Citation: Jinli Han, Suming Chen, Xiaochun Zhou, Hexiang Deng. Uncovering growth species of multivariate MOFs in liquid phase by mass spectrometry[J]. Chinese Chemical Letters, ;2022, 33(8): 3993-3998. doi: 10.1016/j.cclet.2021.11.035 shu

Uncovering growth species of multivariate MOFs in liquid phase by mass spectrometry

Jinli Han ^{a, b} ,
Suming Chen ^c ,
Xiaochun Zhou ^{b, *,} ,
Hexiang Deng ^{a, c, *,}

a.
Key Laboratory of Biomedical Polymers-Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
b.
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125, China
c.
The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China

xczhou2013@sinano.ac.cn

hdeng@whu.edu.cn

Received Date: 16 October 2021
Revised Date: 9 November 2021
Accepted Date: 10 November 2021
Available Online: 18 November 2021

Figures(4)

The unveiling of MOF growth mechanism is hampered by the lack of fundamental knowledge about the very early stage of nucleation, especially the form and ratio of molecular species in the solution for crystal growth. Herein, we report the detection of growth species for a series of MOFs with mono-linker, Cu-MOF-2-BDC and Cu-MOF-2-NDC, and two linkers, MTV-MOF-2-(C₄H₄), by high resolution ESI-MS, where a large variety of Cu-containing species are identified unambiguously. The solvent molecules such as H₂O, methanol and DMF participate in the formation of these species, other than ethanol. Furthermore, in the growth solution of MTV-MOF-2-(C₄H₄), growth species containing two different organic linkers are observed. The feeding ratio is not the only factor controlling the distribution of growth species for MTV-MOFs, but also the solvent involves in coordination, an aspect usually overlooked previously.
- Metal-organic framework,
- Multivariate MOFs,
- Mass spectrometry,
- Growth species,
- Self-assembly
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