Citation: Mengjie Song, Qingyue Hu, Zheng-Yi Li, Xiaoqiang Sun, Ke Yang. NFSI-catalyzed S–S bond exchange reaction for the synthesis of unsymmetrical disulfides[J]. Chinese Chemical Letters, ;2022, 33(9): 4269-4272. doi: 10.1016/j.cclet.2021.12.073 shu

NFSI-catalyzed S–S bond exchange reaction for the synthesis of unsymmetrical disulfides

Mengjie Song ^a ,
Qingyue Hu ^a ,
Zheng-Yi Li ^{a, *,} ,
Xiaoqiang Sun ^b ,
Ke Yang ^{a, *,}

a.
Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
b.
Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China

zyli@cczu.edu.cn

keyang@cczu.edu.cn

Received Date: 17 October 2021
Revised Date: 26 December 2021
Accepted Date: 28 December 2021
Available Online: 2 January 2022

Figures(6)

The metal-free S–S bond exchange reaction of symmetrical disulfides catalyzed by NFSI is described. This novel protocol provides a facile and efficient approach to accessing important unsymmetrical disulfides. Furthermore, this strategy could also be utilized in the late-stage functionalization of amino acids, drugs, and natural products. The broad substrate scope, good functional group tolerance and easy accessibility of catalyst indicate that this strategy affords a green and practical complementary method to various unsymmetrical disulfides.
- Metal-free,
- S–S bond exchange,
- NFSI,
- Unsymmetrical disulfides,
- Organic synthesis
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