Citation: Xue Li, Hui Zhao, Yuyan Li, Yuanyuan Yang, Mingyang Zhang, Suyi Liu, Pengtao Ma, Jingping Wang, Jingyang Niu. Synthesis, structure and properties of three novel transition-metal-containing tantalum-phosphate clusters[J]. Chinese Chemical Letters, ;2022, 33(10): 4675-4678. doi: 10.1016/j.cclet.2021.12.078 shu

Synthesis, structure and properties of three novel transition-metal-containing tantalum-phosphate clusters

Henan Key Laboratory of Polyxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

jpwang@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 2 December 2021
Revised Date: 27 December 2021
Accepted Date: 28 December 2021
Available Online: 4 January 2022

Figures(4)

Peroxide ligation of aqueous metal–oxo clusters provides rich speciation and structural diversity. Here, three novel transition-metal derivatives of polyoxometalate anions, [Ni₂(H₂O)₁₀{P₄Ta₆(O₂)₆O₂₄}]^6– (1a), [Zn(H₂O)₄{P₄Ta₆(O₂)₆O₂₄}]^8– (2a) and [Cd(H₂O)₄{P₄Ta₆(O₂)₆O₂₄}]^8– (3a), have been successfully synthesized by adopting a one-pot reaction strategy. All of these hexatantalates are built from a new-type phosphorus-incorporated hexatantalates. We investigated the solution behaviors, and the peak assignments of the MS spectra indicated some degree of stability of them in water. Furthermore, the proton-conducting ability of compound 1a was also explored and it has shown well conductivity at high relative humidities, with conductivity achieved 1.22 × 10³ S/cm (85 ℃, 90%RH).
- Polyoxotantalates,
- Transition-metal,
- Synthesize,
- Structure,
- Proton-conduction
1. [1]
  A. Merca, S. Garai, A. Müller, et al., Angew. Chem. Int. Ed. 52 (2013) 11765-11769. doi: 10.1002/anie.201305402
2. [2]
  Y.N. Gu, Y. Chen, X.X. Li, et al., Inorg. Chem. 57 (2018) 2472-2479. doi: 10.1021/acs.inorgchem.7b02728
3. [3]
  Y. Zhu, P. Yin, F. Xiao, et al., J. Am. Chem. Soc. 135 (2013) 17155-17160. doi: 10.1021/ja408228b
4. [4]
  J. Gao, J. Miao, Q. Zhang, et al., Dalton Trans. 44 (2015) 14354-14358. doi: 10.1039/C5DT01769F
5. [5]
  G.P. Yang, X.L. Zhang, Y.F. Liu, et al., Inorg. Chem. Front. 8 (2021) 4650-4656. doi: 10.1039/D1QI00485A
6. [6]
  L. Qiao, M. Song, A. Geng, S. Yao, Chin. Chem. Lett. 30 (2019) 1273-1276. doi: 10.1016/j.cclet.2019.01.024
7. [7]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623. doi: 10.1039/c2cs35133a
8. [8]
  Z. Sun, H.Z. Bie, Y. Wu, et al., Chin. Chem. Lett. 24 (2013) 76-78. doi: 10.1016/j.cclet.2012.12.002
9. [9]
  G.P. Yang, K. Li, X.L. Lin, et al., Chin. J. Chem. 39 (2021) 3017-3022. doi: 10.1002/cjoc.202100397
10. [10]
  A. Dolbecq, E. Dumas, C.R. Mayer, P. Mialane, Chem. Rev. 110 (2010) 6009-6048. doi: 10.1021/cr1000578
11. [11]
  M. Cheng, Y. Liu, D. Zhang, et al., Chin. Chem. Lett. (2021), doi: 10.1016/j.cclet.2021.11.059. doi: 10.1016/j.cclet.2021.11.059
12. [12]
  M. Lv, Y. Liu, K. Li, G. Yang, Tetrahedron Lett. 65 (2021) 152757. doi: 10.1016/j.tetlet.2020.152757
13. [13]
  Z. Liang, L. Zhang, J. Wang, Inorg. Chem. 58 (2019) 27-30. doi: 10.1021/acs.inorgchem.8b02528
