Citation: Yi Wei, Wenhui Hou, Peng Zhang, Razium A. Soomro, Bin Xu. Bi₂S₃ nanorods encapsulated in iodine-doped graphene frameworks with enhanced potassium storage properties[J]. Chinese Chemical Letters, ;2022, 33(6): 3212-3216. doi: 10.1016/j.cclet.2021.10.035 shu

Bi₂S₃ nanorods encapsulated in iodine-doped graphene frameworks with enhanced potassium storage properties

Yi Wei ^a ,
Wenhui Hou ^a ,
Peng Zhang ^{a, b} ,
Razium A. Soomro ^a ,
Bin Xu ^{a, *,}

a.
State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

xubin@mail.buct.edu.cn

Received Date: 29 August 2021
Revised Date: 27 September 2021
Accepted Date: 15 October 2021
Available Online: 21 October 2021

Figures(4)

Bismuth sulfide (Bi₂S₃) is a promising anode material for high-performance potassium ion batteries due to its high theoretical capacity. However, the poor conductivity and substantial volume expansion hinder its practical application. We proposed an iodine-doped graphene encapsulated Bi₂S₃ nanorods composite (Bi₂S₃/IG) as an efficient anode for PIBs. The uniform-sized Bi₂S₃ nanorods evenly in-situ encapsulated in iodine-doped graphene framework, facilitating the electron transportation and structural stability. The potassium storage performance was evaluated in three electrolytes, with the best option of 5 mol/L KFSI in DME. The reversible capacity of representative Bi₂S₃/IG reached 453.5 mAh/g at 50 mA/g. Meanwhile, it could deliver an initial reversible capacity of 413.6 mAh/g at 100 mA/g, which maintained 256.9 mAh/g after 200 cycles. The proposed strategy contributes to improving potassium storage performance of metal sulfide anodes.
- Bi₂S₃,
- Iodine-doped graphene,
- Potassium-ion battery,
- Anode materials,
- Nanorods
1. [1]
  Y.C. Liu, B. Huang, Y.J. Shao, et al., Prog. Chem. 31 (2019) 1329–1340.
2. [2]
  W.L. Zhang, J. Yin, W.X. Wang, Z. Bayhan, H.N. Alshareef, Nano Energy 83 (2021) 105792. doi: 10.1016/j.nanoen.2021.105792
3. [3]
  N. Sun, Q. Zhu, B. Anasori, et al., Adv. Funct. Mater. 29 (2019) 1906282. doi: 10.1002/adfm.201906282
4. [4]
  P. Zhang, R.A. Soomro, Z. Guan, N. Sun, B. Xu, Energy Storage Mater. 29 (2020) 163–171. doi: 10.3847/1538-4357/ab71fe
5. [5]
  Z. Jian, W. Luo, X. Ji, J. Am. Chem. Soc. 137 (2015) 11566–11569. doi: 10.1021/jacs.5b06809
6. [6]
  B. Cao, H. Liu, P. Zhang, et al., Adv. Funct. Mater. 31 (2021) 2102126. doi: 10.1002/adfm.202102126
7. [7]
  Z.L. J. ian, S. Hwang, Z.F. Li, et al., Adv. Funct. Mater. 27 (2017) 1700324. doi: 10.1002/adfm.201700324
8. [8]
  W. Hong, Y. Zhang, L. Yang, et al., Nano Energy 65 (2019) 104038. doi: 10.1016/j.nanoen.2019.104038
9. [9]
  X. Wu, Y. Chen, Z. Xing, et al., Adv. Energy Mater. 9 (2019) 1900343. doi: 10.1002/aenm.201900343
10. [10]
  Y. Xu, J. Zhang, D. Li, Chem. Asian J. 15 (2020) 1648–1659. doi: 10.1002/asia.202000030
11. [11]
  Y. Zhang, J. Lou, Y. Shuai, et al., Mater. Lett. 242 (2019) 5–8. doi: 10.1016/j.matlet.2019.01.108
