Citation: Menghan Ge, Xiaoyu Zhou, Yinping Qin, Yang Liu, Jingjing Zhou, Xiaolei Wang, Bingkun Guo. A composite PEO electrolyte with amide-based polymer matrix for suppressing lithium dendrite growth in all-solid-state lithium battery[J]. Chinese Chemical Letters, ;2022, 33(8): 3894-3898. doi: 10.1016/j.cclet.2021.11.073 shu

A composite PEO electrolyte with amide-based polymer matrix for suppressing lithium dendrite growth in all-solid-state lithium battery

Menghan Ge ^{a, 1} ,
Xiaoyu Zhou ^{a, 1} ,
Yinping Qin ^a ,
Yang Liu ^{a, *,} ,
Jingjing Zhou ^a ,
Xiaolei Wang ^{b, *,} ,
Bingkun Guo ^{a, *,}

a.
Materials Genome Institute, Shanghai University, Shanghai 200444, China
b.
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2R3, Canada

xiaolei.wang@ualberta.ca

guobingkun@shu.edu.cn

Received Date: 29 June 2021
Revised Date: 24 October 2021
Accepted Date: 24 November 2021
Available Online: 29 November 2021

Figures(5)

The lithium dendrite growth is still a serious challenge and impeding the realistic applications of all-solid-state lithium batteries. In view of the amide containing sediment layer can be stable on lithium/cathodes, a composite polymer electrolyte with amide-based matrix is in-situ built on porous electrodes. With the introduction of amide, the polymer electrolyte presents excellent ability to inhibit lithium dendrite growth and makes the Li/Li symmetric battery stably work for 500 h with a good ionic conductivity of 4.25 × 10⁻⁵ S/cm at 40 ℃. The solid electrolyte also shows a wide electrochemical stable window and good interface contact with the porous cathode. Utilizing this composite polymer electrolyte, the all-solid-state Li/LiFePO₄ battery shows an initial discharge capacity of 146.5 mAh/g at 0.1 C under 40 ℃ and remains 81.4% in 100 cycles. The polymer electrolyte also can present better properties after modification. These results demonstrate that the presented PA-based composite polymer electrolyte could be served as a good electrolyte candidate for all-solid-state lithium-ion batteries.
- Composite,
- Amide,
- Lithium dendrite,
- Solid state electrolyte,
- Li metal battery
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