Citation: Yisa Xiao, Weichen Huang, Qilong Shen. Stereoselective formation of Z-monofluoroalkenes by nickel-catalyzed defluorinative coupling of gem-difluoroalkenes with lithium organoborates[J]. Chinese Chemical Letters, ;2022, 33(9): 4277-4280. doi: 10.1016/j.cclet.2022.01.020 shu

Stereoselective formation of Z-monofluoroalkenes by nickel-catalyzed defluorinative coupling of gem-difluoroalkenes with lithium organoborates

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China

shenql@mail.sioc.ac.cn

Received Date: 14 September 2021
Revised Date: 9 January 2022
Accepted Date: 9 January 2022
Available Online: 15 January 2022

Figures(4)

A method for stereoselective construction of Z-monofluoroalkenes by nickel-catalyzed defluorinative coupling of gem-difluoroalkenes in mild conditions was described. The combination of lithium organoborate and ZnBr₂ generated in situ lithium aryl zincates, which facilitates the transmetalation step of the nickel-catalyzed cross coupling reaction.
- gem-Difluoroalkenes,
- Lithium organoborate,
- Defluorination,
- Nickel,
- Coupling
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