Citation: Fang Guo, Junqiang Guo, Zhiqiang Zheng, Tao Xia, Aadil Nabi Chishti, Liwei Lin, Wang Zhang, Guowang Diao. Polymerization of pyrrole induced by pillar[5]arene functionalized graphene for supercapacitor electrode[J]. Chinese Chemical Letters, ;2022, 33(11): 4846-4849. doi: 10.1016/j.cclet.2022.01.088 shu

Polymerization of pyrrole induced by pillar[5]arene functionalized graphene for supercapacitor electrode

Fang Guo ^a ,
Junqiang Guo ^a ,
Zhiqiang Zheng ^a ,
Tao Xia ^a ,
Aadil Nabi Chishti ^a ,
Liwei Lin ^a ,
Wang Zhang ^{a, b, *,} ,
Guowang Diao ^a

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
b.
Department of Applied Bioengineering, Graduate School of Convergence Science and Technology, Seoul National University, Suwon 443-270, South Korea

zhangwang@yzu.edu.cn

Received Date: 21 October 2021
Revised Date: 25 January 2022
Accepted Date: 27 January 2022
Available Online: 14 February 2022

Figures(3)

Conducting polymer is an important electrode material for supercapacitors because of its high initial specific capacitance. Herein, a novel nanocomposite composed of polypyrrole (PPy) film homogeneously immobilized on the pillar[5]arene functionalized reduced graphene oxide nanosheets (RGO-HP5A-PPy) was successfully prepared. RGO-HP5A induced pyrrole to polymerize on the graphene surface and the specific capacitance loss caused by PPy agglomeration was avoided. Noticeably, the specific capacitance of RGO-HP5A-PPy was up to 495 F/g at 1 A/g. Compared with pure PPy (319 F/g), the specific capacitance was increased by 55%. The specific capacitance retention of the assembled symmetric supercapacitor reached 76% after 10,000 cycles at 5 A/g. This study gave full play to the advantages of pillar[5]arene, graphene and PPy, and was expected to promote the development of supramolecular functionalized composites in energy storage.
- Nanocomposite,
- Pillar[5]arene,
- Graphene,
- Polypyrrole,
- Supercapacitor
1. [1]
  R.R. Salunkhe, Y.H. Lee, K.H. Chang, Chem. Eur. J. 20 (2014) 13838–13852. doi: 10.1002/chem.201403649
2. [2]
  J.R. Miller, P. Simon, Science 321 (2008) 651–652. doi: 10.1126/science.1158736
3. [3]
  L. Lyu, K. Seong, D. Ko, et al., Mater. Chem. Front. 3 (2019) 2543–2570. doi: 10.1039/C9QM00348G
4. [4]
  M.L. Wang, T.Y. Zhang, M.Z. Cui, et al., Chin. Chem. Lett. 32 (2021) 1111–1116. doi: 10.1016/j.cclet.2020.08.026
5. [5]
  Q.F. Meng, K.F. Cai, Y.X. Chen, et al., Nano Energy 36 (2017) 268–285. doi: 10.1016/j.nanoen.2017.04.040
6. [6]
  Y.Q. Wang, Y. Ding, X.L. Guo, et al., Nano Res. 12 (2019) 1978–1987. doi: 10.1007/s12274-019-2296-9
7. [7]
  M.L. Wang, Y.F. Yu, M.Z. Cui, et al., Electrochim. Acta 329 (2020) 135181. doi: 10.1016/j.electacta.2019.135181
8. [8]
  P. Naskar, A. Maiti, P. Chakraborty, et al., J. Mater. Chem. A 9 (2021) 1970–2017. doi: 10.1039/D0TA09655E
9. [9]
  Y.Z. Zhao, Y.M. Cai, Y. Wang, et al., Sep. Purif. Technol. 259 (2021) 118175. doi: 10.1016/j.seppur.2020.118175
10. [10]
  H. Zhuo, Y.J. Hu, Z.H. Chen, et al., Carbohyd. Polym. 215 (2019) 322–329. doi: 10.1016/j.carbpol.2019.03.101
11. [11]
  A. Ehsani, A.A. Heidari, H.M. Shiri, Chem. Rec. 19 (2019) 908–926. doi: 10.1002/tcr.201800112
12. [12]
  I.J. Gómez, M.V. Sulleiro, D. Mantione, et al., Polymers (Basel) 13 (2021) 745.
13. [13]
  R.B. Choudhary, S. Ansari, B. Purty, J. Energy Storage 29 (2020) 101302. doi: 10.1016/j.est.2020.101302