12. [12]
  W. Li, Z. Bi, W. Zhang, et al., J. Mater. Chem. A 9 (2021) 8221–8247. doi: 10.1039/d0ta12129k
13. [13]
  I. Sultana, M.M. Rahman, S. Mateti, et al., Nanoscale 9 (2017) 3646–3654. doi: 10.1039/C6NR09613A
14. [14]
  J. Chen, D.H.C. Chua, P.S. Lee, Small Methods 4 (2020) 1900648. doi: 10.1002/smtd.201900648
15. [15]
  Q. Pan, Z. Tong, Y. Su, S. Qin, Y. Tang, Adv. Funct. Mater. (2021) 2103912. doi: 10.1002/adfm.202103912
16. [16]
  S. Geng, T. Zhou, M. Jia, et al., Energy Environ. Sci. 14 (2021) 3184–3193. doi: 10.1039/d1ee00193k
17. [17]
  S. Ghosh, Z.M. Qi, H.Y. Wang, S.K. Martha, V.G. Pol, Electrochim. Acta 383 (2021) 138339. doi: 10.1016/j.electacta.2021.138339
18. [18]
  X.D. Ren, Q. Zhao, W.D. McCulloch, Y.Y. Wu, Nano Res. 10 (2017) 1313–1321. doi: 10.1007/s12274-016-1419-9
19. [19]
  Z. Chen, D.G. Yin, M. Zhang, Small 14 (2018) 1703818. doi: 10.1002/smll.201703818
20. [20]
  J.H. Choi, G.D. Park, Y.C. Kang, Chem. Eng. J. 408 (2021) 127278. doi: 10.1016/j.cej.2020.127278
21. [21]
  Y.F. Xu, J.L. Sun, Y.N. He, et al., Sci. China Chem. 64 (2021) 1401–1409. doi: 10.1007/s11426-021-1057-3
22. [22]
  Q.Q. Yao, J.S. Zhang, X.L. Shi, et al., Electrochim. Acta 307 (2019) 118–128. doi: 10.1016/j.electacta.2019.03.184
23. [23]
  Y. Zhao, J.J. Zhu, S.J.H. Ong, et al., Adv. Energy Mater. 8 (2018) 1802565. doi: 10.1002/aenm.201802565
24. [24]
  Z.C. Zhao, Z.Q. Hu, R.S. Jiao, et al., Energy Storage Mater. 22 (2019) 228–234.
25. [25]
  X.X. Jia, E.J. Zhang, X.Z. Yu, B.A. Lu, Energy Technol. 8 (2020) 1900987. doi: 10.1002/ente.201900987
26. [26]
  C. Nithya, G. Thiyagaraj, Sustain. Energy Fuels 4 (2020) 3574–3587. doi: 10.1039/d0se00469c
27. [27]
  T.H. Wang, D.Y. Shen, H. Liu, et al., ACS Appl. Mater. Interfaces 12 (2020) 57907–57915. doi: 10.1021/acsami.0c18285
28. [28]
  V. Lakshmi, A.A. Mikhaylov, A.G. Medvedev, et al., J. Mater. Chem. A 8 (2020) 11424–11434. doi: 10.1039/d0ta03555f
29. [29]
  Y. Zhang, P. Wang, Y. Yin, et al., Chem. Eng. J. 356 (2018) 1042–1051.
30. [30]
  Q.K. Peng, S.P. Zhang, H. Yang, et al., ACS Nano 14 (2020) 6024–6033. doi: 10.1021/acsnano.0c01681
31. [31]
  W.D. Li, D.Z. Wang, Z.J. Gong, et al., ACS Nano 14 (2020) 16046–16056. doi: 10.1021/acsnano.0c07733
32. [32]
  W.W. Chai, F. Yang, W.H. Yin, et al., Dalton Trans. 48 (2019) 1906–1914. doi: 10.1039/c8dt04158j
33. [33]
  W.P. Sun, X.H. Rui, D. Zhang, et al., J. Power Sources 309 (2016) 135–140. doi: 10.1016/j.jpowsour.2016.01.092
34. [34]
  Y.H. Liu, M.L. Li, Y.Y. Zheng, et al., Nanoscale 12 (2020) 24394–24402. doi: 10.1039/d0nr06457b
35. [35]
  Y. Zhang, L. Fan, P. Wang, et al., Nanoscale 9 (2017) 17694–17698. doi: 10.1039/C7NR06921A
36. [36]
  C. Wang, J. Lu, H. Tong, et al., Nano Res. 14 (2021) 3545–3551. doi: 10.1007/s12274-021-3560-3
37. [37]
  Z. Yao, H. Nie, Z. Yang, et al., Chem. Commun. 48 (2012) 1027–1029. doi: 10.1039/C2CC16192C
38. [38]
