Citation: Xiaoyi Liu, Limin Cui, Jun Jiang, Fan Ji, Junwei Zhao. A unique organic-inorganic hybrid Fe^III–Pr^III-included 2-germano-20-tungstate and its electrochemical biosensing properties[J]. Chinese Chemical Letters, ;2022, 33(5): 2630-2634. doi: 10.1016/j.cclet.2021.09.078 shu

A unique organic-inorganic hybrid Fe^III–Pr^III-included 2-germano-20-tungstate and its electrochemical biosensing properties

Xiaoyi Liu ¹ ,
Limin Cui ¹ ,
Jun Jiang ,
Fan Ji ^*, ,
Junwei Zhao ^*,

College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

jifan@henu.edu.cn

zhaojunwei@henu.edu.cn

Received Date: 25 August 2021
Revised Date: 16 September 2021
Accepted Date: 23 September 2021
Available Online: 30 September 2021

Figures(4)

An organic-inorganic hybrid Fe^III–Pr^III-included 2-germano-20-tungstate [Pr(H₂O)₈]₂H₂[Fe₄(H₂O)₄ (pca)₄Ge₂W₂₀O₇₂]•34H₂O (Hpca = 2-pyridinecarboxylic acid) (1) was hydrothermally prepared. Its polyoxoanion comprises one tetra-Fe^III incorporated [Fe₄(H₂O)₄(pca)₄Ge₂W₂₀O₇₂]^8- hybrid entity and two [Pr(H₂O)₈]³⁺ ornamental cations. The [Fe₄(H₂O)₄(pca)₄Ge₂W₂₀O₇₂]^8- 2-germano-20-tungstate entity can be regarded as an infrequent S-type [Ge₂W₂₀O₇₂]^16- cluster pocketed by four [Fe(H₂O)(pca)]²⁺ cations. The S-type [Ge₂W₂₀O₇₂]^16- cluster could be imagined as condensation of two divacant Keggin [α-GeW₁₀O₃₇]^10- segments by sharing two atoms. It is of interest is that carboxyl O and pyridine N atoms on pca ligands concurrently bind with Fe³⁺ cations in a five-membered heterocyclic fashion to increase the stability of the whole structure. Furthermore, the electrochemical biosensing properties of 1 as the modified electrode material have been investigated for detecting norepinephrine (NPP), showing a low detection limit of 3.25 µmol/L. This work not only enriches structures of heterometallic germanotungstates (GTs), but also expands applications of polyoxometalates (POMs) in the electrochemical biosensing field.
- Polyoxometalate,
- Germanotungstate,
- Heterometallic polyoxotungstate,
- Electrochemistry,
- Biosensing
1. [1]
  J.T. Rhule, C.L. Hill, D.A. Judd, et al., Chem. Rev.98 (1998) 327–358. doi: 10.1021/cr960396q
2. [2]
  D.Y. Fu, S.M. Zhang, Z.Y. Qu, et al., ACS Appl. Mater. Interfaces10 (2018) 6137–6145. doi: 10.1021/acsami.7b17082
3. [3]
  J.C. Liu, Q. Han, L.J. Chen, et al., Angew. Chem. Int. Ed. 57 (2018) 8416–8420. doi: 10.1002/anie.201803649
4. [4]
  K. Yang, Y. Hu, L. Li, et al., Nano Energy, 74 (2020) 104851. doi: 10.1016/j.nanoen.2020.104851
5. [5]
  S.J. Folkman, R.G. Finke, ACS Catal. 7 (2017) 7–16. doi: 10.1021/acscatal.6b02244
6. [6]
  X. Xu, X. Liu, D. Wang, et al., Inorg. Chem. 60 (2021) 1037–1044. doi: 10.1021/acs.inorgchem.0c03148
