Citation: Fancheng Sun, Qing Li, Yang Bai, Guangxun Zhang, Shasha Zheng, Maoying Peng, Xudong Chen, Nuo Lin, Huan Pang. A controllable preparation of two-dimensional cobalt oxalate-based nanostructured sheets for electrochemical energy storage[J]. Chinese Chemical Letters, ;2022, 33(6): 3249-3254. doi: 10.1016/j.cclet.2021.10.075 shu

A controllable preparation of two-dimensional cobalt oxalate-based nanostructured sheets for electrochemical energy storage

School of Chemistry and Chemical Engineering, Institute for Innovative Materials and Energy, Yangzhou University, Yangzhou 225009, China

huanpangchem@hotmail.com

panghuan@yzu.edu.cn

Received Date: 15 August 2021
Revised Date: 16 October 2021
Accepted Date: 26 October 2021
Available Online: 29 October 2021

Figures(5)

Well-defined two-dimensional (2D) cobalt oxalate (CoC₂O₄·2H₂O) nanosheets exhibit more excellent property than common bulk cobalt oxalate due to high specific surface areas and high-efficient transport of ion and electron. However, the delicate control of the 2D morphology of CoC₂O₄·2H₂O during their synthesis remains challenging. Herein, 2D CoC₂O₄·2H₂O nanosheets (M1), grown by straightforward chemical precipitation, can be tuned from three-dimensional (3D) structure during their synthesis with no templates or capping agents. This control is obtained by rationally changing the ratio of reactants with ethylene glycol as solvent. Moreover, Co₃O₄/CoC₂O₄ composites (M1-250) have been fabricated through low-temperature thermal treatment of the M1 precursor in air, which possess porous surfaces with the 2D morphology maintained. Benefiting from the porous surfaces, more redox-active sites and better electrical conductivity of Co₃O₄, the constructed M1-250//AC aqueous device manifest improved kinetics of the electrochemistry process with energy density of 27.9 Wh/kg at 550.7 W/kg and good cycling stability with sustaining 73.0 mAh/g after 5000 cycles.
- Two-dimensional nanosheets,
- Cobalt oxalate,
- Co₃O₄,
- Energy storage,
- Capacity
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