Citation: Chang Zhang, Shijiao Sun, Meifen Wu, Xiangyu Zhao. Bismuth chloride@mesocellular carbon foam nanocomposite cathode materials for rechargeable chloride ion batteries[J]. Chinese Chemical Letters, ;2022, 33(4): 2200-2204. doi: 10.1016/j.cclet.2021.09.052 shu

Bismuth chloride@mesocellular carbon foam nanocomposite cathode materials for rechargeable chloride ion batteries

Chang Zhang ^a ,
Shijiao Sun ^{a, *,} ,
Meifen Wu ^b ,
Xiangyu Zhao ^{a, c, *,}

a.
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
b.
CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
c.
Jiangsu Collaborative Innovation Center for Advanced Inorganic Functional Composites, Nanjing Tech University, Nanjing 211816, China

sunshijiao@njtech.edu.cn

xiangyu.zhao@njtech.edu.cn

Received Date: 4 July 2021
Revised Date: 26 August 2021
Accepted Date: 15 September 2021
Available Online: 20 September 2021

Figures(4)

Chloride ion batteries (CIB) are considered to be one of the most promising energy storage devices. As cathode materials for CIBs, metal chlorides have many advantages, such as high theoretical energy density, abundant elemental resources and ideal discharge voltage plateau. However, the dissolution and huge volume change of metal chlorides during cycling lead to considerable short lifespan, which limits their potential application for CIBs. Herein, the bismuth chloride nanocrystal is confined in mesocellular carbon foam matrix by a new vacuum impregnation approach. The mesocellular carbon foam with large interconnected pores (15.7 or 23.2 nm) may buffer the large volume variation of bismuth chloride during charge and discharge, giving rise to significantly enhanced electrochemical performance. The as-prepared bismuth chloride@mesocellular carbon foam cathode delivered an initial discharge capacity of 298 mAh/g and a reversible capacity of 91 mAh/g after 60 cycles. In contrast, the pure bismuth chloride cathode almost cannot discharge after 30 cycles. This is the first report that the metal chloride cathode can achieve a prolonged cycling in CIBs.
- Chloride ion batteries,
- Cathode materials,
- Bismuth chloride,
- Mesocellular carbon foam,
- Electrochemistry
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