Citation: Hao Zhang, Caihong He, Sumei Han, Zeyang Du, Ling Wang, Qinbai Yun, Wenbin Cao, Bowei Zhang, Ya-Hui Tian, Qipeng Lu. Crystal facet-dependent electrocatalytic performance of metallic Cu in CO₂ reduction reactions[J]. Chinese Chemical Letters, ;2022, 33(8): 3641-3649. doi: 10.1016/j.cclet.2021.12.018 shu

Crystal facet-dependent electrocatalytic performance of metallic Cu in CO₂ reduction reactions

Hao Zhang ^{a, 1} ,
Caihong He ^{a, 1} ,
Sumei Han ^a ,
Zeyang Du ^a ,
Ling Wang ^a ,
Qinbai Yun ^b ,
Wenbin Cao ^a ,
Bowei Zhang ^{c, *,} ,
Ya-Hui Tian ^{d, *,} ,
Qipeng Lu ^{a, *,}

a.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
b.
Department of Chemistry, City University of Hong Kong, Hong Kong, China
c.
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
d.
Institute of Acoustics, Chinese Academy of Sciences, Beijing 10019, China

bwzhang@ustb.edu.cn

tianyahui@mail.ioa.ac.cn

qipeng@ustb.edu.cn

Received Date: 29 September 2021
Revised Date: 9 November 2021
Accepted Date: 8 December 2021
Available Online: 11 December 2021

Figures(6)

Developing high-performance electrocatalysts for CO₂ reduction reaction (CO₂RR) is crucial since it is beneficial for environmental protection and the resulting value-add chemical products can act as an alternative to fossil feedstocks. Nonetheless, the direct reduction of CO₂ into long-chain hydrocarbons and oxygenated hydrocarbons with high selectivity remains challenging. Copper (Cu) shows a distinctive advantage that it is the only pure metal catalyst for reducing CO₂ into multi-carbon (C₂₊) products and the certain facets (e.g., (100), (111), (111)) of Cu nanocrystals exhibit relatively low energy barriers for the formation of specific products (e.g., CO, HCOOH, CH₄, C₂H₄, C₂H₅OH, and other C₂₊ products). Therefore, extensive studies have been carried out to explore the relationship between the facets of Cu nanocrystals and corresponding catalytic products. In this review, we will discuss the crystal facet-dependent electrocatalytic CO₂RR performance in metallic Cu catalysts, meanwhile, the detailed reaction mechanisms will be systematically summarized. In addition, we will provide a personal perspective for the future research directions in this emerging field. We believe this review is helpful to guide the design of high-selectivity Cu-based electrocatalysts for CO₂RR.
- Copper,
- CO₂ electrochemical reduction,
- Crystal facet-dependence,
- Electrocatalysts
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Crystal facet-dependent electrocatalytic performance of metallic Cu in CO2 reduction reactions

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通讯作者: 陈斌, bchen63@163.com

Crystal facet-dependent electrocatalytic performance of metallic Cu in CO₂ reduction reactions