Citation: Ying Zhang, Jinfang Su, Junnan Chen, Chengshan Dai, Bingsen Zhang. Insight into the role of iron in platinum-based bimetallic catalysts for selective hydrogenation of cinnamaldehyde[J]. Chinese Chemical Letters, ;2022, 33(8): 3757-3761. doi: 10.1016/j.cclet.2021.11.077 shu

Insight into the role of iron in platinum-based bimetallic catalysts for selective hydrogenation of cinnamaldehyde

Ying Zhang ^{a, c, 1} ,
Jinfang Su ^{a, b, 1} ,
Junnan Chen ^{a, b} ,
Chengshan Dai ^{a, b} ,
Bingsen Zhang ^{a, b, *,}

a.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
b.
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
c.
School of Petrochemical Engineering, Liaoning Pertochemical University, Fushun 113001, China

bszhang@imr.ac.cn

Received Date: 3 September 2021
Revised Date: 8 October 2021
Accepted Date: 25 November 2021
Available Online: 1 December 2021

Figures(4)

Selective hydrogenation of cinnamaldehyde (CAL) toward cinnamyl alcohol (COL) is an extremely important and challenging reaction. Herein, a series of Pt_xFe_y-Al₂O₃ bimetallic catalysts with varied Pt to Fe ratios were prepared by incipient wetness impregnation method. The introduction of Fe significantly modifies the electronic and surface properties of Pt, which clearly enhances the C=O hydrogenation selectivity. Among all the catalysts, Pt₃Fe-Al₂O₃ displays the best catalytic performance and the conversion of CAL is 96.6% with 77.2% selectivity of COL within 1 h. In addition, Pt₃Fe-Al₂O₃ had excellent reusability with 76% COL selectivity after five runs of the recycle process. Further characterization of the fresh, used and cycled catalysts revealed that the structure and electronic state of the synthesized Pt_xFe_y-Al₂O₃ are unchanged after hydrogenation reaction. The identical-location transmission electron microscopy (IL-TEM) results revealed that the interaction between the nanoparticles and the supports was strong and the catalyst was relatively stable.
- Pt_xFe_y NPs,
- Cinnamaldehyde,
- Hydrogenation,
- Chemoselective,
- IL-TEM
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沈阳化工大学材料科学与工程学院沈阳 110142