Citation: Zuozhong Liang, Hongbo Guo, Haitao Lei, Rui Cao. Co porphyrin-based metal-organic framework for hydrogen evolution reaction and oxygen reduction reaction[J]. Chinese Chemical Letters, ;2022, 33(8): 3999-4002. doi: 10.1016/j.cclet.2021.11.055 shu

Co porphyrin-based metal-organic framework for hydrogen evolution reaction and oxygen reduction reaction

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

liangzuozhong@snnu.edu.cn

ruicao@snnu.edu.cn

Received Date: 7 September 2021
Revised Date: 9 November 2021
Accepted Date: 16 November 2021
Available Online: 24 November 2021

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Constructing molecule@support composites is an attractive strategy to realize heterogeneous molecular electrocatalysis. Herein, we synthesized metal-organic framework (MOF)-supported molecular catalysts for hydrogen evolution and oxygen reduction reaction (HER/ORR). Ligand exchange strategy was used to prepare molecule@support hybrids due to the same functional group. A series of hybrids were obtained using Co porphyrin (1) and different MOFs including MIL-88(Fe), MOF-5(NiCo) and UIO-66(Zr). The 1@MOF-5(NiCo) had the best HER and ORR activity compared with 1@MIL-88(Fe) and 1@MOF-5(NiCo). These hybrids also exhibited tunable selectivity for ORR with four-electron process, which can be attributed to the synergistic effect of porphyrin molecules and MOFs. This work provides a possibility for molecular catalysts to improve activity of HER and tune selectivity of ORR.
- Molecular catalysis,
- Hydrogen evolution reaction (HER),
- Oxygen reduction reaction (ORR),
- Co porphyrin,
- Metal-organic framework (MOF)
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