Citation: Chengxiang Shi, Hui Li, Xiaofeng Shi, Liang Zhao, Hongdeng Qiu. Chiral pillar[n]arenes: Conformation inversion, material preparation and applications[J]. Chinese Chemical Letters, ;2022, 33(8): 3613-3622. doi: 10.1016/j.cclet.2021.12.010 shu

Chiral pillar[n]arenes: Conformation inversion, material preparation and applications

Chengxiang Shi ^{a, b, 1} ,
Hui Li ^{a, 1} ,
Xiaofeng Shi ^c ,
Liang Zhao ^{a, *,} ,
Hongdeng Qiu ^{a, d, e, *,}

a.
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Department of Gansu Provincial Cancer Hospital, Institute of Materia Medica, Lanzhou 730000, China
d.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
e.
College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China

zhaol@licp.cas.cn

hdqiu@licp.cas.cn

Received Date: 6 October 2021
Revised Date: 5 November 2021
Accepted Date: 6 December 2021
Available Online: 9 December 2021

Figures(10)

Chiral pillar[n]arenes have shown great research value and application prospect in construction of chiral materials and chiral applications, due to their inherent planar chiral configurations, chiral recognition ability, easy modification and highly symmetric hydrophobic cavity. This review systematically summarized the conformation inversion factors of planar chiral Pillar[5]arenes (pR/pS), such as solvents, temperature, substituent size, alkyl chains, chiral and achiral guest molecules. We firstly introduced the applications of chiral pillar[n]arenes for constructing chiral materials and pointed out that planar conformation inversion showed a great potential role in constructing chiral materials. Then, we mainly concluded the chiral applications of chiral and planar chiral pillar[n]arenes like chiral enantiomer analysis by circular dichroism, electrochemistry or chiral fluorescence sensing. From this review, we found that the inherent planar chiral conformation of chiral pillar[n]arenes have played a very important role in chiral field in the future.
- Chiral pillar[n]arene,
- Planar chiral configuration,
- Chiral supramolecular materials,
- Chiral separation and analysis,
- Conformation inversion
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沈阳化工大学材料科学与工程学院沈阳 110142