Citation: Lixia Jia, Xin Tan, Yanfang Li, Yizhong Zhang, Shiqian Cao, Wei Zhou, Xiang Huang, Lequan Liu, Tao Yu. Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range[J]. Chinese Chemical Letters, ;2022, 33(6): 3053-3060. doi: 10.1016/j.cclet.2021.09.043 shu

Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range

Lixia Jia ^a ,
Xin Tan ^{a, d} ,
Yanfang Li ^a ,
Yizhong Zhang ^a ,
Shiqian Cao ^c ,
Wei Zhou ^{c, *,} ,
Xiang Huang ^d ,
Lequan Liu ^e ,
Tao Yu ^{b, *,}

a.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
b.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
c.
School of Science, Tianjin University, Tianjin 300350, China
d.
School of Science, Tibet University, Lhasa 850000, China
e.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China

weizhou@tju.edu.cn

yutao@tju.edu.cn

Received Date: 12 July 2021
Revised Date: 12 August 2021
Accepted Date: 13 September 2021
Available Online: 17 September 2021

Figures(9)

Conversion of hexavalent chromium (Cr(Ⅵ)) to trivalent chromium (Cr(Ⅲ)) is an effective way to reduce its environmental risk, especially via photoreduction process. However, over a wide range of pH values, it is still a great challenge to achieve a high removal rate, and the disposal of produced Cr(Ⅲ) should be concerned. In this work, we implemented a high removal rate at 98% for Cr(Ⅵ) and total chromium (Cr(T)) over a wide pH range (4–10) through the synergistic effect of adsorption, photoreduction and immobilization on the surface of BiOBr_0.25I_0.75. The substitution of bromine by iodine reduced the adsorption energy of Cr(Ⅵ) on BiOBr_0.25I_0.75, promoting the adsorption of Cr(Ⅵ). Meanwhile, the introduced iodine upshifted the conduction band (CB), enhancing the reduction ability for Cr(Ⅵ) to Cr(Ⅲ). The negative surface of BiOBr_0.25I_0.75 can capture Cr(Ⅲ), achieving a high removal rate for Cr(T). The pH-independent feature for Cr(Ⅵ) and Cr(Ⅲ) removal make BiOBr_0.25I_0.75 a potential material for chromium-containing wastewater treatment. This work provides an effective strategy for removing chromium over a wide pH range.
- Adsorption,
- Photoreduction,
- BiOBr_0.25I_0.75,
- Chromium
1. [1]
  D. Wang, Y. Xu, L. Jing, et al., J. Hazard. Mater. 384 (2020) 121480-121489. doi: 10.1016/j.jhazmat.2019.121480
2. [2]
  A. Jin, X. Liu, M. Li, et al., ACS Sustain. Chem. Eng. 7 (2019) 5122-5133. doi: 10.1021/acssuschemeng.8b05969
3. [3]
  A. Zhitkovich, Chem. Res. Toxicol. 24 (2011) 1617-1629. doi: 10.1021/tx200251t
4. [4]
  Y. Liu, Z. Shen, J. Song, et al., Chin. Chem. Lett. 31 (2020) 2747-2751. doi: 10.1016/j.cclet.2020.06.016
5. [5]
  M. Sun, F. Li, M. Su, et al., J. Colloid Interface Sci. 596 (2021) 278-287. doi: 10.1016/j.jcis.2021.02.121
6. [6]
  H.H. Wu, C.W. Chang, D. Lu, et al., ACS Appl. Mater. Interfaces 11 (2019) 35702-35712. doi: 10.1021/acsami.9b10555
7. [7]
  B.A. Marinho, R. Djellabi, R.O. Cristóvão, et al., Chem. Eng. J. 318 (2017) 76-88. doi: 10.1016/j.cej.2016.05.077
