Citation: Qian Zhao, Chong-Chen Wang, Peng Wang. Effective norfloxacin elimination via photo-Fenton process over the MIL-101(Fe)-NH₂ immobilized on α-Al₂O₃ sheet[J]. Chinese Chemical Letters, ;2022, 33(11): 4828-4833. doi: 10.1016/j.cclet.2022.01.033 shu

Effective norfloxacin elimination via photo-Fenton process over the MIL-101(Fe)-NH₂ immobilized on α-Al₂O₃ sheet

Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation/Beijing Energy Conservation & Sustainable Urban and Rural Development Provincial and Ministry Co-construction Collaboration Innovation Center, School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

chongchenwang@126.com

Received Date: 22 November 2021
Revised Date: 15 December 2021
Accepted Date: 13 January 2022
Available Online: 16 January 2022

Figures(4)

MIL-101(Fe)-NH₂@Al₂O₃ (MA) catalysts were successfully synthesized by reactive seeding (RS) method on α-Al₂O₃ substrate, which demonstrated excellent photo-Fenton degradation performance toward fluoroquinolone antibiotics (i.e., norfloxacin, ciprofloxacin, and enrofloxacin). The structure and morphology of the obtained MA were characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), atomic force microscope (AFM). The as-prepared MA could accomplish > 90% of norfloxacin degradation efficiency for 10 cycles' photo-Fenton processes, owing to its excellent chemical and water stability. In addition, the effects of operational factors including H₂O₂ concentration, foreign ions, and pH on the photo-Fenton degradation of norfloxacin over MA were clarified. The ESR spectra further document that ^•O₂⁻, ¹O₂ and ^•OH radicals are prominent in the decomposition process of antibiotic molecules. Finally, the plausible photo-Fenton norfloxacin degradation mechanisms were proposed and verified.
- MIL-101(Fe)-NH₂@Al₂O₃ (MA),
- Photo-Fenton,
- NOR,
- Mechanism,
- Real solar
1. [1]
  Y. Picó, V. Andreu, Anal. Bioanal. Chem. Res. 387 (2007) 1287–1299. doi: 10.1007/s00216-006-0843-1
2. [2]
  Y. Chen, T. Lan, L. Duan, et al., PLoS One 10 (2015) e0145025. doi: 10.1371/journal.pone.0145025
3. [3]
  M. Li, D. Wei, H. Zhao, et al., Chemosphere 95 (2014) 220–226. doi: 10.1016/j.chemosphere.2013.09.002
4. [4]
  Q. Zeng, S. Chang, M. Wang, et al., Chin. Chem. Lett. 32 (2021) 2212–2216. doi: 10.1016/j.cclet.2020.12.062
5. [5]
  J. Rivas, A. Encinas, F. Beltran, et al., J. Environ. Sci. Health A 46 (2011) 944–951. doi: 10.1080/10934529.2011.586249
6. [6]
  F. Li, Z. Wei, K. He, et al., Water Res. 185 (2020) 116219. doi: 10.1016/j.watres.2020.116219
7. [7]
  Y. Pi, J. Feng, M. Song, et al., Chin. Sci. Bull. 59 (2014) 2618–2624. doi: 10.1007/s11434-014-0293-7
8. [8]
  J.J. Pignatello, E. Oliveros, A. MacKay, Crit. Rev. Environ. Sci. Technol. 36 (2006) 1–84. doi: 10.1080/10643380500326564
9. [9]
  B. Ponnusami, K. Muthukumar, J. Environ. Chem. Eng. 2 (2014) 557–572. doi: 10.1016/j.jece.2013.10.011
10. [10]
  D. Wang, D. Astruc, Chem. Rev. 114 (2014) 6949–6985. doi: 10.1021/cr500134h
11. [11]
  D. Ma, S. Peh, H. Gang, et al., ACS Appl. Mater. Interfaces 9 (2017) 7523–7534. doi: 10.1021/acsami.6b14223
12. [12]
  H. Fu, C.C. Wang, W. Liu, Chin. Chem. Lett. 33 (2022) 1647–1649. doi: 10.1016/j.cclet.2021.08.065
13. [13]
  X.H. Yi, C.C. Wang, Prog. Chem. 3 (2021) 471–489.
14. [14]
