Citation: Qianqian Liu, Junjun Lu, Hongyan Lin, Xiuli Wang, Zhihan Chang, Yongzhen Chen, Yuchen Zhang. Polyoxometalate-based metal–organic complexes constructed from a new bis-pyrimidine-amide ligand with high capacitance performance and selectivity for the detection of Cr(Ⅵ)[J]. Chinese Chemical Letters, ;2022, 33(9): 4389-4394. doi: 10.1016/j.cclet.2021.12.024 shu

Polyoxometalate-based metal–organic complexes constructed from a new bis-pyrimidine-amide ligand with high capacitance performance and selectivity for the detection of Cr(Ⅵ)

College of Chemistry and Materials Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou 121013, China

wangxiuli@bhu.edu.cn

Received Date: 14 November 2021
Revised Date: 30 November 2021
Accepted Date: 10 December 2021
Available Online: 17 December 2021

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In this paper, three new polyoxometalates (POM)-based metal–organic complexes constructed from a new semi-rigid organic ligand N,N'-bis(4-pyrimidinecarboxamido)-1,2-cyclohexane (4-bpmah) H₂[Cu(4-bpmah)₂(SiMo₁₂O₄₀)(H₂O)₂]·2H₂O (1), H[Cu(4-bpmah)₂(PMo₁₂O₄₀)(H₂O)₂]·2H₂O (2) and [Cu(4-bpmah)(H₂O)₂]·[Cu₂(TeMo₆O₂₄)(H₂O)₁₀]·4H₂O (3) were synthesized by hydrothermal method. Single crystal X-ray analyses showed that complexes 1 and 2 were isostructural, in which the isolated Keggin-type [SiMo₁₂O₄₀]^4–/[PMo₁₂O₄₀]^3– anions and [Cu(4-bpmah)₂(H₂O)₂]²ⁿ⁺ units were expanded into 3D supramolecular structures through hydrogen bond interactions. In complex 3, the 1D [Cu(4-bpmah)(H₂O)₂]²ⁿ⁺ metal–organic chains and isolated [Cu₂(TeMo₆O₂₄)(H₂O)₁₀]^2n– units were expanded into a 3D supramolecular framework by the hydrogen bond interactions. In this paper, carbon cloth working electrodes composited by the title complexes (1/CC, 2/CC and 3/CC) were prepared and used as electrodes for supercapacitors. The performance of supercapacitors as well as the influence of electrolyte solution and title complexes quality load on the performance of supercapacitors were studied. Furthermore, the electrochemistry and electrocatalytic behaviors of complexes 1–3 bulk-modified carbon paste electrodes (1-CPE, 2-CPE and 3-CPE) toward the reduction of KBrO₃, KNO₂, Cr(Ⅵ), as well as their sensing behaviors on Cr(Ⅵ) were investigated.
- Polyoxometalates,
- Metal–organic complexes,
- Supercapacitor,
- Electrocatalysis,
- Electrochemical sensors
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