8. [8]
  Y. Wang, L. Rao, P. Wang, et al., Appl. Catal. B: Environ. 262 (2020) 118308. doi: 10.1016/j.apcatb.2019.118308
9. [9]
  F. Chen, M. Zhang, L. Ma, et al., Sci. Total Environ. 730 (2020) 138930. doi: 10.1016/j.scitotenv.2020.138930
10. [10]
  H. Shen, F. Fu, W. Xue, et al., J. Colloid Interface Sci. 599 (2021) 741-751. doi: 10.1016/j.jcis.2021.04.122
11. [11]
  B. Valizadeh, T.N. Nguyen, S. Kampouri, et al., J. Mater. Chem. A 8 (2020) 9629-9637. doi: 10.1039/D0TA01046D
12. [12]
  Z. Ding, J. Liang, W. Zhang, et al., J. Mater. Chem. A 8 (2020) 11362-11369. doi: 10.1039/D0TA01847C
13. [13]
  W. Chen, Z. Yang, Z. Xie, et al., J. Mater. Chem. A 7 (2019) 998-1004. doi: 10.1039/C8TA10046B
14. [14]
  S. Wang, X. Zhao, H.M.A. Sharif, et al., Chem. Eng. J. 406 (2021) 126849. doi: 10.1016/j.cej.2020.126849
15. [15]
  R. Yuan, C. Yue, J. Qiu, et al., Appl. Catal. B: Environ. 251 (2019) 229-239. doi: 10.1016/j.apcatb.2019.03.068
16. [16]
  F. Li, Z. Wei, K. He, et al., Water Res. 185 (2020) 116219. doi: 10.1016/j.watres.2020.116219
17. [17]
  W. Liu, J. Ni, X. Yin, Water Res. 53 (2014) 12-25. doi: 10.1016/j.watres.2013.12.043
18. [18]
  N. Li, Y. Tian, J. Zhao, et al., Appl. Catal. B: Environ. 214 (2017) 126-136. doi: 10.1016/j.apcatb.2017.05.041
19. [19]
  L. Jiang, Y. Xie, F. He, et al., Chin. Chem. Lett. 32 (2021) 2187-2191. doi: 10.1016/j.cclet.2020.12.010
20. [20]
  Z. Shi, Y. Zhang, G. Duoerkun, et al., Environ. Sci. Nano 7 (2020) 2708-2722. doi: 10.1039/D0EN00551G
21. [21]
  S.M. El-Sheikh, A.B. Azzam, R.A. Geioushy, et al., J. Alloys Compd. 857 (2021) 157513-157524. doi: 10.1016/j.jallcom.2020.157513
22. [22]
  Z. Chen, J. Zhao, J. Chen, et al., Sep. Purif. Technol. 258 (2021) 118007. doi: 10.1016/j.seppur.2020.118007
23. [23]
  C. Zhao, J. Wang, X. Chen, et al., Sci. Total Environ. 752 (2021) 141901. doi: 10.1016/j.scitotenv.2020.141901
24. [24]
  J. Di, J. Xia, M. Ji, et al., J. Mater. Chem. A 3 (2015) 15108-15118. doi: 10.1039/C5TA02388B
25. [25]
  Y. Bai, L. Ye, T. Chen, et al., Appl. Catal. B: Environ. 203 (2017) 633-640. doi: 10.1016/j.apcatb.2016.10.066
26. [26]
  L. Meng, Y. Qu, L. Jing, Chin. Chem. Lett. (2021), doi: 10.1016/j.cclet.2021.03.083. doi: 10.1016/j.cclet.2021.03.083
27. [27]
  J. Shang, W. Hao, X. Lv, et al., ACS Catal. 4 (2014) 954-961. doi: 10.1021/cs401025u
28. [28]
  Z. Long, G. Zhang, H. Du, et al., J. Hazard. Mater. 407 (2021) 124394. doi: 10.1016/j.jhazmat.2020.124394
29. [29]
  L. Jia, W. Zhou, X. Huang, et al., Environ. Sci. Nano 6 (2019) 3601-3610. doi: 10.1039/C9EN00717B
30. [30]
  J. Wu, Y. Xie, Y. Ling, et al., Chem. Eng. J. 400 (2020) 125944. doi: 10.1016/j.cej.2020.125944
31. [31]
  J.E.D. Davies, J. Inorg, Nucl. Chem. 35 (1973) 1531-1534. doi: 10.1016/0022-1902(73)80242-8
32. [32]
  W. Zeng, J. Li, L. Feng, et al., Adv. Funct. Mater. 29 (2019) 1900129. doi: 10.1002/adfm.201900129
33. [33]