14. [14]
  L. Li, K. Dong, J. Wang, et al., Chem. Eur. J. 23 (2017) 16957-16960. doi: 10.1002/chem.201704071
15. [15]
  Z. Liang, D. Zhang, J. Niu, et al., Chem. Eur. J. 21 (2015) 8380-8383. doi: 10.1002/chem.201500289
16. [16]
  S. Chen, P. Ma, J. Wang, Chem. Commun. 53 (2017) 3709-3712. doi: 10.1039/C7CC00591A
17. [17]
  J. Niu, P. Ma, J. Wang, et al., Chem. Eur. J. 13 (2007) 8739-8748. doi: 10.1002/chem.200700612
18. [18]
  Y. Wu, X. Li, S. Zheng, Angew. Chem. Int. Ed. 57 (2018) 8572-8576. doi: 10.1002/anie.201804088
19. [19]
  L. Jin, Z.K. Zhu, S.T. Zheng, Angew. Chem. Int. Ed. 56 (2017) 16288-16292. doi: 10.1002/anie.201709565
20. [20]
  J.H. Son, D.H. Park, D.A. Keszler, W.H. Casey, Chem. Eur. J. 21 (2015) 6727-6731. doi: 10.1002/chem.201500684
21. [21]
  Z.Y. Zhang, J. Peng, et al., Chem. Commun. 51 (2015) 3091-3093. doi: 10.1039/C4CC09612F
22. [22]
  H.L. Wu, Z.M. Zhang, Y.G. Li, X.L. Wang, E.B. Wang, CrystEngComm 17 (2015) 6261-6268. doi: 10.1039/C5CE00909J
23. [23]
  J.H. Son, W.H. Casey, Chem. Commun. 51 (2015) 1436-1438. doi: 10.1039/C4CC05689B
24. [24]
  Y. Hou, L.N. Zakharov, M. Nyman, J. Am. Chem. Soc. 135 (2013) 16651-16657. doi: 10.1021/ja4086484
25. [25]
  J.Q. Shen, S. Yao, Z.M. Zhang, et al., Dalton Trans. 42 (2013) 5812. doi: 10.1039/c3dt32855d
26. [26]
  Y. Hou, T.M. Alam, M.A. Rodriguez, M. Nyman, Chem. Commun. 48 (2012) 6004. doi: 10.1039/c2cc31284k
27. [27]
  R.P. Bontchev, M. Nyman, Angew. Chem. 118 (2006) 6822-6824. doi: 10.1002/ange.200602200
28. [28]
  M. Nyman, A.J. Celestian, J.B. Parise, G.P. Holland, T.M. Alam, Inorg. Chem. 45 (2006) 1043-1052. doi: 10.1021/ic051155g
29. [29]
  M. Nyman, F. Bonhomme, T.M. Alam, J.B. Parise, G.M.B. Vaughan, Angew. Chem. Int. Ed. 43 (2004) 2787-2792. doi: 10.1002/anie.200353410
30. [30]
  I. Lindqvist, B. Aronsson, Ark. Kemi 7 (1954) 49-52.
31. [31]
  M. Matsumoto, Y. Ozawa, A. Yagasaki, Inorg. Chem. 51 (2012) 5991-5993. doi: 10.1021/ic3004883
32. [32]
  M. Matsumoto, Y. Ozawa, A. Yagasaki, Inorg. Chem. Commun. 14 (2011) 115-117. doi: 10.1016/j.inoche.2010.09.045
33. [33]
  L. Shen, Y.Q. Xu, Y.Z. Gao, F.Y. Cui, C.W. Hu, J. Mol. Struct. 934 (2009) 37-43. doi: 10.1016/j.molstruc.2009.06.018
34. [34]
  M. Nyman, T.M. Anderson, P.P. Provencio, Cryst. Growth. Des. 9 (2009) 1036-1040. doi: 10.1021/cg800849y
35. [35]
  P.A. Abramov, M.N. Sokolov, V.P. Fedin, et al., Dalton Trans. (44) (2015) 2234-2239.
36. [36]
  I. Abrahams, D.C. Bradley, H. Chudzynska, M. Motevalli, P. O'Shaughnessy, J. Chem. Soc. Dalton Trans. (2000) 2685-2691.
37. [37]
  M. Matsumoto, Y. Ozawa, A. Yagasaki, Y. Zhe, Inorg. Chem. 52 (2013) 7825-7827. doi: 10.1021/ic400864e
38. [38]
  J.H. Son, W.H. Casey, Chem. Eur. J. 22 (2016) 14155-14157. doi: 10.1002/chem.201603335
39. [39]
  Z. Liang, S. Zhao, P. Ma, C. Zhang, et al., Inorg. Chem. 57 (2018) 12471-12474. doi: 10.1021/acs.inorgchem.8b02100
40. [40]
  S.J. Li, S.M. Liu, J.H. Ye, et al., J. Am. Chem. Soc. 134 (2012) 19716. doi: 10.1021/ja307484a
41. [41]
