Citation: Yangmian Lu, Jindong Li, Weizhi Gu, Ning Li, Zhenggen Zha, Zhiyong Wang. Lewis acid-catalyzed enantioselective Friedel-Crafts reaction of pyrazole-4, 5-diones with β-naphthol[J]. Chinese Chemical Letters, ;2022, 33(8): 4048-4052. doi: 10.1016/j.cclet.2021.12.038 shu

Lewis acid-catalyzed enantioselective Friedel-Crafts reaction of pyrazole-4, 5-diones with β-naphthol

Hefei National Laboratory for Physical Sciences at Microscale, Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

zwang3@ustc.edu.cn

Received Date: 30 August 2021
Revised Date: 7 December 2021
Accepted Date: 14 December 2021
Available Online: 20 December 2021

Figures(7)

A series of pyrazolone derivatives bearing a tetrasubstituted chiral center were prepared by virtue of a Lewis acid-catalyzed Friedel-Crafts reaction, in which a chiral copper complex was employed as the catalyst. This reaction can be carried out smoothly under mild condition to afford the pyrazolone derivatives with high yields (up to 85%) and excellent enantioselectivities (up to 99%). In addition, the gram scale synthesis proved the practicality of this reaction.
- Asymmetry,
- Friedel-Crafts reaction,
- Lewis acid-catalyst,
- Pyrazole-4, 5-diones,
- β-Naphthol
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