Citation: Lixia Lu, Xinyu Shao, Xiaoxiao Lin, Linhe Ding, Bingchan Song, Jian Sun. Tb³⁺-xylenol orange complex-based colorimetric and luminometric dual-readout sensing platform for dipicolinic acid and metal ions[J]. Chinese Chemical Letters, ;2023, 34(1): 107203. doi: 10.1016/j.cclet.2022.02.009 shu

Tb³⁺-xylenol orange complex-based colorimetric and luminometric dual-readout sensing platform for dipicolinic acid and metal ions

Lixia Lu ^{a, *,} ,
Xinyu Shao ^a ,
Xiaoxiao Lin ^a ,
Linhe Ding ^a ,
Bingchan Song ^a ,
Jian Sun ^{b, *,}

a.
Shandong Provincial Key Laboratory of Animal Resistance Biology, Institute of Biomedical Sciences, Key Laboratory of Food Nutrition and Safety of Shandong Normal University, College of Life Science, Shandong Normal University, Ji′nan 250014, China
b.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

lulixia@sdnu.edu.cn

jiansun@ciac.ac.cn

Received Date: 6 December 2021
Revised Date: 9 January 2022
Accepted Date: 7 February 2022
Available Online: 9 February 2022

Figures(5)

A dual-readout sensing platform based on two signal transduction channels can integrate the unique advantages of each sensing pattern, compensate for the deficiency in the adaptive capacity, and enable a more convincing performance in analytical applications. Here, we introduce a responsive molecule dye, xylenol orange (XO), to combine with lanthanide terbium ions (Tb³⁺). The resultant Tb³⁺-XO complex exhibited tunable optical properties and was used as a novel colorimetric and luminometric dual-readout sensing platform for assaying the anthrax biomarker, dipicolinic acid (DPA). In the presence of Tb³⁺, the XO solution underwent a color change from yellow to magenta; however, upon adding DPA, the color changed back to yellow immediately, accompanied by the characteristic luminescence emission of Tb³⁺. Considering the strong affinity between DPA/XO and metal ions, the proposed sensing platform was further employed for the determination and differentiation of certain metal ions using linear discriminant analysis. This convenient dual-readout sensing platform offers several notable features and significantly promotes the application and development of lanthanide-based materials.
- Lanthanide complex,
- Xylenol orange,
- Bacillus anthracis,
- Multiple detection,
- Linear discriminant analysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Tb3+-xylenol orange complex-based colorimetric and luminometric dual-readout sensing platform for dipicolinic acid and metal ions

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通讯作者: 陈斌, bchen63@163.com

Tb³⁺-xylenol orange complex-based colorimetric and luminometric dual-readout sensing platform for dipicolinic acid and metal ions