14. [14]
  R. Zhang, H. Pang, J. Energy Storage 33 (2021) 102037. doi: 10.1016/j.est.2020.102037
15. [15]
  J.H. Zhao, J.P. Wu, B. Li, et al., Prog. Nat. Sci. 26 (2016) 237–242. doi: 10.1016/j.pnsc.2016.05.015
16. [16]
  T.F. Yi, L.Y. Qiu, J. Mei, et al., Sci. Bull. 65 (2020) 546–556. doi: 10.1016/j.scib.2020.01.011
17. [17]
  B.C. Kim, J.Y. Hong, G.G. Wallace, et al., Adv. Energy Mat. 5 (2015) 1500959. doi: 10.1002/aenm.201500959
18. [18]
  L.B. Ni, W. Zhang, Z. Wu, et al., Appl. Surf. Sci. 396 (2017) 412–420. doi: 10.1016/j.apsusc.2016.10.168
19. [19]
  B. Wang, T.T. Ruan, Y. Chen, et al., Energy Storage Mater 24 (2020) 22–51. doi: 10.1016/j.ensm.2019.08.004
20. [20]
  D. Nandi, V.B. Mohan, A.K. Bhowmick, et al., J. Mater. Sci. 55 (2020) 6375–6400. doi: 10.1007/s10853-020-04475-z
21. [21]
  Ni L. B, G. Yang, C.Y. Sun, et al., Mater. Today Energy 6 (2017) 53–64. doi: 10.1016/j.mtener.2017.08.005
22. [22]
  A.G. Olabi, M.A. Abdelkareem, T. Wilberforce, et al., Renew. Sust. Energ. Rev. 135 (2021) 110026. doi: 10.1016/j.rser.2020.110026
23. [23]
  M.L. He, L.J. Chen, B. Jiang, et al., Chin. Chem. Lett. 30 (2019) 131–134. doi: 10.1016/j.cclet.2018.10.035
24. [24]
  Y. Han, C.Y. Nie, S. Jiang, et al., Chin. Chem. Lett. 31 (2020) 725–728. doi: 10.1016/j.cclet.2019.09.014
25. [25]
  Y. Cai, Z.C. Zhang, Y. Ding, et al., Chin. Chem. Lett. 32 (2021) 1267–1279. doi: 10.1016/j.cclet.2020.10.036
26. [26]
  C. Peng, W.T. Liang, J.C. Ji, et al., Chin. Chem. Lett. 32 (2021) 345–348. doi: 10.1016/j.cclet.2020.03.079
27. [27]
  J. Zhou, M. Chen, J. Xie, et al., ACS Appl. Mater. Interfaces 5 (2013) 11218–11224. doi: 10.1021/am403463p
28. [28]
  F. Guo, P. Xiao, B.Y. Yan, et al., Chem. Eng. J. 391 (2020) 123511. doi: 10.1016/j.cej.2019.123511
29. [29]
  Y. Gao, Nanoscale Res. Lett. 12 (2017) 387. doi: 10.1186/s11671-017-2150-5
30. [30]
  J.P. Wang, X. Li, X.F. Du, et al., Chem. Pap. 71 (2017) 293–316. doi: 10.1007/s11696-016-0048-9
31. [31]
  W.L. Wu, L.Q. Yang, S.L. Chen, et al., RSC Adv. 5 (2015) 91645–91653. doi: 10.1039/C5RA17036B
32. [32]
  S.Z. Xu, H.L. Hao, Y.N. Chen, et al., Nanotechnology 32 (2021) 305401. doi: 10.1088/1361-6528/abf9c4
33. [33]
  S. Kulandaivalu, N. Suhaimi, Y. Sulaiman, Sci. Rep. 9 (2019) 4884. doi: 10.1038/s41598-019-41203-3
34. [34]
  Y.K. Kim, K.Y. Shin, Appl. Surf. Sci. 547 (2021) 149141. doi: 10.1016/j.apsusc.2021.149141
35. [35]
  R. Montecinos, F. Diaz-Wilson, A. Bravo-Sepulveda, et al., J. Phys. Org. Chem. 32 (2019) e3889. doi: 10.1002/poc.3889
36. [36]
  W. Zhang, Y.Y. Kong, X.Z. Jin, et al., Electrochim. Acta 331 (2020) 135345. doi: 10.1016/j.electacta.2019.135345
37. [37]
  Y.Z. Fang, B.W. Yang, D.T. He, et al., Chin. Chem. Lett. 31 (2020) 1004–1008. doi: 10.1016/j.cclet.2019.08.043
38. [38]
  J.J. Jiang, X.Y. Lin, G.W. Diao, ACS Appl. Mater. Interfaces 3 (2017) 36688–36694.
39. [39]
  F.B. Ajdari, E. Kowsari, A. Ehsani, J. Solid State Chem. 265 (2018) 155–166. doi: 10.1016/j.jssc.2018.05.038
40. [40]
  F.B. Ajdari, E. Kowsari, A. Ehsani, et al., Electrochim. Acta 292 (2018) 789–804. doi: 10.1016/j.electacta.2018.09.177
41. [41]
  W. Zhang, X.Z. Jin, H. Chai, et al., Adv. Mater. Interfaces 5 (2018) 1800106. doi: 10.1002/admi.201800106
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6. [6]
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