Citation: Shuai Chen, Chuang Yu, Shaoqing Chen, Linfeng Peng, Cong Liao, Chaochao Wei, Zhongkai Wu, Shijie Cheng, Jia Xie. Enabling ultrafast lithium-ion conductivity of Li₂ZrCl₆ by indium doping[J]. Chinese Chemical Letters, ;2022, 33(10): 4635-4639. doi: 10.1016/j.cclet.2021.12.048 shu

Enabling ultrafast lithium-ion conductivity of Li₂ZrCl₆ by indium doping

Shuai Chen ^{a, b} ,
Chuang Yu ^{a, *,} ,
Shaoqing Chen ^c ,
Linfeng Peng ^a ,
Cong Liao ^a ,
Chaochao Wei ^a ,
Zhongkai Wu ^a ,
Shijie Cheng ^a ,
Jia Xie ^{a, *,}

a.
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
c.
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China

cyu2020@hust.edu.cn

xiejia@hust.edu.cn

Received Date: 30 September 2021
Revised Date: 7 December 2021
Accepted Date: 20 December 2021
Available Online: 24 December 2021

Figures(4)

Solid-state batteries with high energy density and safety are promising next-generation battery systems. However, lithium oxide and lithium sulfide electrolytes suffer low ionic conductivity and poor electrochemical stability, respectively. Lithium halide solid electrolyte shows high conductivity and good compatibility with the pristine high-voltage cathode but limited applications due to the high price of rare metal. Zr-based lithium halides with low cost and high stability possess great potential. Herein, a small amount of In³⁺ is introduced in Li₂ZrCl₆ to synthesize Li_2.25Zr_0.75In_0.25Cl₆ electrolytes with a high room temperature Li-ion conductivity of 1.08 mS/cm. Solid-state batteries using Li_2.25Zr_0.75In_0.25Cl₆/Li_5.5PS_4.5Cl_1.5 bilayer solid electrolytes combined with Li-In anode and pristine LiNi_0.7Mn_0.2Co_0.1O₂ cathode deliver high initial discharge capacities under different cut-off voltages. This work provides an effective strategy for enhancing the conductivity of Li₂ZrCl₆ electrolytes, promoting their applications in solid-state batteries.
- Solid electrolyte,
- Li₂ZrCl₆,
- Li-ion conductivity,
- In-doping,
- Solid-state battery
1. [1]
  J. Janek, W.G. Zeier, Nat. Energy. 1 (2016) 16141. doi: 10.1038/nenergy.2016.141
2. [2]
  A. Manthiram, X. Yu, S. Wang, Nat. Rev. Mater. 2 (2017) 16103. doi: 10.1038/natrevmats.2016.103
3. [3]
  C.Z. Ke, F. Liu, Z.M. Zheng, et al., Rare Met. 40 (2021) 1347–1356. doi: 10.1007/s12598-021-01716-1
4. [4]
  Q. Yu, K. Jiang, C. Yu, et al., Chin. Chem. Lett. 32 (2021) 2659–2678. doi: 10.1016/j.cclet.2021.03.032
5. [5]
  J.C. Bachman, S. Muy, A. Grimaud, et al., Chem. Rev. 116 (2016) 140–162. doi: 10.1021/acs.chemrev.5b00563
6. [6]
  J. Park, J.Y. Kim, D.O. Shid, et al., Chem. Eng. J. 391 (2020) 123528. doi: 10.1016/j.cej.2019.123528
7. [7]
  N. Kamayan, K. Homma, Y. Yamakawa, et al., Nat. Mater. 10 (2011) 682–686. doi: 10.1038/nmat3066
8. [8]
  Z.Y. He, Z.Q. Zhang, M. Yu, et al., Rare Met. 41 (2022) 798–805. doi: 10.1007/s12598-021-01827-9
9. [9]
  R. Murugan, V. Thangadurai, W. Weppner, Angew. Chem. Int. Ed. 46 (2007) 7778–7781. doi: 10.1002/anie.200701144
10. [10]
  M. Weiss, F.J. Simon, M.R. Busche, et al., Energy Rev. 3 (2020) 221–238. doi: 10.1007/s41918-020-00062-7
11. [11]
  Z. Liu, S. Ma, J. Liu, et al., ACS Energy Lett. 6 (2020) 298–304.
12. [12]
  X. Li, J. Liang, K.R. Adair, et al., Nano Lett. 20 (2020) 4384–4392. doi: 10.1021/acs.nanolett.0c01156
13. [13]
  F. Han, T. Gao, Y. Zhu, et al., Adv. Mater. 27 (2015) 3473–3483. doi: 10.1002/adma.201500180
14. [14]
  B.R. Shin, Y.J. Nam, D.Y. Oh, et al., Electrochim. Acta 146 (2014) 395–402. doi: 10.1016/j.electacta.2014.08.139
15. [15]
  M. Kotobuki, H. Mumakata, K. Kanamura, et al., J. Electrochem. Soc. 157 (2010) A1076. doi: 10.1149/1.3474232
16. [16]
  X. Li, J. Liang, X. Yang, et al., Energy Environ. Sci. 13 (2020) 1429–1461. doi: 10.1039/c9ee03828k
