Citation: Ying Na, Zhe Chen, Zhongkai Xu, Qi An, Xi Zhang, Xiaohong Sun, Shu Cai, Chunming Zheng. Novel fast lithium-ion conductor LiTa₂PO₈ enhances the performance of poly(ethylene oxide)-based polymer electrolytes in all-solid-state lithium metal batteries[J]. Chinese Chemical Letters, ;2022, 33(8): 4037-4042. doi: 10.1016/j.cclet.2021.12.022 shu

Novel fast lithium-ion conductor LiTa₂PO₈ enhances the performance of poly(ethylene oxide)-based polymer electrolytes in all-solid-state lithium metal batteries

Ying Na ^a ,
Zhe Chen ^a ,
Zhongkai Xu ^a ,
Qi An ^a ,
Xi Zhang ^a ,
Xiaohong Sun ^{a, *,} ,
Shu Cai ^a ,
Chunming Zheng ^{b, *,}

a.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China
b.
School of Chemistry and Chemical Engineering, State Key Laboratory of Hollow-fiber Membrane Materials and Membrane Processes, Tiangong University, Tianjin 300387, China

sunxh@tju.edu.cn

zhengchunming@tiangong.edu.cn

Received Date: 13 October 2021
Revised Date: 29 November 2021
Accepted Date: 10 December 2021
Available Online: 17 December 2021

Figures(4)

At present, replacing the liquid electrolyte in a lithium metal battery with a solid electrolyte is considered to be one of the most powerful strategies to avoid potential safety hazards. Composite solid electrolytes (CPEs) have excellent ionic conductivity and flexibility owing to the combination of functional inorganic materials and polymer solid electrolytes (SPEs). Nevertheless, the ionic conductivity of CPEs is still lower than those of commercial liquid electrolytes, so the development of high-performance CPEs has important practical significance. Herein, a novel fast lithium-ion conductor material LiTa₂PO₈ was first filled into poly(ethylene oxide) (PEO)-based SPE, and the optimal ionic conductivity was achieved by filling different concentrations (the ionic conductivity is 4.61 × 10⁻⁴ S/cm with a filling content of 15 wt% at 60 ℃). The enhancement in ionic conductivity is due to the improvement of PEO chain movement and the promotion of LiTFSI dissociation by LiTa₂PO₈. In addition, LiTa₂PO₈ also takes the key in enhancing the mechanical strength and thermal stability of CPEs. The assembled LiFePO₄ solid-state lithium metal battery displays better rate performance (the specific capacities are as high as 157.3, 152, 142.6, 105 and 53.1 mAh/g under 0.1, 0.2, 0.5, 1 and 2 C at 60 ℃, respectively) and higher cycle performance (the capacity retention rate is 86.5% after 200 cycles at 0.5 C and 60 ℃). This research demonstrates the feasibility of LiTa₂PO₈ as a filler to improve the performance of CPEs, which may provide a fresh platform for developing more advanced solid-state electrolytes.
- Composite solid electrolyte,
- All-solid-state lithium metal battery,
- LiTa₂PO₈,
- Poly(ethylene oxide),
- Lewis acid
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Novel fast lithium-ion conductor LiTa2PO8 enhances the performance of poly(ethylene oxide)-based polymer electrolytes in all-solid-state lithium metal batteries

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通讯作者: 陈斌, bchen63@163.com

Novel fast lithium-ion conductor LiTa₂PO₈ enhances the performance of poly(ethylene oxide)-based polymer electrolytes in all-solid-state lithium metal batteries