Citation: Huafeng Li, Mengnan Yang, Zelong Yuan, Yahao Sun, Pengtao Ma, Jingyang Niu, Jingping Wang. Construction of one Ru₂W₁₂-cluster and six lacunary Keggin tungstoarsenate leading to the larger Ru-containing polyoxometalate photocatalyst[J]. Chinese Chemical Letters, ;2022, 33(10): 4664-4668. doi: 10.1016/j.cclet.2021.12.081 shu

Construction of one Ru₂W₁₂-cluster and six lacunary Keggin tungstoarsenate leading to the larger Ru-containing polyoxometalate photocatalyst

Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

jyniu@henu.edu.cn

jpwang@henu.edu.cn

Received Date: 30 November 2021
Revised Date: 23 December 2021
Accepted Date: 28 December 2021
Available Online: 4 January 2022

Figures(4)

Construction of two Ru^Ⅲ cations and six lacunary Keggin fragments resulted in a novel Ru₂W₁₂-cluster {(RuO₆)₂(WO₃)₁₂(H₂O)₁₂} bridged polyoxometalate, NaH₁₁[(RuO₆)(AsW₉O₃₃)₃{(W₆O₃)(H₂O)₆}]₂ 53H₂O (NaH₁₁·1·53H₂O), which represent the largest cluster in all the Ru-containing polyoxometalates. The most interesting characteristic is that the symmetry-related Ru₂W₁₂-cluster-based hexamers contain two windmill-shaped [(RuO₆)(AsW₉O₃₃)₃{(W₆O₃)(H₂O)₆}] trimers or the Ru₂W₁₂ cluster was tightly wrapped by six segments of B-β-AsW₉O₃₃. The other remarkable feature is that there have one intriguing cubane structure: which is composed of the Ru(1, 2) and W(1, 28, 50, 51, 52, 53) atoms. The oxygenation reactions of anilines to azoxybenzenes was evaluated when NaH₁₁·1·53H₂O served as effective catalyst by probing various reaction. The inherent redox property of oxygen-rich polyoxometalate surfaces and high photocatalytic activity of the Ru-containing metal cluster imbedded in NaH₁₁·1·53H₂O provide sufficient driving force for the photocatalytic transformation from anilines to azoxybenzenes. The oxidation of anilines can be realized with higher selectivity to afford various azoxybenzene compounds. The durability test shows that Ru-doping catalyst displays excellent chemical stability during the photocatalytic process.
- Ru-containing polyoxometalate,
- Photocatalyst,
- Oxidation,
- Azoxy compounds,
- Durability
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Construction of one Ru2W12-cluster and six lacunary Keggin tungstoarsenate leading to the larger Ru-containing polyoxometalate photocatalyst

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通讯作者: 陈斌, bchen63@163.com

Construction of one Ru₂W₁₂-cluster and six lacunary Keggin tungstoarsenate leading to the larger Ru-containing polyoxometalate photocatalyst