Citation: Chan Wang, Bangqi Wei, Han Zhu, Yimin He, Guoxia Ran, Qijun Song. Engineering FeS₂ nanoparticles on tubular g-C₃N₄ for photo-Fenton treatment of paint wastewater[J]. Chinese Chemical Letters, ;2022, 33(6): 3073-3077. doi: 10.1016/j.cclet.2021.09.051 shu

Engineering FeS₂ nanoparticles on tubular g-C₃N₄ for photo-Fenton treatment of paint wastewater

Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical & Material Engineering, Jiangnan University, Wuxi 214122, China

wangchan@jiangnan.edu.cn

qsong@jiangnan.edu.cn

Received Date: 24 May 2021
Revised Date: 18 August 2021
Accepted Date: 14 September 2021
Available Online: 20 September 2021

Figures(5)

An efficient photo-Fenton catalyst (FeS₂@HTCN) was designed by maximizing the synergistic effect of FeS₂ nanoparticles and hollow tubular g-C₃N₄ (HTCN). Molecule self-assembly and molten salts-assisted calcination were used to engineering the hollow structured g-C₃N₄ before anchoring FeS₂ nanoparticles on the walls of HTCN via reflux method. Compared to bulk g-C₃N₄, the unique structure of HTCN and heterojunction in the composite endowed FeS₂@HTCN with more active sites and abundant channels for electron transfer and charge separation. The enriched electrons can improve the Fe³⁺ recycling and boost Fe²⁺ catalyzed ^•OH production via H₂O₂. As-prepared photo-Fenton catalyst was successfully applied to the treatment of industrial paint wastewater. The paint wastewater with its COD as high as 8200 mg/L can be effectively degraded with 0.2 mol/L H₂O₂ in 90 min under visible light irradiation. The photo-Fenton system was further evaluated according to the process stability and economic benefit, proving that the strategy presented in this work would be applicable to the treatment of real wastewater.
- Photo-Fenton catalysts,
- FeS₂ nanoparticles,
- Hollow tubular g-C₃N₄,
- Heterojunction,
- Reactive oxygen species,
- Paint wastewater degradation
1. [1]
  R. Mohtashami, J.Q. Shang, J. Clean. Prod. 218 (2019) 335-346. doi: 10.1016/j.jclepro.2019.01.326
2. [2]
  M.H. Ordouei, A. Elkamel, J. Clean. Prod. 166 (2017) 253-262. doi: 10.1016/j.jclepro.2017.07.247
3. [3]
  A.A. Zorpas, V.J. Inglezakis, Technol. Soc. 34 (2012) 55-83. doi: 10.1016/j.techsoc.2011.12.006
4. [4]
  K.Y. Show, M. Ling, H. Guo, D.J. Lee, Bioresour. Technol. 310 (2020) 123376. doi: 10.1016/j.biortech.2020.123376
5. [5]
  D. Güven, O. Hanhan, E.C. Aksoy, G. Insel, E. Çogör, J. Hazard. Mater. 330 (2017) 61-67. doi: 10.1016/j.jhazmat.2017.01.048
6. [6]
  A.D. Barbosa, L.F. da Silva, H.M. de Paula, et al., Water Res. 145 (2018) 153-161. doi: 10.1016/j.watres.2018.08.022
7. [7]
  I.R. Bautitz, R.F.P. Nogueira, Catal. Today 151 (2010) 94-99. doi: 10.1016/j.cattod.2010.02.018
8. [8]
  D.L. Zheng, S.L. Pei, S. Geng, L.S. Zhang, J. Nanosci. Nanotechnol. 19 (2019) 5858-5863. doi: 10.1166/jnn.2019.16513
9. [9]
  E. López-Loveira, F. Ariganello, M.S. Medina, et al., Environ. Sci. Pollut. Res. 24 (2016) 25634-25644.
10. [10]
  N.M. Mahmoodi, S. Khorramfar, Desalin. Water Treat. 52 (2014) 5007-5014. doi: 10.1080/19443994.2013.810378
11. [11]
  W.J. Li, Y. Li, D. Ning, et al., New J. Chem. 42 (2018) 29-33. doi: 10.1039/C7NJ03815A
12. [12]
  S.J. Yuan, X.H. Dai, Appl. Catal. B: Environ. 154-155 (2014) 252-258.
13. [13]
  S. Xavier, R. Gandhimathi, P.V. Nidheesh, et al., Desalin. Water Treat. 57 (2016) 12832-12841. doi: 10.1080/19443994.2015.1054887
14. [14]
  Y. Gou, P. Chen, L. Yang, et al., Chemosphere 270 (2021) 129481. doi: 10.1016/j.chemosphere.2020.129481
15. [15]
