Citation: Yingjie Gao, Ying Han, Bingrui Liu, Jianfeng Gou, Dan Feng, Xiuwen Cheng. CoFe₂O₄ nanoparticles anchored on waste eggshell for catalytic oxidation of florfenicol via activating peroxymonosulfate[J]. Chinese Chemical Letters, ;2022, 33(8): 3713-3720. doi: 10.1016/j.cclet.2021.11.096 shu

CoFe₂O₄ nanoparticles anchored on waste eggshell for catalytic oxidation of florfenicol via activating peroxymonosulfate

Yingjie Gao ^a ,
Ying Han ^a ,
Bingrui Liu ^a ,
Jianfeng Gou ^a ,
Dan Feng ^{b, c} ,
Xiuwen Cheng ^{a, b, c, *,}

a.
Key Laboratory for Environmental Pollution Prediction and Control, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China
b.
College of Chemistry and Environmental Sciences, Yili Normal University, Yining 835000, China
c.
Key Laboratory of Pollutant Chemistry and Environmental Treatment, Yili Normal University, Yining 835000, China

chengxw@lzu.edu.cn

Received Date: 26 August 2021
Revised Date: 7 October 2021
Accepted Date: 30 November 2021
Available Online: 5 December 2021

Figures(4)

Eggshell-loaded CoFe₂O₄ catalyst was synthesized via a convenient hydrothermal method during our work, then the surface morphology and elemental composition of the composites were systematically investigated. Performance of CoFe₂O₄/eggshell-activated peroxymonosulfate (PMS) system was evaluated by selecting florfenicol (FF) as the model pollutant, and effects of operating parameters and water matrices on the FF removal efficiency in this system were investigated. In addition, main radicals involved in FF degradation were identified by EPR tests and radical quenching experiments, and possible mechanism was proposed. The reduction of toxicity during FF degradation was confirmed, and in combination with HP-LC tests, it was found that dehalogenation and defluorination were effectively carried out during FF degradation. In addition, the prepared CoFe₂O₄ polyvinylidene fluoride (PVDF) membrane effectively improved the stability of the material and reduced the precipitation of metals.
- CoFe₂O₄/eggshell,
- Peroxymonosulfate,
- Florfenicol,
- PVDF membrane
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沈阳化工大学材料科学与工程学院沈阳 110142

CoFe2O4 nanoparticles anchored on waste eggshell for catalytic oxidation of florfenicol via activating peroxymonosulfate

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通讯作者: 陈斌, bchen63@163.com

CoFe₂O₄ nanoparticles anchored on waste eggshell for catalytic oxidation of florfenicol via activating peroxymonosulfate