Citation: Ruonan Guo, Ying Chen, Bingrui Liu, Ying Han, Jianfeng Gou, Xiuwen Cheng. Catalytic degradation of lomefloxacin by photo-assisted persulfate activation on natural hematite: Performance and mechanism[J]. Chinese Chemical Letters, ;2022, 33(8): 3809-3817. doi: 10.1016/j.cclet.2021.11.061 shu

Catalytic degradation of lomefloxacin by photo-assisted persulfate activation on natural hematite: Performance and mechanism

Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China

goujf@lzu.edu.cn

chengxw@lzu.edu.cn

Received Date: 27 July 2021
Revised Date: 8 October 2021
Accepted Date: 21 November 2021
Available Online: 26 November 2021

Figures(4)

The natural hematite (α-Fe₂O₃) is stable and abundant on the earth, as well as with strange electronic band structure and good visible light absorption properties. However, the composition and catalytic performance of natural hematite should be explored. In this study, the photo-assisted hematite nanoparticles activated persulfate (H-NPs/PS/vis) system was constructed. As detected, H-NPs had an irregular agglomerate structure with abundant internal pore and were mainly composed of Fe₂O₃, SiO₂ and TiO₂. The system was applied to removing various antibiotic (i.e., lomefloxacin, ciprofloxacin and enrofloxacin with initial concentration of 10 mg/L), achieving high degradation performance of 82.0%, 81.2% and 82.2% after 120, 330 and 240 min, respectively. Moreover, H-NPs had excellent reusability with low metal leaching (Ti leaching percentage lower than 0.01%, Fe dissolution percentage was 0.48%) and stable structure. At last, a possible reaction mechanism of H-NPs/PS/vis system was proposed that lomefloxacin (LOM) was efficiently removed via the synergistic process of components contained in H-NPs with PS and light, involving the generation of ^•O₂⁻, ^•OH and SO₄^•−. Above all, this paper provided a novel application scheme of natural hematite through in-depth and comprehensive experimental exploration.
- Natural hematite,
- Persulfate,
- Photocatalytic,
- Antibiotic degradation
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