Citation: Xinyue Xiong, Zhanglin Liu, Li Zhao, Mei Huang, Lichun Dai, Dong Tian, Jianmei Zou, Yongmei Zeng, Jinguang Hu, Fei Shen. Tailoring biochar by PHP towards the oxygenated functional groups (OFGs)-rich surface to improve adsorption performance[J]. Chinese Chemical Letters, ;2022, 33(6): 3097-3100. doi: 10.1016/j.cclet.2021.09.099 shu

Tailoring biochar by PHP towards the oxygenated functional groups (OFGs)-rich surface to improve adsorption performance

Xinyue Xiong ^{a, b} ,
Zhanglin Liu ^{a, b} ,
Li Zhao ^{a, b} ,
Mei Huang ^{a, b} ,
Lichun Dai ^c ,
Dong Tian ^{a, b} ,
Jianmei Zou ^{a, b} ,
Yongmei Zeng ^{a, b} ,
Jinguang Hu ^d ,
Fei Shen ^{a, b, *,}

a.
Institute of Ecological and Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China
b.
Rural Environment Protection Engineering & Technology Center of Sichuan Province, Sichuan Agricultural University, Chengdu 611130, China
c.
Key Laboratory of Development and Application of Rural Renewable Energy, Biogas Institute of Ministry of Agriculture and Rural Affairs, Chengdu 610041, China
d.
Chemical and Petroleum Engineering, Schulich School of Engineering, the University of Calgary, Calgary T2N4H9, Canada

fishen@sicau.edu.cn

Received Date: 13 July 2021
Revised Date: 21 August 2021
Accepted Date: 28 September 2021
Available Online: 2 October 2021

Figures(4)

In this work, a modification method of H₃PO₄ plus H₂O₂ (PHP) was introduced to targetedly form abundant oxygenated functional groups (OFGs) on biochar, and methylene blue (MB) was employed as a model pollutant for adsorption to reflect the modification performance. Results indicated that parent biochars, especially derived from lower temperatures, substantially underwent oxidative modification by PHP, and OFGs were targetedly produced. Correspondingly, approximately 21.5-fold MB adsorption capacity was achieved by PHP-modified biochar comparing with its parent biochar. To evaluate the compatibility of PHP-modification, coefficient of variation (CV) based on MB adsorption capacity by the biochar from various precursors was calculated, in which the CV of PHP-modified biochars was 0.0038 comparing to 0.64 of the corresponding parent biochars. These results suggested that the PHP method displayed the excellent feedstock compatibility on biochar modification. The maximum MB adsorption capacity was 454.1 mg/g when the H₃PO₄ and H₂O₂ fraction in PHP were 65.2% and 7.0%; the modification was further intensified by promoting temperature and duration. Besides, average 94.5% H₃PO₄ was recovered after 10-batch modification, implying 1.0 kg H₃PO₄ (85%) in PHP can maximally modify 2.37 kg biochar. Overall, this work offered a novel method to tailor biochar towards OFGs-rich surface for efficient adsorption.
- Biochar,
- Oxidative modification,
- Phosphoric acid,
- Hydrogen peroxide,
- Oxygenated functional groups
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