Citation: Yuxin Zeng, Siyao Zhang, Lifeng Yin, Yunrong Dai. Electrocatalytic degradation of pesticide micropollutants in water by high energy pulse magnetron sputtered Pt/Ti anode[J]. Chinese Chemical Letters, ;2022, 33(12): 5196-5199. doi: 10.1016/j.cclet.2022.01.031 shu

Electrocatalytic degradation of pesticide micropollutants in water by high energy pulse magnetron sputtered Pt/Ti anode

Yuxin Zeng ^a ,
Siyao Zhang ^a ,
Lifeng Yin ^{a, *,} ,
Yunrong Dai ^{b, *,}

a.
School of Environment, Beijing Normal University, Beijing 100875, China
b.
School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing 100083, China

lfyin@bnu.edu.cn

Daiyr@cugb.edu.cn

Received Date: 7 September 2021
Revised Date: 8 December 2021
Accepted Date: 13 January 2022
Available Online: 17 January 2022

Figures(4)

The increasing occurrence of pesticide micropollutants highlights the need for innovative water treatment technologies, particularly for small-community and household applications. Electro-oxidation is being widely studied in this area, unfortunately, safe, stable and efficient electrocatalytic anodes without released heavy metal ions are still highly required. In this study, we fabricated a Pt/Ti anode by high energy pulse magnetron sputtering (HiPIMS-PtTi) which was used to decompose dichlorvos (DDVP) and azoxystrobin (AZX) in water. The results show that the reaction rate constant (k_ENR) on HIPIMS was 35.7 min^–1 (DDVP) and 41.3 min^–1 (AZX), respectively, superior to electroplating Pt/Ti anode (EP-PtTi). The identification of radicals (^•OH, ¹O₂, ^•O₂⁻) and micro-area analyses evidenced that Pt atoms were embedded into the TiO₂ lattice on the surface of Ti plate by high-energy ions, which resulted in more adsorbed hydroxyls, and higher production of ^•OH under polarization conditions. Besides, the electro-oxidation intermediates of DDVP and AZX were identified and the degradation pathways were speculated: (1) indirect oxidation dominated by ^•OH attack, and (2) direct electron transfer reaction of pesticides on the anode surface. The cooperated reactions achieve the complete degradation and highly efficient mineralization of DDVP and AZX.
- Electrocatalysis,
- Magnetron sputtering,
- Pesticide,
- Degradation mechanism,
- Dichlorvos,
- Azoxystrobin
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