Citation: Junbu Wang, Zeai Huang, Ying Wang, Jundao Wu, Zhiqiang Rao, Fang Wang, Ying Zhou. Low temperature conversion of methane to syngas using lattice oxygen over NiO-MgO[J]. Chinese Chemical Letters, ;2022, 33(10): 4687-4690. doi: 10.1016/j.cclet.2021.12.060 shu

Low temperature conversion of methane to syngas using lattice oxygen over NiO-MgO

Junbu Wang ^{a, b} ,
Zeai Huang ^{a, b, *,} ,
Ying Wang ^b ,
Jundao Wu ^b ,
Zhiqiang Rao ^b ,
Fang Wang ^b ,
Ying Zhou ^{a, b, *,}

a.
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China
b.
Institute of Carbon neutrality & School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China

zeai.huang@swpu.edu.cn

yzhou@swpu.edu.cn

Received Date: 18 October 2021
Revised Date: 15 November 2021
Accepted Date: 22 December 2021
Available Online: 27 December 2021

Figures(4)

The conversion of methane to syngas (H₂ and CO) is an important route to produce high value-added products. Oxidize methane into syngas in the absence of gaseous oxidants is an economical route. In this work, NiO-MgO composite is successfully synthesized via an impregnation method. At 764 K, methane is directly converted to syngas on the NiO-MgO without gaseous oxidants. A synergistic effect of NiO and MgO was observed, in which NiO induced lattice oxygen of MgO mobility to oxidize methane and suppressed the formation of intermediates for side reaction. As a result, NiO-MgO exhibited enhancement of catalytic activity with the H₂ production rate of 1241.0 μmol g^-1 min^-1, which was 3.4 times higher than that of pure MgO. This work provides a direct guidance to understand of methane oxidation via lattice oxygen under low temperature (< 773 K).
- Methane,
- Lattice oxygen,
- Syngas,
- Hydrogen,
- NiO
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