Citation: Xingzi Zheng, Mengwei Yuan, Xianqiang Huang, Huifeng Li, Genban Sun. In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery[J]. Chinese Chemical Letters, ;2023, 34(1): 107152. doi: 10.1016/j.cclet.2022.01.045 shu

In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery

Xingzi Zheng ^a ,
Mengwei Yuan ^{a, c} ,
Xianqiang Huang ^b ,
Huifeng Li ^{a, *,} ,
Genban Sun ^a

a.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
b.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
c.
Department of Physics and Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China

lihuifeng@bnu.edu.cn

Received Date: 13 December 2021
Revised Date: 8 January 2022
Accepted Date: 16 January 2022
Available Online: 20 January 2022

Figures(4)

Application of Li-oxygen (Li-O₂) battery is in urgent need of bifunctional ORR/OER electrocatalyst. A surface-functionalization CoP/Ti₃C₂T_x composite was fabricated theoretically, with the optimized electronic structure and more active electron, which is beneficial to the electrochemical reaction. The accordion shaped Ti₃C₂T_x is featured with large specific surface area and outstanding electronic conductivity, which is beneficial for the adequate exposure of active sites and the deposition of Li₂O₂. Transition metal phosphides provide more electrocatalytic active sites and present good electrocatalytic effect. The CoP/Ti₃C₂T_x composite served as the electrocatalyst of Li-O₂ battery reaches a high specific discharge capacity of 17, 413 mAh/g at 100 mA/g and the lower overpotential of 1.25 V, superior to those of the CoP and Ti₃C₂T_x individually. The composite of transition metal phosphides and MXene are applied in Li-O₂ battery, not only demonstrating higher cycling stability of the prepared CoP/Ti₃C₂T_x composite, but pointing out the direction for their electrochemical performance improvement.
- MXene,
- Transition metal phosphide,
- Oxygen adsorption ability,
- Li-oxygen battery,
- Electrocatalyst
1. [1]
  Y.Y. Shao, F. Ding, J. Xiao, et al., Adv. Funct. Mater.23 (2013) 987–1004. doi: 10.1002/adfm.201200688
2. [2]
  A. Manthiram, L. Li, Adv. Energy Mater. 5 (2015) 1401302. doi: 10.1002/aenm.201401302
3. [3]
  C. Liu, K. Sato, X.B. Han, S. Ye, Curr. Opin. Electrochem. 14 (2019) 151–156. doi: 10.1016/j.coelec.2019.02.003
4. [4]
  S.A. Freunberger, Y.H. Chen, N.E. Drewett, et al., Angew. Chem. Int. Ed. 50 (2011) 8609–8613. doi: 10.1002/anie.201102357
5. [5]
  C.Z. Shu, J.Z. Wang, J.P. Long, H.K. Liu, S.X. Dou, Adv. Mater. 31 (2019) 43.
6. [6]
  M.W. Yuan, R. Wang, W.B. Fu, et al., ACS Appl. Mater. Interfeces 11 (2019) 11403–11413. doi: 10.1021/acsami.8b21808
7. [7]
  M.W. Yuan, S.T. Zhang, L. Lin, et al., ACS Sustain. Chem. Eng., 7 (2019) 17464–17473. doi: 10.1021/acssuschemeng.9b04674
8. [8]
  H.X. Yin, D.D. Li, Z.Z. Chi, et al., J. Mater. Chem. A9 (2021) 17865–17875. doi: 10.1039/d1ta04830a
9. [9]
  W. Zhao, X.M. Li, R. Yin, et al., Nanoscale 11 (2019) 50–59. doi: 10.1039/c8nr08457b
10. [10]
  W. Chen, Y.F. Gong, J.H. Liu, Chinese Chem. Lett. 28 (2017) 709–718. doi: 10.1016/j.cclet.2016.10.023
11. [11]
  M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, Adv. Mater. 26 (2014) 992–1005. doi: 10.1002/adma.201304138
12. [12]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23 (2011) 4248–4253. doi: 10.1002/adma.201102306
13. [13]
  M.R. Lukatskaya, O. Mashtalir, C.E. Ren, et al., Science 341 (2013) 1502–1505. doi: 10.1126/science.1241488
14. [14]
  L. Shi, Z. Li, Y.P. Li, et al., ACS Appl. Mater. Interfaces 13 (2021) 30766–30775. doi: 10.1021/acsami.1c08750
15. [15]
  Y.X. Min, H. Yuan, W.G. Wang, L. Xu, J. Phys. Chem. Lett. 12 (2021) 2742–2748. doi: 10.1021/acs.jpclett.1c00482
16. [16]
  Y.H. Liu, C.Y. Wang, S.L. Yang, F.F. Cao, H. Ye, J. Energy Chem. 66 (2022) 429–439. doi: 10.1016/j.jechem.2021.08.040
17. [17]
  R. Niu, R. Han, Y. Huang, et al., J. Alloy. Compd. 894 (2022) 162385. doi: 10.1016/j.jallcom.2021.162385
18. [18]
  Z.H. Liu, Y.H. Cui, Q. Li, Q.Y. Zhang, B.L. Zhang, J. Colloid Interface Sci. 607 (2022) 633–644. doi: 10.1016/j.jcis.2021.09.009
19. [19]
  X.Y. Li, C.Y. Wen, H.F. Li, G.B. Sun, J. Energy Chem. 47 (2020) 272–280. doi: 10.1016/j.jechem.2020.02.016
20. [20]
  C.Y. Wen, X.Z. Zheng, X.Y. Li, et al., Chem. Eng. J. 409 (2021) 12.
21. [21]
  X.Y. Li, C.Y. Wen, M.W. Yuan, et al., J. Alloy. Compd. 824 (2020) 9.
22. [22]
  C.Y. Wen, T.J. Zhu, X.Y. Li, et al., Chinese Chem. Lett. 31 (2020) 1000–1003. doi: 10.1016/j.cclet.2019.09.028
23. [23]
