Citation: Xiao-Min Ding, Li Chen, Xi Luo, Feng-Ming He, Yan-Fang Xiao, Yu-Zhong Wang. Biomass-derived dynamic covalent epoxy thermoset with robust mechanical properties and facile malleability[J]. Chinese Chemical Letters, ;2022, 33(6): 3245-3248. doi: 10.1016/j.cclet.2021.10.079 shu

Biomass-derived dynamic covalent epoxy thermoset with robust mechanical properties and facile malleability

The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (MoE), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Polymer Materials Engineering, College of Chemistry, Sichuan University, Chengdu 610064, China

l.chen.scu@gmail.com

yzwang@scu.edu.cn

Received Date: 20 August 2021
Revised Date: 7 October 2021
Accepted Date: 26 October 2021
Available Online: 29 October 2021

Figures(5)

Biomass-derived dynamic covalent thermoset has been considered as a promising solution to the high dependence on fossil resources and the difficulty in recyclability after curing of conventional bisphenol A epoxy resins. However, the design and preparation of a dynamic covalent biobased epoxy thermoset with both comparable thermal and mechanical performances to bisphenol A epoxy resins and reprocessibility remains a significant challenge. Herein, based on imine chemistry, a novel Schiff base-containing dynamic covalent epoxy thermoset was facilely fabricated from biobased protocatechualdehyde and synthetic siloxane diamine. Due to the more reactive epoxides in the epoxy monomer than in bisphenol A epoxy oligomer, the thermoset exhibited a high cross-linking density, resulting in high thermal stability and glass transition temperature. The rigid aromatic Schiff base moieties endowed the thermoset with excellent mechanical properties: Thanks to the plasticization of the flexible siloxane, the thermoset displayed high impact strength. Meanwhile, owing to the high segmental mobility, the fast exchange of imine bonds was guaranteed; and the thermoset was able to be recycled through reprocessing. Taking these features, this work provided great potential for designing and preparing sustainable substitutes for bisphenol A epoxy resins in the high-performance applications.
- Epoxy resin,
- Dynamic covalent thermoset,
- Protocatechualdehyde,
- Imine chemistry,
- High-performance
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