7. [7]
  J.Q. Sha, P.P. Zhu, X.Y. Yang, et al., Inorg. Chem. 56 (2017) 11998–12002. doi: 10.1021/acs.inorgchem.7b01962
8. [8]
  J.W. Zhang, Y.C. Huang, G. Li, et al., Coord. Chem. Rev. 378 (2019) 395–414. doi: 10.1016/j.ccr.2017.10.025
9. [9]
  G.P. Yang, Y.F. Liu, K. Li, et al., Chin. Chem. Lett. 31 (2020) 3233–3236. doi: 10.1016/j.cclet.2020.07.018
10. [10]
  H. Bian, X.J. Zhang, H.K. Zhao, et al., Chin. Chem. Lett. 30 (2019) 1097–1099. doi: 10.1016/j.cclet.2019.01.030
11. [11]
  Y.W. Peng, C.S. Shan, H.J. Wang, et al., Adv. Energy Mater. 2019 (9) 1900597.
12. [12]
  H.Y. Zhao, Y.Z. Li, J.W. Zhao, et al., Coord. Chem. Rev. 440 (2021) 213966.
13. [13]
  X. Ma, W. Yang, L. Chen, et al., CrystEngComm17 (2015) 8175–8197. doi: 10.1039/C5CE01240F
14. [14]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
15. [15]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
16. [16]
  X. Ma, H. Li, L. Chen, et al., Dalton Trans. 45 (2016) 4935–4960. doi: 10.1039/C5DT05020K
17. [17]
  P.T. Ma, F. Hu, J.P. Wang, et al., Coord. Chem. Rev. 378 (2019) 281–309. doi: 10.1016/j.ccr.2018.02.010
18. [18]
  L.Z. Qiao, M. Song, A.F. Geng, et al., Chin. Chem. Lett. 30 (2019) 1273–1276. doi: 10.1016/j.cclet.2019.01.024
19. [19]
  N. Zhang, L.Y. Hong, A.F. Geng, et al., Chin. Chem. Lett. 29 (2018) 1409–1412. doi: 10.1016/j.cclet.2017.12.003
20. [20]
  Y. Hao, L. Zhong, H.H. Li, et al., Cryst. Growth Des. 19 (2019) 1329–1335. doi: 10.1021/acs.cgd.8b01717
21. [21]
  M. Samaniyan, M. Mirzaei, R. Khajavian, et al., ACS Catal. 9 (2019) 10174–10191. doi: 10.1021/acscatal.9b03439
22. [22]
  C. Boskovic, Acc. Chem. Res. 50 (2017) 2205–2214. doi: 10.1021/acs.accounts.7b00197
23. [23]
  V. Das, R. Kaushik, F. Hussain, Coord. Chem. Rev. 413 (2020) 213271. doi: 10.1016/j.ccr.2020.213271
24. [24]
  J.W. Zhao, Y.Z. Li, L.J. Chen, et al., Chem. Commun. 52 (2016) 4418–4445. doi: 10.1039/C5CC10447E
25. [25]
  Z.M. Zhang, Y.G. Li, S. Yao, et al., Dalton Trans. 40 (2011) 6475–6479. doi: 10.1039/c1dt10133a
26. [26]
  C.T. Kresge, M.E. Leonowicz, W.J. Roth, et al., Nature359 (1992) 710–712. doi: 10.1038/359710a0
27. [27]
  U. Kortz, S. Nellutla, A.C. Stowe, et al., Inorg. Chem. 43 (2004) 2308–2317. doi: 10.1021/ic0354421
28. [28]
  Y.Z. Li, J. Luo, L.J. Chen, et al., RSC Adv. 4 (2014) 50679–50692. doi: 10.1039/C4RA08045A
29. [29]
  S. Reinoso, J.R. Galán-Mascarós, Inorg. Chem. 49 (2010) 377–379. doi: 10.1021/ic902217g
30. [30]
  H.Y. Zhao, J.W. Zhao, B.F. Yang, et al., Cryst. Growth Des. 13 (2013) 5169–5174. doi: 10.1021/cg4014575
31. [31]
  J. Wang, J.W. Zhao, H.Y. Zhao, et al., CrystEngComm16 (2014) 252–259. doi: 10.1039/C3CE42023J
32. [32]