  M. Xu, N. Bai, H.X. Li, et al., Chinese Chem. Lett. 29 (2018) 1313–1316. doi: 10.1016/j.cclet.2018.04.023
24. [24]
  X. Zhang, J.W. Miao, P. Zhang, et al., Chinese Chem. Lett. 31 (2020) 2305–2308. doi: 10.1016/j.cclet.2020.03.040
25. [25]
  P. He, X.Y. Yu, X.W. Lou, Angew. Chem. Int. Ed. 56 (2017) 3897–3900. doi: 10.1002/anie.201612635
26. [26]
  A. Mendoza-Garcia, H.Y. Zhu, Y.S. Yu, et al., Angew. Chem. Int. Ed. 54 (2015) 9642–9645. doi: 10.1002/anie.201503386
27. [27]
  V.V.T. Doan-Nguyen, S. Zhang, E.B. Trigg, et al., ACS Nano 9 (2015) 8108–8115. doi: 10.1021/acsnano.5b02191
28. [28]
  Z.H. Yang, L. Liu, X.Y. Wang, S.Y. Yang, X.P. Su, J. Alloy. Compd. 509 (2011) 165–171. doi: 10.1016/j.jallcom.2010.09.018
29. [29]
  Y. Zhang, L. Gao, E.J.M. Hensen, J.P. Hofmann, ACS Energy Lett. 3 (2018) 1360–1365. doi: 10.1021/acsenergylett.8b00514
30. [30]
  Y. Li, B. Jia, B. Chen, et al., Dalton T. 47 (2018) 14679–14685. doi: 10.1039/c8dt02706d
31. [31]
  Y. Gong, W. Ding, Z. Li, et al., ACS Catal. 8 (2018) 4082–4090. doi: 10.1021/acscatal.7b04401
32. [32]
  M. Shekhirev, C.E. Shuck, A. Sarycheva, Y. Gogotsi, Prog. Mater. Sci. 120 (2021) 31.
33. [33]
  J.M. Luo, X.Y. Tao, J. Zhang, et al., ACS Nano 10 (2016) 2491–2499. doi: 10.1021/acsnano.5b07333
34. [34]
  T.E. Rosser, J.P.S. Sousa, Y. Ziouani, et al., Catal. Sci. Technol. 10 (2020) 2398–2406. doi: 10.1039/d0cy00123f
35. [35]
  F.H. Saadi, A.I. Carim, W.S. Drisdell, et al., J. Am. Chem. Soc. 139 (2017) 12927–12930. doi: 10.1021/jacs.7b07606
36. [36]
  S. Liu, Z. Lin, R. Wan, et al., J. Mater. Chem. A9 (2021) 21259–21269. doi: 10.1039/d1ta05648d
37. [37]
  F.L. Yang, Y.T. Chen, G.Z. Cheng, S.L. Chen, W. Luo, ACS Catal. 7 (2017) 3824–3831. doi: 10.1021/acscatal.7b00587
38. [38]
  N.C.S. Selvam, J. Lee, G.H. Choi, et al., J. Mater. Chem. A7 (2019) 27383–27393. doi: 10.1039/c9ta10664b
39. [39]
  J. Yan, C.E. Ren, K. Maleski, et al., Adv. Funct. Mater. 27 (2017) 10.
40. [40]
  M. Ghidiu, J. Halim, S. Kota, et al., Chem. Mater. 28 (2016) 3507–3514. doi: 10.1021/acs.chemmater.6b01275
41. [41]
  Y. Wang, Y.C. Lu, Energy Storage Mater. 28 (2020) 235–246. doi: 10.1016/j.ensm.2020.03.007
42. [42]
  P. Wang, C.X. Li, S.H. Dong, et al., Adv. Energy Mater. 9 (2019) 14.
1. [1]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
2. [2]
  Junan Pan , Xinyi Liu , Huachao Ji , Yanwei Zhu , Yanling Zhuang , Kang Chen , Ning Sun , Yongqi Liu , Yunchao Lei , Kun Wang , Bao Zang , Longlu Wang . The strategies to improve TMDs represented by MoS₂ electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(11): 109515-. doi: 10.1016/j.cclet.2024.109515
3. [3]
  Yi Zhou , Yanzhen Liu , Yani Yan , Zonglin Yi , Yongfeng Li , Cheng-Meng Chen . Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping. Chinese Chemical Letters, 2025, 36(1): 109569-. doi: 10.1016/j.cclet.2024.109569
4. [4]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
5. [5]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
6. [6]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
7. [7]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
8. [8]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
9. [9]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
10. [10]
  Juhong Zhou , Hui Zhao , Ping Han , Ziyue Wang , Yan Zhang , Xiaoxia Mao , Konglin Wu , Shengjue Deng , Wenxiang He , Binbin Jiang . Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst. Chinese Journal of Structural Chemistry, 2025, 44(1): 100470-100470. doi: 10.1016/j.cjsc.2024.100470
11. [11]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
12. [12]
  Jincheng Zhang , Mengjie Sun , Jiali Ren , Rui Zhang , Min Ma , Qingzhong Xue , Jian Tian . Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst. Chinese Chemical Letters, 2025, 36(1): 110491-. doi: 10.1016/j.cclet.2024.110491
13. [13]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
14. [14]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
15. [15]
  Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
16. [16]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
17. [17]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
18. [18]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2024.100210

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(663)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

In situ decoration of CoP/Ti3C2Tx composite as efficient electrocatalyst for Li-oxygen battery

Metrics

通讯作者: 陈斌, bchen63@163.com

In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery