Citation: Ying Zhang, Tongtong Gao, Chengshan Dai, Liyun Zhang, Yiming Niu, Junnan Chen, Zhong-Wen Liu, Bingsen Zhang. Tailoring the surface structure of iron compounds to optimize the selectivity of 3-nitrostyrene hydrogenation reaction over Pt catalyst[J]. Chinese Chemical Letters, ;2022, 33(6): 2911-2914. doi: 10.1016/j.cclet.2021.10.049 shu

Tailoring the surface structure of iron compounds to optimize the selectivity of 3-nitrostyrene hydrogenation reaction over Pt catalyst

Ying Zhang ^{a, b, 1} ,
Tongtong Gao ^{b, c, 1} ,
Chengshan Dai ^{b, d} ,
Liyun Zhang ^e ,
Yiming Niu ^{b, d} ,
Junnan Chen ^{b, d} ,
Zhong-Wen Liu ^{c, **,} ,
Bingsen Zhang ^{b, d, *,}

a.
School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China
b.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
c.
Key Laboratory of Syngas Conversion of Shaanxi Province, School of Chemistry and Chemical Engineering Shaanxi Normal University, Xi'an 710119, China
d.
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
e.
Department of Chemical Engineering, Qufu Normal University, Qufu 273165, China

^**

bszhang@imr.ac.cn

zwliu@snnu.edu.cn

Received Date: 26 July 2021
Revised Date: 17 September 2021
Accepted Date: 18 October 2021
Available Online: 23 October 2021

Figures(4)

Selective hydrogenation of substituted nitroarenes is an important reaction to obtain amines. Supported metal catalysts are wildly used in this reaction because the surface structure of supports can tune the properties of the supported metal nanoparticles (NPs) and promote the selectivity to amines. Herein, Pt NPs were immobilized on FeOOH, Fe₃O₄ and α-Fe₂O₃ nanorods to synthesize a series of iron compounds supported Pt catalysts by liquid phase reduction method. Chemoselective hydrogenation of 3-nitrostyrene to 3-aminostyrene was used as probe reaction to evaluate the performance of the catalysts. The results show that Pt/FeOOH exhibits the highest selectivity and activity. FeOOH support with pores and -OH groups can tune the electronic structure of Pt NPs. The positive charge of Pt NPs supported on FeOOH is key factor for improving the catalytic performance.
- Pt,
- Electronic structure,
- Surface structure,
- Iron compounds,
- Selective hydrogenation,
- 3-Nitrostyrene
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