Citation: Guicong Hu, Wen Chang, Sai An, Bo Qi, Yu-Fei Song. Self-assembly of reverse micelle nanoreactors by zwitterionic polyoxometalate-based surfactants for high selective production of β-hydroxyl peroxides[J]. Chinese Chemical Letters, ;2022, 33(8): 3968-3972. doi: 10.1016/j.cclet.2021.11.006 shu

Self-assembly of reverse micelle nanoreactors by zwitterionic polyoxometalate-based surfactants for high selective production of β-hydroxyl peroxides

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

bqi@mail.buct.edu.cn

songyf@mail.buct.edu.cn

Received Date: 6 October 2021
Revised Date: 27 October 2021
Accepted Date: 1 November 2021
Available Online: 7 November 2021

Figures(3)

Surfactants with polyoxometalates (POMs) as polar head groups have shown fascinating self-assembly behaviors and various functional applications. However, self-assembly them into reverse micelles is still challenging owing to the large molecular size and intermolecular strong electrostatic repulsions of POM heads. In this work, a zwitterionic POM-based surfactant was synthesized by covalently grafting two cationic long alkyl tails onto the lacunary site of [PW₁₁O₃₉]⁷⁻. With decreased electrostatic repulsions and increased hydrophobic effect, the POM-based reverse micelles with an average diameter of 5 nm were obtained. Interestingly, when these reverse micelles were applied for catalyzing the oxidation of styrene, an unprecedented β-hydroxyl peroxide compound of 2-hydroxyl-2-phenylethan-1-tert-butylperoxide was produced in high selectivity of 95.2%. In comparison, the cetyltrimethylammonium electrostatically encapsulated POMs mainly generated the epoxides or 1, 2-diols. A free radical mechanism was proposed for the oxidation reaction catalyzed by the zwitterionic POM surfactants.
- Polyoxometalate,
- Self-assembly,
- Peroxide,
- Catalysis,
- Zwitterionic surfactant
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