17. [17]
  H.T. Ren, Z.Q. Zhang, J.Z. Zhang, et al., Rare Met. 41 (2021) 106–114. doi: 10.1109/icaa53760.2021.00027
18. [18]
  S. Lou, F. Zhang, C. Fu, et al., Mater. Res. Bull. 33 (2021) 2000721. doi: 10.1002/adma.202000721
19. [19]
  L. Hanebali, T. Machej, C. Cros, et al., Mater. Res. Bull. 16 (1981) 887–901. doi: 10.1016/0025-5408(81)90165-3
20. [20]
  T. Asano, A. Sakai, S. Ouchi, et al., Adv. Mater. 30 (2018) e1803075. doi: 10.1002/adma.201803075
21. [21]
  X. Li, J. Liang, J. Luo, et al., Energy Environ. Sci. 12 (2019) 2665–2671. doi: 10.1039/c9ee02311a
22. [22]
  X. Li, J. Liang, N. Chen, et al., Angew. Chem. Int. Ed. 58 (2019) 16427–16432. doi: 10.1002/anie.201909805
23. [23]
  J. Liang, X. Li, S. Wang, et al., J. Am. Chem. Soc. 142 (2020) 7012–7022. doi: 10.1021/jacs.0c00134
24. [24]
  K. Yamada, K. Kumano, T. Okuda, Solid State Ion. 177 (2006) 1691–1695. doi: 10.1016/j.ssi.2006.06.026
25. [25]
  R. Schlem, S. Muy, N. Prinz, et al., Adv. Energy Mater. 10 (2020) 1903719. doi: 10.1002/aenm.201903719
26. [26]
  H. Kwak, D. Han, J. Lyoo, et al., Adv. Energy Mater. 11 (2021) 2003190. doi: 10.1002/aenm.202003190
27. [27]
  K. Wang, Q. Ren, Z. Gu, et al., Nat. Commun. 12 (2021) 4410. doi: 10.1038/s41467-021-24697-2
28. [28]
  K. Kim, D. Park, H.G. Jung, et al., Chem. Mater. 33 (2021) 3669–3677. doi: 10.1021/acs.chemmater.1c00555
29. [29]
  L. Peng, C. Yu, Z. Zhang, et al., Chem. Eng. J. 430 (2022) 132896. doi: 10.1016/j.cej.2021.132896
30. [30]
  J. Liang, X. Li, K.R. Adair, et al., Acc. Chem. Res. 54 (2021) 1023–1033. doi: 10.1021/acs.accounts.0c00762
31. [31]
  X. Liang, Q. Pang, I.R. Kochetkov, et al., Nat Energy 2 (2017) 17119. doi: 10.1038/nenergy.2017.119
32. [32]
  L. Peng, H. Ren, J. Zhang, et al., Energy Stor. Mater. 43 (2021) 53–61. doi: 10.1016/j.ensm.2021.08.028
1. [1]
  Han Yan , Jingming Yao , Zhangran Ye , Qiaoquan Lin , Ziqi Zhang , Shulin Li , Dawei Song , Zhenyu Wang , Chuang Yu , Long Zhang . Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes. Chinese Chemical Letters, 2025, 36(1): 109568-. doi: 10.1016/j.cclet.2024.109568
2. [2]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
3. [3]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
4. [4]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
5. [5]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390
6. [6]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
7. [7]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
8. [8]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
9. [9]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
10. [10]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
11. [11]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
12. [12]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
13. [13]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
14. [14]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
15. [15]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
16. [16]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
17. [17]
  Kezhen Qi , Shu-yuan Liu , Ruchun Li . Selective dissolution for stabilizing solid electrolyte interphase. Chinese Chemical Letters, 2024, 35(5): 109460-. doi: 10.1016/j.cclet.2023.109460
18. [18]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
19. [19]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
20. [20]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536

Get Citation

PDF

XML

Metrics

PDF Downloads(25)
Abstract views(729)
HTML views(157)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Enabling ultrafast lithium-ion conductivity of Li2ZrCl6 by indium doping

Metrics

通讯作者: 陈斌, bchen63@163.com

Enabling ultrafast lithium-ion conductivity of Li₂ZrCl₆ by indium doping