  J. Yang, J. Zhang, X. Li, et al., Nano Energy 53 (2018) 916–925. doi: 10.1016/j.nanoen.2018.09.044
39. [39]
  Z. Xiao, Z. Yang, L. Zhang, H. Pan, R. Wang, ACS Nano 11 (2017) 8488–8498. doi: 10.1021/acsnano.7b04442
40. [40]
  C. Shen, G. Song, X. Zhu, et al., Nano Energy 78 (2020) 105294. doi: 10.1016/j.nanoen.2020.105294
41. [41]
  K. Li, J. Zhang, D. Lin, et al., Nat. Commun. 10 (2019) 725. doi: 10.1038/s41467-019-08506-5
42. [42]
  L. Fan, S. Chen, R. Ma, et al., Small 14 (2018) 1801806. doi: 10.1002/smll.201801806
43. [43]
  L. Zhou, Z. Cao, J. Zhang, et al., Adv. Mater. 33 (2021) 2005993. doi: 10.1002/adma.202005993
44. [44]
  J. Zhang, Z. Cao, L. Zhou, et al., ACS Energy Lett. 5 (2020) 3124–3131. doi: 10.1021/acsenergylett.0c01634
45. [45]
  X. Min, J. Xiao, M. Fang, et al., Energy Environ. Sci. 14 (2021) 2186–2243. doi: 10.1039/d0ee02917c
46. [46]
  J. Wang, B. Wang, B. Lu, Adv. Energy Mater. 10 (2020) 2000884. doi: 10.1002/aenm.202000884
47. [47]
  L. Fan, R. Ma, Q. Zhang, X. Jia, B. Lu, Angew. Chem. Int. Ed. 58 (2019) 10500–10505. doi: 10.1002/anie.201904258
48. [48]
  K.T. Chen, H.Y. Tuan, ACS Nano 14 (2020) 11648–11661. doi: 10.1021/acsnano.0c04203
1. [1]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
2. [2]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
3. [3]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
4. [4]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
5. [5]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
6. [6]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
7. [7]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
8. [8]
  Guanyang Zeng , Xingqiang Liu , Liangqiao Wu , Zijie Meng , Debin Zeng , Changlin Yu . Novel visible-light-driven I- doped Bi2O2CO3 nano-sheets fabricated via an ion exchange route for dye and phenol removal. Chinese Journal of Structural Chemistry, 2024, 43(12): 100462-100462. doi: 10.1016/j.cjsc.2024.100462
9. [9]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
10. [10]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
11. [11]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
12. [12]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
13. [13]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
14. [14]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
15. [15]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
16. [16]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
17. [17]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
18. [18]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
19. [19]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
20. [20]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(540)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Bi2S3 nanorods encapsulated in iodine-doped graphene frameworks with enhanced potassium storage properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Bi₂S₃ nanorods encapsulated in iodine-doped graphene frameworks with enhanced potassium storage properties