Citation: Xue Li, Hui Zhao, Yuyan Li, Yuanyuan Yang, Mingyang Zhang, Suyi Liu, Pengtao Ma, Jingping Wang, Jingyang Niu. Synthesis, structure and properties of three novel transition-metal-containing tantalum-phosphate clusters[J]. Chinese Chemical Letters, ;2022, 33(10): 4675-4678. doi: 10.1016/j.cclet.2021.12.078 shu

Synthesis, structure and properties of three novel transition-metal-containing tantalum-phosphate clusters

Henan Key Laboratory of Polyxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

jpwang@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 2 December 2021
Revised Date: 27 December 2021
Accepted Date: 28 December 2021
Available Online: 4 January 2022

Figures(4)

Peroxide ligation of aqueous metal–oxo clusters provides rich speciation and structural diversity. Here, three novel transition-metal derivatives of polyoxometalate anions, [Ni₂(H₂O)₁₀{P₄Ta₆(O₂)₆O₂₄}]^6– (1a), [Zn(H₂O)₄{P₄Ta₆(O₂)₆O₂₄}]^8– (2a) and [Cd(H₂O)₄{P₄Ta₆(O₂)₆O₂₄}]^8– (3a), have been successfully synthesized by adopting a one-pot reaction strategy. All of these hexatantalates are built from a new-type phosphorus-incorporated hexatantalates. We investigated the solution behaviors, and the peak assignments of the MS spectra indicated some degree of stability of them in water. Furthermore, the proton-conducting ability of compound 1a was also explored and it has shown well conductivity at high relative humidities, with conductivity achieved 1.22 × 10³ S/cm (85 ℃, 90%RH).
- Polyoxotantalates,
- Transition-metal,
- Synthesize,
- Structure,
- Proton-conduction
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