Citation: Sai-Sai Yan, Jin-Yun Wang, Zi-You Pan, Da-Sheng Zheng, Qian-Chong Zhang, Zhong-Ning Chen. Freezing the conductance of platinum(Ⅱ) complexes by quantum interference effect[J]. Chinese Chemical Letters, ;2022, 33(6): 3263-3266. doi: 10.1016/j.cclet.2021.10.092 shu

Freezing the conductance of platinum(Ⅱ) complexes by quantum interference effect

Sai-Sai Yan ^{a, b} ,
Jin-Yun Wang ^b ,
Zi-You Pan ^b ,
Da-Sheng Zheng ^{a, b} ,
Qian-Chong Zhang ^{b, c, *,} ,
Zhong-Ning Chen ^{b, c, *,}

a.
Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

zhangqianchong@fjirsm.ac.cn

czn@fjirsm.ac.cn

Received Date: 8 October 2021
Revised Date: 23 October 2021
Accepted Date: 31 October 2021
Available Online: 7 November 2021

Figures(4)

Understanding the impact of substituents on the quantum interference effect at single molecule scale is of great importance for the design of molecular devices. In this work, three platinum(Ⅱ) complexes with –H, –NH₂ and –NO₂ groups on conductive backbones were designed and synthesized. Single-molecule conductance, which was measured using scanning tunnelling microscope break junction (STM-BJ) technique, demonstrated a conductance freeze phenomenon under the variation of substituents. Theoretical study revealed that, despite the electronic effect of the substituents shifting the energy level of molecular orbital, the quantum interference effect vanished the influence of electronic effect on the conductance and eventually leaded to the conductance freeze.
- Platinum(Ⅱ) complex,
- Electronic effect,
- Single-molecule conductance,
- Quantum interference,
- Magic ratio rule
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