Citation: Zhihao Zhu, Peng Liu, Yucheng Liu, Xingxing Gu, Zhi Su, Zhong Su, Chao Lai. Defect-rich and highly porous carbon nanosheets derived from Ti₃AlC₂ MAX with good lithium storage properties[J]. Chinese Chemical Letters, ;2023, 34(2): 107228. doi: 10.1016/j.cclet.2022.02.033 shu

Defect-rich and highly porous carbon nanosheets derived from Ti₃AlC₂ MAX with good lithium storage properties

Zhihao Zhu ^{a, b} ,
Peng Liu ^b ,
Yucheng Liu ^b ,
Xingxing Gu ^{c, d, *,} ,
Zhi Su ^{a, *,} ,
Zhong Su ^{b, *,} ,
Chao Lai ^b

a.
College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi 830054, China
b.
School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou 221116, China
c.
Chongqing Key Laboratory of Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China
d.
National Research Base of Intelligent Manufacturing Service, Chongqing Technology and Business University, Chongqing 400067, China

x.gu@ctbu.edu.cn

suzhi@sina.com

suzhongjs@163.com

Received Date: 23 January 2022
Revised Date: 13 February 2022
Accepted Date: 16 February 2022
Available Online: 18 February 2022

Figures(8)

Defect-rich, highly porous two-dimensional carbon nanosheets (CNS) have attracted tremendous research interests in catalysis and environmental purification and other fields, because of their unique micromorphology, chemical stability and high specific surface area. Herein, in this work, we report a new solution to synthesize an ultrathin two-dimensional CNS with rich defects and abundant pores via two-step etching the Ti₃AlC₂ with the help of I₂ and NaOH. The CNS thickness, specific surface area and pore volume could be all tunable by adding the amount of I₂. And the highest specific surface area and pore volume of the synthesized 2D CNS can be achieved 1134.4 m²/g and 0.80 cm³/g, with a thickness of only 0.64 nm and a yield of 35.9%. When employed as the anodes for lithium-ion batteries, the synthesized CNS anodes exhibit good cycling and rate capabilities. This work provides a novel and facile strategy for synthesizing highly porous and defective 2D carbon materials with good lithium storage properties.
- Ti₃AlC₂,
- Two-dimensional,
- Carbon nanosheets,
- Rich defect,
- High specific surface area
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沈阳化工大学材料科学与工程学院沈阳 110142

Defect-rich and highly porous carbon nanosheets derived from Ti3AlC2 MAX with good lithium storage properties

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通讯作者: 陈斌, bchen63@163.com

Defect-rich and highly porous carbon nanosheets derived from Ti₃AlC₂ MAX with good lithium storage properties