0128-z
41. [41]
  H. Liu, Y. Lv, S. Li, et al., J. Mater. Chem. C 5 (2017) 9383–9388. doi: 10.1039/C7TC01263B
42. [42]
  P. Mialane, G. Zhang, I.M. Mbomekalle, et al., Chem. Eur. J. 16 (2010) 5572–5576. doi: 10.1002/chem.201000062
43. [43]
  S.F. Wang, W.R. Fan, Z.C. Liu, A.B. Yu, X.C. Jiang, J. Mater. Chem. C 6 (2018) 191–212. doi: 10.1039/C7TC04189F
44. [44]
  A. Dolbecq, E. Dumas, C.R. Mayer, P. Mialane, Chem. Rev. 110 (2010) 6009–6048. doi: 10.1021/cr1000578
45. [45]
  Z.H. Gong, L. Shi, X.M. Gao, et al., J. Mol. Struct. 1206 (2020) 127716. doi: 10.1016/j.molstruc.2020.127716
46. [46]
  Y. Duan, J.C. Waerenborgh, J.M. Clemente-Juan, C. Giménez-Saiz, E. Coronado, Chem. Sci. 8 (2017) 305–315. doi: 10.1039/C6SC01919F
47. [47]
  H. Dridi, A. Boulmier, P. Bolle, et al., J. Mater. Chem. C 8 (2020) 637–649. doi: 10.1039/c9tc05906g
48. [48]
  M. Sánchez, A. González, L. Sabio, et al., Mater. Today Chem. 21 (2021) 100491. doi: 10.1016/j.mtchem.2021.100491
49. [49]
  T. Yamase, Chem. Rev. 98 (1998) 307–325. doi: 10.1021/cr9604043
50. [50]
  K. Hakouk, O. Oms, A. Dolbecq, et al., Inorg. Chem. 52 (2013) 555–557. doi: 10.1021/ic302477p
51. [51]
  C.R. Mayer, V. Cabuil, T. Lalot, R. Thouvenot, Angew. Chem. Int. Ed. 38 (1999) 3672–3675. doi: 10.1002/(SICI)1521-3773(19991216)38:24<3672::AID-ANIE3672>3.0.CO;2-#
52. [52]
  H. El Moll, W. Zhu, E. Oldfield, et al., Inorg. Chem. 51 (2012) 7921–7931. doi: 10.1021/ic3010079
53. [53]
  C.L. Hill, D.A. Bouchard, J. Am. Chem. Soc. 107 (1985) 5148–5157. doi: 10.1021/ja00304a019
54. [54]
  J.Z. Liao, C. Wu, X.Y. Wu, S.Q. Deng, C.Z. Lu, Chem. Commun. 52 (2016) 7394–7397. doi: 10.1039/C6CC02711C
55. [55]
  X. Lopez, C. Bo, J.M. Poblet, Inorg. Chem. 42 (2003) 2634–2638. doi: 10.1021/ic0262280
56. [56]
  L.I. Udalova, S.A. Adonin, P.A. Abramov, et al., New J. Chem. 40 (2016) 9981–9985. doi: 10.1039/C6NJ02155G
57. [57]
  R. Dessapt, M. Collet, V. Coue, et al., Inorg. Chem. 48 (2009) 574–580. doi: 10.1021/ic8013865
58. [58]
  J.J. Liu, Y. Wang, M.J. Lin, C.C. Huang, W.X. Dai, Dalton Trans. 44 (2015) 484–487. doi: 10.1039/C4DT03029J
59. [59]
  L. Shimoni-Livny, J.P. Glusker, C.W. Bock, Inorg. Chem. 37 (1998) 1853–1867. doi: 10.1021/ic970909r
1. [1]
  Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
2. [2]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
3. [3]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
4. [4]
  Lei Shen , Yang Zhang , Linlin Zhang , Chuanwang Liu , Zhixian Ma , Kangjiang Liang , Chengfeng Xia . Phenylhydrazone anions excitation for the photochemical carbonylation of aryl iodides with aldehydes. Chinese Chemical Letters, 2024, 35(4): 108742-. doi: 10.1016/j.cclet.2023.108742
5. [5]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
6. [6]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
7. [7]
  Tian-Yu Gao , Xiao-Yan Mo , Shu-Rong Zhang , Yuan-Xu Jiang , Shu-Ping Luo , Jian-Heng Ye , Da-Gang Yu . Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO₂. Chinese Chemical Letters, 2024, 35(7): 109364-. doi: 10.1016/j.cclet.2023.109364
8. [8]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
9. [9]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
10. [10]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
11. [11]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
12. [12]
  Qiongqiong Wan , Yanan Xiao , Guifang Feng , Xin Dong , Wenjing Nie , Ming Gao , Qingtao Meng , Suming Chen . Visible-light-activated aziridination reaction enables simultaneous resolving of C=C bond location and the sn-position isomers in lipids. Chinese Chemical Letters, 2024, 35(4): 108775-. doi: 10.1016/j.cclet.2023.108775
13. [13]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
14. [14]
  Weiwei He , Hongbo Zhang , Xudong Lin , Lili Zhu , Tingting Zheng , Hao Pei , Yang Tian , Min Zhang , Guoyue Shi , Lei Wu , Jianlong Zhao , Gulinuer Wumaier , Shengqing Li , Yufang Xu , Honglin Li , Xuhong Qian . Advancements in life-on-a-chip: The impact of "Beyond Limits Manufacturing" technology. Chinese Chemical Letters, 2024, 35(5): 109091-. doi: 10.1016/j.cclet.2023.109091
15. [15]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
16. [16]
  Meihui Liu , Xinyuan Zhou , Xiao Li , Zhenjie Xue , Tie Wang . Pushing the frontiers: Chip-based detection based on micro- and nano-structures. Chinese Chemical Letters, 2024, 35(4): 108875-. doi: 10.1016/j.cclet.2023.108875
17. [17]
  Dong-Sheng Deng , Su-Qin Tang , Yong-Tu Yuan , Ding-Xiong Xie , Zhi-Yuan Zhu , Yue-Mei Huang , Yun-Lin Liu . C-F insertion reaction sheds new light on the construction of fluorinated compounds. Chinese Chemical Letters, 2024, 35(8): 109417-. doi: 10.1016/j.cclet.2023.109417
18. [18]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
19. [19]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
20. [20]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(435)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142