Citation: Guilan Xu, Qin-Long Hong, Yayong Sun, Meng Liu, Hai-Xia Zhang, Jian Zhang. Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO₂[J]. Chinese Chemical Letters, ;2022, 33(6): 2915-2918. doi: 10.1016/j.cclet.2021.10.061 shu

Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO₂

Guilan Xu ^a ,
Qin-Long Hong ^a ,
Yayong Sun ^a ,
Meng Liu ^b ,
Hai-Xia Zhang ^{a, *,} ,
Jian Zhang ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Key Lab for Sport Shoes Upper Materials of Fujian Province, Fujian Huafeng New Material Co., Ltd., Putian 351164, China

zhanghaixia@fjirsm.ac.cn

zhj@fjirsm.ac.cn

Received Date: 6 September 2021
Revised Date: 8 October 2021
Accepted Date: 21 October 2021
Available Online: 27 October 2021

Figures(4)

The photocatalytic reduction of CO₂ to energy-rich chemicals is highly appealing for alleviation of energy crisis and environment pollution. The introduction of different active sites is a key factor to determine the reaction activity and selectivity. Here, we demonstrate the metal ion-dependent performance for photocatalytic CO₂ reduction by anchoring transition metal ions (Co²⁺ and Ni²⁺) in an amine-functionalized boron imidazolate framework (BIF-43). As a result, Ni@BIF-43 realized a high selectivity of 90.2% for the CO₂-to-CO, while Co@BIF-43 achieved more efficient conversion with a high CO production rate of 2036.0 µmol g⁻¹ h⁻¹. Significantly, precise control of isolated metal site on a well-defined structure through coordination-assisted strategies enables us to better understand the specific effects of different metal-ion species on photoreduction of CO₂ as well as the catalytic mechanism.
- Metal-organic framework,
- CO₂ reduction,
- Boron-imidazolate framework,
- Photocatalysis,
- Structure
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沈阳化工大学材料科学与工程学院沈阳 110142

Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO2

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通讯作者: 陈斌, bchen63@163.com

Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO₂