  L. Zhong, X.X. Li, T. Yang, et al., Angew. Chem. Int. Ed. 56 (2017) 2664–2669. doi: 10.1002/anie.201612046
33. [33]
  J.W. Zhao, D.Y. Shi, L.J. Chen, et al., Dalton Trans. 41 (2012) 10740–10751. doi: 10.1039/c2dt30949a
34. [34]
  J.W. Zhao, D.Y. Shi, L.J. Chen, et al., Cryst. Growth Des. 13 (2013) 4368–4377. doi: 10.1021/cg400746n
35. [35]
  J.W. Zhao, Y.Z. Li, F. Ji, et al., Dalton Trans. 43 (2014) 5694–5706. doi: 10.1039/C3DT53616E
36. [36]
  K.J. Samdani, D.W. Joh, M.K. Rath, et al., Electrochim. Acta252 (2017) 268–274. doi: 10.1016/j.electacta.2017.08.187
37. [37]
  F.M. Morawski, B.B. Xavier, A.H. Virgili, et al., Mater. Sci. Eng. C: Mater. Biol. Appl. 120 (2021) 111646–111657. doi: 10.1016/j.msec.2020.111646
38. [38]
  M.Y. Emran, M. Mekawy, N. Akhtar, et al., Biosens. Bioelectron. 100 (2018) 122–131. doi: 10.1016/j.bios.2017.08.050
39. [39]
  J. Mårtensson, A.C. Gordon, Anal. Chim. Acta1039 (2018) 124–131. doi: 10.1016/j.aca.2018.07.043
40. [40]
  T. Pradhan, H.S. Jung, J.H. Jang, et al., Chem. Soc. Rev. 43 (2014) 4684–4713. doi: 10.1039/C3CS60477B
41. [41]
  T. Chen, Y.H. Xu, S. Wei, et al., Biosens. Bioelectron. 124-125 (2019) 224–232. doi: 10.1016/j.bios.2018.10.030
42. [42]
  C.L. Zhou, S. Li, W. Zhu, et al., Electrochim. Acta113 (2013) 454–463. doi: 10.1016/j.electacta.2013.09.109
43. [43]
  J. Jiang, L.L. Liu, G.P. Liu, et al., Inorg. Chem. 59 (2020) 15355–15364. doi: 10.1021/acs.inorgchem.0c02318
44. [44]
  L.L. Liu, J. Jiang, X.Y. Liu, et al., Inorg. Chem. Front. 7 (2020) 4640–4651. doi: 10.1039/D0QI01031F
45. [45]
  A.A. Lahcen, S.A. Errayess, A. Amine, Microchim. Acta183 (2016) 2169–2176. doi: 10.1007/s00604-016-1850-3
46. [46]
  M. Sadakane, E. Steckhan, Chem. Rev. 98 (1998) 219–237. doi: 10.1021/cr960403a
47. [47]
  U. Kortz, M.G. Savelieff, B.S. Bassil, et al., Inorg. Chem. 41 (2002) 783–789. doi: 10.1021/ic010855s
48. [48]
  Z.G. Han, Y.L. Zhao, J. Peng, et al., Electrochim. Acta51 (2005) 218–224. doi: 10.1016/j.electacta.2005.04.016
49. [49]
  C.M. Kuskur, B.E. Kumara Swamy, H. Jayadevappa, Ionics (Kiel)25 (2019) 1845–1855. doi: 10.1007/s11581-018-2606-3
50. [50]
  B.N. Chandrashekar, B.E. Kumara Swamy, Anal. Methods4 (2012) 849–854. doi: 10.1039/c2ay05632a
51. [51]
  H. Beitollahi, A. Mohadesi, S.K. Mahani, et al., Ionics (Kiel)18 (2012) 703–710. doi: 10.1007/s11581-012-0669-0
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沈阳化工大学材料科学与工程学院沈阳 110142

A unique organic-inorganic hybrid FeIII–PrIII-included 2-germano-20-tungstate and its electrochemical biosensing properties

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通讯作者: 陈斌, bchen63@163.com

A unique organic-inorganic hybrid Fe^III–Pr^III-included 2-germano-20-tungstate and its electrochemical biosensing properties