Citation: Jun Duan, Long Chen, Haodong Ji, Peishen Li, Fan Li, Wen Liu. Activation of peracetic acid by metal-organic frameworks (ZIF-67) for efficient degradation of sulfachloropyridazine[J]. Chinese Chemical Letters, ;2022, 33(6): 3172-3176. doi: 10.1016/j.cclet.2021.11.072 shu

Activation of peracetic acid by metal-organic frameworks (ZIF-67) for efficient degradation of sulfachloropyridazine

Jun Duan ^{a, b} ,
Long Chen ^a ,
Haodong Ji ^{a, b} ,
Peishen Li ^a ,
Fan Li ^{a, b} ,
Wen Liu ^{a, b, *}

a.
The Key Laboratory of Water and Sediment Science, Ministry of Education, College of Environment Science and Engineering, Peking University, Beijing 100871, China
b.
State Environmental Protection Key Laboratory of All Material Fluxes in River Ecosystems, Peking University, Beijing 100871, China

wen.liu@pku.edu.cn

Received Date: 22 September 2021
Revised Date: 9 November 2021
Accepted Date: 24 November 2021
Available Online: 29 November 2021

Figures(5)

Peracetic acid (PAA)-based system is becoming an emerging advanced oxidation process (AOP) for effective removal of organic contaminants from water. Various approaches have been tested to activate PAA, while no previous researches reported the application of metal-organic frameworks (MOFs) materials for PAA activation. In this study, zeolitic imidazole framework (ZIF)-67, a representative MOFs, was facile synthesized via direct-mixing method at room temperature, and tested for PAA activation and sulfachloropyridazine (SCP) degradation. The as-synthesized ZIF-67 exhibited excellent performance for PAA activation and SCP degradation with 100% of SCP degraded within 3 min, owing to the specific MOFs structure and abundant Co²⁺ sites. The pseudo-first-order kinetic model was applied to fit the kinetic data, with rate constant k₁ of ZIF-67 activated PAA system 34.2 and 156.5 times higher than those of conventional Co₃O₄ activated PAA and direct oxidation by PAA. Radical quenching experiments and electron paramagnetic resonance (EPR) analysis indicated that CH₃C(O)OO^· played a major role in this PAA activation system. Then, the Fukui index based on density functional theory (DFT) calculation was used to predict the possible reaction sites of SCP for electrophilic attack by CH₃C(O)OO^·. In addition, the degradation pathway of SCP was proposed based on Fukui index values and intermediates detection, which mainly included the S-N bond cleavage and SO₂ extrusion and followed by further oxidation, dechlorination, and hydroxylation. Therefore, ZIF-67 activated PAA is a novel strategy and holds strong potential for the removal of emerging organic contaminants (EOCs) from water.
- Peracetic acid activation,
- Metal-organic frameworks,
- Zeolitic imidazole framework (ZIF)-67,
- Emerging organic contaminants,
- Acetylperoxy radical,
- DFT calculation
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