Citation: Tao Zhang, Panpan Zhang, Zhongquan Liao, Faxing Wang, Jinhui Wang, Mingchao Wang, Ehrenfried Zschech, Xiaodong Zhuang, Oliver G. Schmidt, Xinliang Feng. Interfacial synthesis of crystalline quasi-two-dimensional polyaniline thin films for high-performance flexible on-chip micro-supercapacitors[J]. Chinese Chemical Letters, ;2022, 33(8): 3921-3924. doi: 10.1016/j.cclet.2021.11.052 shu

Interfacial synthesis of crystalline quasi-two-dimensional polyaniline thin films for high-performance flexible on-chip micro-supercapacitors

Tao Zhang ^{a, *,} ,
Panpan Zhang ^{b, c, 1} ,
Zhongquan Liao ^d ,
Faxing Wang ^{b, c} ,
Jinhui Wang ^{e, f, h} ,
Mingchao Wang ^{b, c} ,
Ehrenfried Zschech ^d ,
Xiaodong Zhuang ^g ,
Oliver G. Schmidt ^{e, f} ,
Xinliang Feng ^{b, c, *,}

a.
Key Laboratory of Bio-based Polymeric Materials Technology and Application of Zhejiang Province, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
b.
Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Dresden 01062, Germany
c.
Center for Advancing Electronics Dresden (cfaed), Technische Universität Dresden, Dresden 01062, Germany
d.
Fraunhofer Institute for Ceramic Technologies and Systems (IKTS), Dresden 01109, Germany
e.
Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz 09107, Germany
f.
Institute for Integrative Nanosciences, IFW Dresden, Dresden 01069, Germany
g.
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China
h.
Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, China

tzhang@nimte.ac.cn

xinliang.feng@tu-dresden.de

Received Date: 15 September 2021
Revised Date: 22 October 2021
Accepted Date: 15 November 2021
Available Online: 19 November 2021

Figures(4)

Quasi-two-dimensional (q2D) conducting polymer thin film synergizes the advantageous features of long-range molecular ordering and high intrinsic conductivity, which are promising for flexible thin film-based micro-supercapacitors (MSCs). Herein, we present the high-performance flexible MSCs based on highly ordered quasi-two-dimensional polyaniline (q2D-PANI) thin film using surfactant monolayer assisted interfacial synthesis (SMAIS). Owing to high electrical conductivity, rich redox chemistry, and thin-film morphology, the q2D-PANI MSCs show high volumetric specific capacitance (ca. 360 F/cm³) and energy density (17.9 mWh/cm³), which outperform the state-of-art PANI thin-film based MSCs and promise for future flexible electronics.
- 2D polymers,
- Conducting polymers,
- Interfacial synthesis,
- Flexible electronics,
- Microsupercapacitor
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