  P. Zeng, J.J. Du, Y.H. Song, et al., Environ. Earth Sci. 73 (2015) 4979-4987. doi: 10.1007/s12665-015-4204-2
16. [16]
  E. Kattel, M. Trapido, N. Dulova, Chem. Eng. J. 304 (2016) 646-654. doi: 10.1016/j.cej.2016.06.135
17. [17]
  W. Miao, Y. Liu, X. Chen, Y.X. Zhao, S. Mao, Carbon 159 (2020) 461-470. doi: 10.1016/j.carbon.2019.12.056
18. [18]
  Y. Deng, M. Xing, J. Zhang, Appl. Catal. B: Environ. 211 (2017) 157-166. doi: 10.1016/j.apcatb.2017.04.037
19. [19]
  X. He, H. Fang, D.J. Gosztola, et al., ACS Appl. Mater. Inter. 11 (2019) 12516-12524. doi: 10.1021/acsami.9b00223
20. [20]
  Y.H. Zhang, F.Z. Lv, T. Wu, et al., J. Sol-Gel Sci. Technol. 59 (2011) 387-391. doi: 10.1007/s10971-011-2449-0
21. [21]
  S.F. Kang, C.H. Liao, S.T. Po, Chemosphere 41 (2000) 1287-1294. doi: 10.1016/S0045-6535(99)00524-X
22. [22]
  S.F. Kang, C.H. Liao, H.P. Hung, J. Hazard. Mater. B 65 (1999) 317-333. doi: 10.1016/S0304-3894(99)00005-9
23. [23]
  J.T. Gao, Y. Wang, S.J. Zhou, W. Lin, Y. Kong, ChemCatChem 9 (2017) 1708-1715.
24. [24]
  M.A. Qamar, S. Shahid, M. Javed, Ceram. Int. 46 (2020) 22171-22180. doi: 10.1016/j.ceramint.2020.05.294
25. [25]
  C.W. Wang, H.F. Zhao, J. Wang, et al., J. Mater. Chem. A 7 (2019) 1451-1458. doi: 10.1039/C8TA09722D
26. [26]
  B.Q. Wei, C. Wang, Y.M. He, G. X. Ran, Q. J. Song. Compos. Commun. 24 (2021) 100652. doi: 10.1016/j.coco.2021.100652
27. [27]
  W. Luo, W.Y. Huang, X.Q. Feng, et al., RSC Adv. 10 (2020) 21876-21886. doi: 10.1039/D0RA00993H
28. [28]
  X. Wang, M. He, Z. Nan, Sep. Purif. Technol. 256 (2021) 117765. doi: 10.1016/j.seppur.2020.117765
29. [29]
  Y.S. Jun, E.Z. Lee, X. Wang, et al., Adv. Funct. Mater. 23 (2013) 3661-3667. doi: 10.1002/adfm.201203732
30. [30]
  S. Guo, Z.P. Deng, M.X. Li, et al., Angew. Chem. Int. Ed. 55 (2016) 1830-1834. doi: 10.1002/anie.201508505
31. [31]
  S. Zhao, Y.W. Zhang, Y.M. Zhou, et al., Carbon 126 (2018) 247-256. doi: 10.1016/j.carbon.2017.10.033
32. [32]
  C. Wang, Y. Chen, T. Hu, et al., Nanoscale 11 (2019) 11967-11974. doi: 10.1039/C9NR03038G
33. [33]
  G.G. Liu, G.X. Zhao, W. Zhou, Y.Y. Liu, H. Pang, Adv. Funct. Mater. 26 (2016) 6822-6829. doi: 10.1002/adfm.201602779
34. [34]
  F. Yang, D.Z. Liu, Y.X. Li, L.J. Cheng, J.H. Ye, Appl. Catal. B: Environ. 240 (2019) 64-71. doi: 10.1016/j.apcatb.2018.08.072
35. [35]
  X.Y. Qian, X.Q. Meng, J.W. Sun, et al., ACS Appl. Mater. Inter. 11 (2019) 27226-27232. doi: 10.1021/acsami.9b08651
36. [36]
  S. Zhou, Y. Liu, J.M. Li, et al., Appl. Catal. B: Environ. 158-159 (2014) 20-29.
37. [37]
  J. Ye, Y.P. Zang, Q.Y. Wang, et al., J. Energy Chem. 56 (2021) 283-289. doi: 10.1016/j.jechem.2020.08.014
38. [38]
  R.G. Morais, N. Rey-Raap, J.L. Figueiredo, M.F.R. Pereira, J. Energy Chem. 50 (2020) 260-270. doi: 10.1016/j.jechem.2020.03.039
39. [39]
  C. Cai, Z. Zhang, J Liu, et al., Appl. Catal. B: Environ. 182 (2016) 456-468. doi: 10.1016/j.apcatb.2015.09.056
40. [40]
  F.A. Barreiro, Y. Kumagai, M. Jonsson, J. Coord. Chem. 71 (2018) 1799-1807. doi: 10.1080/00958972.2018.1466287
41. [41]
  G. Anirudh, G. Anurag, Chemosphere 193 (2018) 1181-1188. doi: 10.1016/j.chemosphere.2017.11.046
42. [42]
  H. Kusič, N. Koprivanac, A.L. Božič, I. Selanec, J. Hazard. Mater. 136 (2006) 632-644. doi: 10.1016/j.jhazmat.2005.12.046
43. [43]
  S. Xavier, R. Gandhimathi, P.V. Nidheesh, S.T. Ramesh, Desalin. Water Treat. 57 (2016) 12832-12841. doi: 10.1080/19443994.2015.1054887
44. [44]
  L.Q. Ye, J.Y. Liu, Z. Jiang, T.Y. Peng, L. Zan, Appl. Catal. B: Environ. 142-143 (2013) 1-7.
45. [45]
  L. Wang, Y. Chen, B.Y. Chen, J. Yang, J. Hazard. Mater. 404 (2021) 124040. doi: 10.1016/j.jhazmat.2020.124040