  P. Huang, C. Qin, Z.M. Su, et al., Chem. Commun. 52 (2016) 13787. doi: 10.1039/C6CC07649A
42. [42]
  D. Zhang, Z. Liang, J. Niu, et al., Inorg. Chem. 56 (2017) 5537-5543. doi: 10.1021/acs.inorgchem.6b02524
43. [43]
  Z. Liang, H. Wu, J. Wang, et al., Inorg. Chem. 58 (2019) 13030-13036. doi: 10.1021/acs.inorgchem.9b01952
44. [44]
  L.B. Fullmer, C.E. Malmberg, M. Nyman, et al., Dalton Trans. 46(46) (2017) 8486-8493.
45. [45]
  C.P. Pradeep, D.L. Long, L. Cronin, Dalton Trans. 39 (2010) 9443. doi: 10.1039/c0dt00325e
46. [46]
  S.C. Abrahams, R.L. Collin, W.N. Lipscomb, Acta Cryst. 4 (1951) 15-20. doi: 10.1107/S0365110X51000039
47. [47]
  D. Brown, D. Altermatt, Acta Cryst, Sect. B 41 (1985) 244.
48. [48]
  H.H. Thorp, Inorg. Chem. 31 (1992) 1585. doi: 10.1021/ic00035a012
49. [49]
  F.A. Cotton, G. Wilkinson, C.A. Murillo, M. Bochmann, Advanced Inorganic chemistry, 6th. ed., Wiley, New York, 1999.
50. [50]
  D.W. Lim, H. Kitagawa, Chem. Rev. 120 (2020) 8416-8467. doi: 10.1021/acs.chemrev.9b00842
51. [51]
  W.H. Wang, Q. Gao, X.H. Bu, et al., Chin. Chem. Lett. 29 (2018) 336-338. doi: 10.1016/j.cclet.2017.08.033
1. [1]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
2. [2]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
3. [3]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
6. [6]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353
7. [7]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
8. [8]
  Haiming Wu , Gaya N. Andrew , Rajini Anumula , Zhixun Luo . Corrigendum to 'How ligand coordination and superatomic-states accommodate the structure and property of a metal cluster: Cu₄ (dppy)₄ Cl₂ vs. Cu₂₁ (dppy)₁₀ with altered photoluminescence' [Chin. Chem. Lett. 35 (2024) 108340]. Chinese Chemical Letters, 2024, 35(12): 109912-. doi: 10.1016/j.cclet.2024.109912
9. [9]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
10. [10]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
11. [11]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
12. [12]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
13. [13]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
14. [14]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
15. [15]
  Teng-Yu Huang , Junliang Sun , De-Xian Wang , Qi-Qiang Wang . Recent progress in chiral zeolites: Structure, synthesis, characterization and applications. Chinese Chemical Letters, 2024, 35(12): 109758-. doi: 10.1016/j.cclet.2024.109758
16. [16]
  Guilong Li , Wenbo Ma , Jialing Zhou , Caiqin Wu , Chenling Yao , Huan Zeng , Jian Wang . A composite hydrogel with porous and homogeneous structure for efficient osmotic energy conversion. Chinese Chemical Letters, 2025, 36(2): 110449-. doi: 10.1016/j.cclet.2024.110449
17. [17]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
18. [18]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361
19. [19]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
20. [20]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(499)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142