Citation: Rong Fu, Longyue Yu, Junying Zhang, Huidong Yu, Shengyu Feng, Xing-Dong Xu. Facile construction of aggregation-induced emission molecular liquids via Piers-Rubinsztajn reaction for green fluorescent ink[J]. Chinese Chemical Letters, ;2022, 33(4): 1993-1996. doi: 10.1016/j.cclet.2021.10.018 shu

Facile construction of aggregation-induced emission molecular liquids via Piers-Rubinsztajn reaction for green fluorescent ink

Rong Fu ^a ,
Longyue Yu ^a ,
Junying Zhang ^a ,
Huidong Yu ^b ,
Shengyu Feng ^a ,
Xing-Dong Xu ^{a, *,}

a.
Key Laboratory of Special Functional Aggregated Materials of Ministry of Education, Shandong Key Laboratory of Advanced Silicone Materials and Technology, School of Chemistry and Chemical Engineering, National Engineering Research Center for Colloidal Materials, Shandong University, Ji'nan 250100, China
b.
Shandong Qilu Zhonghe Technology Co., Ltd., Ji'nan 250100, China

xuxd@sdu.edu.cn

Received Date: 25 April 2021
Revised Date: 8 October 2021
Accepted Date: 11 October 2021
Available Online: 16 October 2021

Figures(5)

Solvent-free luminescent molecular liquids (LMLs), which exhibit nonvolatile fluidic nature and active optoelectronic properties, were widely used. For further development, we introduced siloxane units into AIE molecules, designed and synthesized TPE derivatives with siloxane side chains via facile Piers-Rubinsztajn reaction. The obtained AIE molecular liquids exhibit unique photophysical properties. Compared with the obtained alkyl TPE-solids, siloxane TPE show liquid state, which proves that the siloxane units have stronger liquefaction effect than alkyl. Viscosity test shows that siloxane TPE-liquids has far more lower viscosity and better fluidity than the long-chain alkyl molecular liquids in previous research. All those properties are attributed to the weak interaction between flexible molecular chains of siloxane. Besides, fluorescence test shows temperature responsiveness of siloxane TPE-liquids. We developed this low-viscosity nonvolatile AIE molecular liquid as green fluorescent ink.
- TPE derivatives,
- Piers-rubinsztajn reaction,
- Molecular liquids,
- Aggregation-induced emission,
- Green fluorescent ink
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