Citation: Lei Xu, Xinyue Cui, Jianbo Liao, Yufeng Liu, Baoyi Jiang, Junfeng Niu. Synchronous mineralization of three aqueous non-steroidal anti-inflammatory drugs in electrochemical advanced oxidation process[J]. Chinese Chemical Letters, ;2022, 33(8): 3701-3704. doi: 10.1016/j.cclet.2021.10.065 shu

Synchronous mineralization of three aqueous non-steroidal anti-inflammatory drugs in electrochemical advanced oxidation process

Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China

niujf@dgut.edu.cn

Received Date: 10 September 2021
Revised Date: 3 October 2021
Accepted Date: 22 October 2021
Available Online: 29 October 2021

Figures(4)

Electrochemical degradation performances of three non-steroidal anti-inflammatory drugs (NSAIDs), acetaminophen (ACT), aspirin (ASP) and ibuprofen (IBP), were investigated and compared in their alone and mixture conditions using Ti/SnO₂-Sb/La-PbO₂. The pseudo-first-order degradation kinetics (k) order was k_IBP-A (0.110 min⁻¹) > k_ASP-A (0.092 min⁻¹) > k_ACT-A (0.066 min⁻¹) in their alone condition, while that was k_ACT_-_M (0.088 min⁻¹) > k_ASP_-_M (0.063 min⁻¹) > k_IBP_-_M (0.057 min⁻¹) in their mixture condition. The ^•OH apparent production rate constant of 5.23 mmol L⁻¹ min⁻¹ m⁻² and an electrical energy per order (E_EO) value of 6.55 Wh/L could ensure the synchronous degradation of the NSAIDs mixture. The mineralization efficiency of NSAIDs mixture was 86.9% at 240 min with a mineralization current efficiency of 1.67%. Acetic acid and oxalic acid were the main products in the mineralization process for the both conditions. In the mixture condition, there were higher k values at lower initial concentrations and higher current density, while the presence of carbonate and humic acid inhibited their degradation. The results indicated electrochemical advanced oxidation process can effectively and synchronously mineralize NSAIDs mixture in wastewater.
- Electrochemical advanced oxidation,
- Non-steroidal anti-inflammatory drugs,
- Degradation kinetics,
- Synchronous mineralization,
- Wastewater
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