1. [1]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
2. [2]
  Qinyu Zhao , Yunchao Zhao , Songjing Zhong , Zhaoyang Yue , Zhuoheng Jiang , Shaobo Wang , Quanhong Hu , Shuncheng Yao , Kaikai Wen , Linlin Li . Urchin-like piezoelectric ZnSnO₃/Cu₃P p-n heterojunction for enhanced cancer sonodynamic therapy. Chinese Chemical Letters, 2024, 35(12): 109644-. doi: 10.1016/j.cclet.2024.109644
3. [3]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
4. [4]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
5. [5]
  Zhongyu Wang , Lijun Wang , Huaixin Zhao . DNA-based nanosystems to generate reactive oxygen species for nanomedicine. Chinese Chemical Letters, 2024, 35(11): 109637-. doi: 10.1016/j.cclet.2024.109637
6. [6]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
7. [7]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
8. [8]
  Kun-Heng Li , Hong-Yang Zhao , Dan-Dan Wang , Ming-Hui Qi , Zi-Jian Xu , Jia-Mi Li , Zhi-Li Zhang , Shi-Wen Huang . Mitochondria-targeted nano-AIEgens as a powerful inducer for evoking immunogenic cell death. Chinese Chemical Letters, 2024, 35(5): 108882-. doi: 10.1016/j.cclet.2023.108882
9. [9]
  Feifei Wang , Hang Yao , Xinyue Wu , Yijian Tang , Yang Bai , Hui Chong , Huan Pang . Metal–organic framework and its composites modulate macrophage polarization in the treatment of inflammatory diseases. Chinese Chemical Letters, 2024, 35(5): 108821-. doi: 10.1016/j.cclet.2023.108821
10. [10]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
11. [11]
  Jiaqi Huang , Renjiang Kong , Yanmei Li , Ni Yan , Yeyang Wu , Ziwen Qiu , Zhenming Lu , Xiaona Rao , Shiying Li , Hong Cheng . Feedback enhanced tumor targeting delivery of albumin-based nanomedicine to amplify photodynamic therapy by regulating AMPK signaling and inhibiting GSTs. Chinese Chemical Letters, 2024, 35(8): 109254-. doi: 10.1016/j.cclet.2023.109254
12. [12]
  Haijing Cui , Weihao Zhu , Chuning Yue , Ming Yang , Wenzhi Ren , Aiguo Wu . Recent progress of ultrasound-responsive titanium dioxide sonosensitizers in cancer treatment. Chinese Chemical Letters, 2024, 35(10): 109727-. doi: 10.1016/j.cclet.2024.109727
13. [13]
  Xiangdong Lai , Tengfei Liu , Zengchao Guo , Yihan Wang , Jiang Xiao , Qingxiu Xia , Xiaohui Liu , Hui Jiang , Xuemei Wang . In situ formed fluorescent gold nanoclusters inhibit hair follicle regeneration in oxidative stress microenvironment via suppressing NFκB signal pathway. Chinese Chemical Letters, 2025, 36(2): 109762-. doi: 10.1016/j.cclet.2024.109762
14. [14]
  Chunyan Yang , Qiuyu Rong , Fengyin Shi , Menghan Cao , Guie Li , Yanjun Xin , Wen Zhang , Guangshan Zhang . Rationally designed S-scheme heterojunction of BiOCl/g-C₃N₄ for photodegradation of sulfamerazine: Mechanism insights, degradation pathways and DFT calculation. Chinese Chemical Letters, 2024, 35(12): 109767-. doi: 10.1016/j.cclet.2024.109767
15. [15]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
16. [16]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
17. [17]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
18. [18]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
19. [19]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
20. [20]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(509)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Engineering FeS2 nanoparticles on tubular g-C3N4 for photo-Fenton treatment of paint wastewater

Metrics

通讯作者: 陈斌, bchen63@163.com

Engineering FeS₂ nanoparticles on tubular g-C₃N₄ for photo-Fenton treatment of paint wastewater