Citation: Yuxuan Wang, Qifeng Zhou, Xiaoxiao He, Ying Zhang, Hongwei Tan, Jianhua Xu, Cuihong Wang, Wei Wang, Xiping Luo, Jinquan Chen, Lin Xu. Dithienylethene metallodendrimers with high photochromic efficiency[J]. Chinese Chemical Letters, ;2022, 33(3): 1613-1618. doi: 10.1016/j.cclet.2021.09.048 shu

Dithienylethene metallodendrimers with high photochromic efficiency

Yuxuan Wang ^{a, c, *,} ,
Qifeng Zhou ^{a, 1} ,
Xiaoxiao He ^b ,
Ying Zhang ^d ,
Hongwei Tan ^d ,
Jianhua Xu ^b ,
Cuihong Wang ^{a, **,} ,
Wei Wang ^a ,
Xiping Luo ^c ,
Jinquan Chen ^{b, **,} ,
Lin Xu ^{a, **,}

a.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
b.
State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China
c.
Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass, Department of Chemistry, Zhejiang A & F University, Hangzhou 311300, China
d.
College of Chemistry, Beijing Normal University, Beijing 100050, China

^**

20190050@zafu.edu.cn

chwang@chem.ecnu.edu.cn

jqchen@lps.ecnu.edu.cn

lxu@chem.ecnu.edu.cn

Received Date: 12 June 2021
Revised Date: 9 September 2021
Accepted Date: 13 September 2021
Available Online: 20 September 2021

Figures(5)

It has been challenging to achieve multi-photochromic systems without affecting the individual photoswitching properties of the constituent units. Herein, we present the design and synthesis of a new family of platinum-acetylide dendrimers containing up to twenty-one photochromic dithienylethene (DTE) units that exhibit both high photochromic efficiency and individual switching properties. Upon irradiation with ultraviolet (UV) and visible (vis) light, the resultant metallodendrimers display high conversion yield and good fatigue resistance. More interestingly, cyclization-cycloreversion kinetics revealed that the photochromic property of each DTE unit in these metallodendrimers is unaffected by its neighbor and the full ring-closure of up to twenty-one DTE units in one single dendrimer has been achieved.
- Photochromic compounds,
- Stimulus response,
- Dendrimers,
- Platinum-acetylide complexes,
- Dithienylethene
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