  W.L. Huang, J. Comput. Chem. 30 (2009) 1882-1891. doi: 10.1002/jcc.21191
34. [34]
  W.L. Huang, Q. Zhu, Comput. Mater. Sci. 43 (2008) 1101-1108. doi: 10.1016/j.commatsci.2008.03.005
35. [35]
  T. Jia, J. Wu, J. Song, et al., Chem. Eng. J. 396 (2020) 125258. doi: 10.1016/j.cej.2020.125258
36. [36]
  S. Chen, D. Huang, G. Zeng, et al., Chem. Eng. J. 382 (2020) 122840. doi: 10.1016/j.cej.2019.122840
37. [37]
  X. Xue, R. Chen, H. Chen, et al., Nano Lett. 18 (2018) 7372-7377. doi: 10.1021/acs.nanolett.8b03655
38. [38]
  Q. Wang, Z. Liu, D. Liu, et al., Appl. Catal. B: Environ. 236 (2018) 222-232. doi: 10.1016/j.apcatb.2018.05.029
39. [39]
  G. Zhang, D. Chen, N. Li, et al., Appl. Catal. B: Environ. 250 (2019) 313-324. doi: 10.1016/j.apcatb.2019.03.055
40. [40]
  J. Bai, J. Sun, X. Zhu, et al., Small 16 (2020) 1904783. doi: 10.1002/smll.201904783
41. [41]
  J. Qi, J. Liu, F. Sun, et al., Chin. Chem. Lett. 32 (2021) 1814-1818. doi: 10.1016/j.cclet.2020.11.026
42. [42]
  L. Li, L. Ai, C. Zhang, et al., Nanoscale 6 (2014) 4627-4634. doi: 10.1039/c3nr06533b
43. [43]
  X. Wu, K. Zhang, G. Zhang, et al., Chem. Eng. J. 325 (2017) 59-70. doi: 10.1016/j.cej.2017.05.044
44. [44]
  N. Liu, C. Schneider, D. Freitag, et al., Nano Lett. 14 (2014) 3309-3313. doi: 10.1021/nl500710j
45. [45]
  C. Mao, H. Cheng, H. Tian, et al., Appl. Catal. B: Environ. 228 (2018) 87-96. doi: 10.1016/j.apcatb.2018.01.018
46. [46]
  Y. Yu, K. Wu, W. Xu, et al., J. Hazard. Mater. 404 (2021) 124171. doi: 10.1016/j.jhazmat.2020.124171
47. [47]
  X. Wang, S.O. Pehkonen, A.K. Ray, Ind. Eng. Chem. Res. 43 (2004) 1665-1672. doi: 10.1021/ie030580j
48. [48]
  H. Liang, T. Li, J. Zhang, et al., J. Colloid Interface Sci. 558 (2020) 85-94. doi: 10.1016/j.jcis.2019.09.105
49. [49]
  R. Li, D. Hu, K. Hu, et al., Sci. Total Environ. 704 (2020) 135284. doi: 10.1016/j.scitotenv.2019.135284
50. [50]
  M. Ma, L. Chen, J. Zhao, et al., Chin. Chem. Lett. 30 (2019) 2191-2195. doi: 10.1016/j.cclet.2019.09.031
51. [51]
  T. Li, Y. Gao, L. Zhang, et al., Appl. Catal. B: Environ. 277 (2020) 119065-119074. doi: 10.1016/j.apcatb.2020.119065
52. [52]
  T. Li, G. Zhang, H. Lan, et al., ACS Sustain. Chem. Eng. 7 (2019) 2429-2436. doi: 10.1021/acssuschemeng.8b05297
53. [53]
  R.A. Geioushy, S.M. El-Sheikh, A.B. Azzam, et al., J. Hazard. Mater. 381 (2020) 120955. doi: 10.1016/j.jhazmat.2019.120955
54. [54]
  C. Zhu, F. Liu, L. Song, et al., Environ. Sci. Nano 5 (2018) 487-496. doi: 10.1039/C7EN01075C
55. [55]
  Y. Yang, J. Li, T. Yan, et al., J. Colloid Interface Sci. 562 (2020) 493-501. doi: 10.1016/j.jcis.2019.11.088
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沈阳化工大学材料科学与工程学院沈阳 110142

Design of BiOBr0.25I0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range

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通讯作者: 陈斌, bchen63@163.com

Design of BiOBr_0.25I_0.75 for synergy photoreduction Cr(Ⅵ) and capture Cr(Ⅲ) over wide pH range