  J. Huang, K. Li, L. Wang, et al., Chin. Chem. Lett. 33 (2022) 3787–3791. doi: 10.1016/j.cclet.2021.11.028
15. [15]
  D. Wang, R. Huang, W. Liu, et al., ACS Catal. 4 (2014) 4254–4260. doi: 10.1021/cs501169t
16. [16]
  Q. Wu, H. Yang, L. Kang, et al., Appl. Catal. B 263 (2020) 118282. doi: 10.1016/j.apcatb.2019.118282
17. [17]
  J. Maina, J. Schütz, L. Grundy, et al., ACS Appl. Mater. Interfaces 9 (2017) 35010–35017. doi: 10.1021/acsami.7b11150
18. [18]
  R. Molinari, T. Marino, A. Pietro, Int. J. Hydrogen Energy 39 (2014) 7247–7261. doi: 10.1016/j.ijhydene.2014.02.174
19. [19]
  Y. Liu, F. Liu, N. Ding, et al., Chin. Chem. Lett. 31 (2020) 2539–2548. doi: 10.1016/j.cclet.2020.03.011
20. [20]
  X.D. Du, X.H. Yi, P. Wang, et al., Chem. Eng. J. 356 (2019) 393–399. doi: 10.1016/j.cej.2018.09.084
21. [21]
  Q. Zhao, X.H. Yi, C.C. Wang, et al., Chem. Eng. J. 429 (2022) 132497. doi: 10.1016/j.cej.2021.132497
22. [22]
  Z. Zhang, X. Li, B. Liu, et al., RSC Adv. 6 (2015) 4289.
23. [23]
  M. Cheng, C. Lai, Y. Liu, et al., Coord. Chem. Rev. 368 (2018) 80–92. doi: 10.1016/j.ccr.2018.04.012
24. [24]
  H. Fu, X.X. Song, L. Wu, et al., Mater. Res. Bull. 125 (2020) 110806. doi: 10.1016/j.materresbull.2020.110806
25. [25]
  M. Xia, M. Long, Y. Yang, et al., Appl. Catal. B 110 (2011) 118–125. doi: 10.1016/j.apcatb.2011.08.033
26. [26]
  Q. Chen, P. Wu, Y. Li, et al., J. Hazard. Mater. 168 (2009) 901–908.
27. [27]
  X.H. Yi, H. Ji, C.C. Wang, et al., Appl. Catal. B 293 (2021) 120229. doi: 10.1016/j.apcatb.2021.120229
28. [28]
  F.X. Wang, C.C. Wang, X. Du, et al., Chem. Eng. J. 429 (2022) 132495. doi: 10.1016/j.cej.2021.132495
29. [29]
  X. Chen, R. Zhuan, J. Wang, et al., J. Hazard. Mater. 404 (2021) 124172.
30. [30]
  W. Liu, J. Zhang, C. Zhang, et al., Chem. Eng. J. 171 (2011) 431–438. doi: 10.1016/j.cej.2011.03.099
31. [31]
  V. Sharma, M. Feng, J. Hazard. Mater. 372 (2017) 3–16.
32. [32]
  J.M. Monteagudo, A. Durán, M.R. Martínez, et al., Chem. Eng. J. 380 (2020) 122410. doi: 10.1016/j.cej.2019.122410
33. [33]
  C.S. Bao, J. Zhao, Y.Y. Sun, et al., Environ. Sci. Nano 8 (2021) 2347–2359. doi: 10.1039/D1EN00250C
34. [34]
  H. Li, J. Chen, H. Hou, et al., Water Res. 126 (2017) 274–284. doi: 10.1016/j.watres.2017.09.001
35. [35]
  C. Wang, G. Yu, H. Chen, et al., Chemosphere 270 (2021) 129408. doi: 10.1016/j.chemosphere.2020.129408
36. [36]
  H. Chen, J.L. Wang, J. Hazard. Mater. 403 (2020) 123697.
37. [37]
  M.J. Chen, W. Chu, Appl. Catal. B 168-169 (2015) 175–182.
38. [38]
  M. Huang, T. Zhou, X. Wu, et al., Water Res. 119 (2017) 47–56. doi: 10.1016/j.watres.2017.03.008
39. [39]
  D. Ding, C. Liu, Y. Ji, et al., Chem. Eng. J. 308 (2017) 330–339. doi: 10.1016/j.cej.2016.09.077
40. [40]
  D. Yu, J. He, Z. Wang, et al., Chem. Eng. J. 417 (2021) 129240. doi: 10.1016/j.cej.2021.129240
41. [41]
  R. Yin, Y. Chen, S. He, et al., J. Hazard. Mater. 388 (2020) 121996. doi: 10.1016/j.jhazmat.2019.121996
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沈阳化工大学材料科学与工程学院沈阳 110142

Effective norfloxacin elimination via photo-Fenton process over the MIL-101(Fe)-NH2 immobilized on α-Al2O3 sheet

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通讯作者: 陈斌, bchen63@163.com

Effective norfloxacin elimination via photo-Fenton process over the MIL-101(Fe)-NH₂ immobilized on α-Al₂O₃ sheet