Citation: Lei Zhang, Zhe-Ji Wang, Bo Ma, Xiang-Yang Li, Yu-Chi Dai, Guowen Hu, Yong Peng, Qiang Wang, Hao-Li Zhang. Covalent carbene modification of 2D black phosphorus[J]. Chinese Chemical Letters, ;2022, 33(10): 4640-4644. doi: 10.1016/j.cclet.2021.12.046 shu

Covalent carbene modification of 2D black phosphorus

Lei Zhang ^{a, b} ,
Zhe-Ji Wang ^a ,
Bo Ma ^a ,
Xiang-Yang Li ^a ,
Yu-Chi Dai ^a ,
Guowen Hu ^a ,
Yong Peng ^c ,
Qiang Wang ^{a, b, *,} ,
Hao-Li Zhang ^{a, d, *,}

a.
State Key Laboratory of Applied Organic Chemistry (SKLAOC), Key Laboratory of Special Function Materials and Structure Design (MOE), College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
b.
Office of Laboratory and Equipment Management, Lanzhou University, Lanzhou 73000, China
c.
Key Laboratory of Magnetism and Magnetic Materials of Ministry of Education, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
d.
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China

qiangwang@lzu.edu.cn

haoli.zhang@lzu.edu.cn

Received Date: 30 September 2021
Revised Date: 30 October 2021
Accepted Date: 20 December 2021
Available Online: 24 December 2021

Figures(9)

Black phosphorus (BP) has attracted an ever-growing interest due to its unique anisotropic two-dimensional structure, impressive photoelectronic properties and attractive application potential. However, the tools for bandgap engineering and passivation via covalent modification of BP nanosheets remain limited to diazonium salt and nucleophilic addition methods, so that developing new modification strategies for BP nanosheets is crucial to explore its physical and chemical properties and enrich the toolbox for functionalization. Herein, we report the covalent modification of liquid-phase exfoliated BP nanosheets based on a rational analysis of BP structure. The modification of BP is achieved via carbene, a highly reactive organic mediate. The carbene modification improves the solubility and stability of BP nanosheets. Detailed microscopic and spectroscopic characterizations including infrared spectra, Raman spectra, X-ray photoelectron spectra, SEM and TEM were conducted to provide insights for the reaction. The proof of the existence of covalent bonds between BP nanosheets and organic moieties confirms the successful modification. Moreover, theoretical calculations were conducted to unveil the reaction mechanism of the two different types of bonds and the chemical property of two-dimensional BP.
- Two-dimensional materials,
- Black phosphorus,
- Covalent functionalization,
- Carbene,
- Solubility
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