Citation: Shu Niu, Liang-Liang Mao, Hongyan Xiao, Yongye Zhao, Chen-Ho Tung, Li-Zhu Wu, Huan Cong. Adsorption of polyhaloalkane vapors by adaptive macrocycle crystals of WreathArene through C-halogen…π interactions[J]. Chinese Chemical Letters, ;2022, 33(4): 1970-1974. doi: 10.1016/j.cclet.2021.09.090 shu

Adsorption of polyhaloalkane vapors by adaptive macrocycle crystals of WreathArene through C-halogen…π interactions

Shu Niu ^a ,
Liang-Liang Mao ^a ,
Hongyan Xiao ^a ,
Yongye Zhao ^a ,
Chen-Ho Tung ^a ,
Li-Zhu Wu ^a ,
Huan Cong ^{a, *,}

a.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100190, China

hcong@mail.ipc.ac.cn

Received Date: 7 August 2021
Revised Date: 22 September 2021
Accepted Date: 25 September 2021
Available Online: 30 September 2021

Figures(6)

Polyhaloalkanes are broadly useful yet environmentally harmful stock chemicals, therefore the development of adsorbent materials with capacity and selectivity for polyhaloalkane vapors is highly desirable. Here we report a novel macrocycle WreathArene, a fluorinated C₃-symmetrical [1₆]-paracyclophane. In the crysalline state, WreathArene features guest-adaptive polymorphism for polyhaloalkanes including chloroform, tribromomethane, 1,1,2-trichloroethane, and 1,2-dibromoethane. Non-covalent C-halogen…π interactions are observed in all of these host-guest structures. Based on these properties, the activated WreathArene crystals can be utilized as a selective and recyclable adsorbent for polyhaloalkane vapors with excellent capacity under user-friendly conditions.
- Macrocycle,
- Paracyclophane,
- Halogen…π,
- Polyhaloalkane,
- Adsorption
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